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Chemical Bonding and Molecular Structure

243 questions · Chemistry · JEE Main
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Chemical Bonding and Molecular Structure

243 questions · Chemistry · JEE Main

  1. Among SO2​,NF3​,NH3​,XeF2​,ClF3​ and SF4​, the hybridization of the molecule with nonzero dipole moment and highest number of lone-pairs of electrons on the central atom is2025 · 2 Apr · Shift 1 · Q14 · MCQ
  2. Consider the following molecules: The correct order of rate of hydrolysis is : Includes diagram2025 · 2 Apr · Shift 1 · Q20 · MCQ
  3. A molecule with the formula AX4​Y has all it's elements from p-block. Element A is rarest, monoatomic, non-radioactive from its group and has the lowest ionization enthalpy value among A,X and Y .…2025 · 2 Apr · Shift 1 · Q8 · MCQ
  4. Which among the following molecules is (a) involved in sp3 d hybridization, (b) has different bond lengths and (c) has lone pair of electrons on the central atom?2025 · 2 Apr · Shift 2 · Q5 · MCQ
  5. Given below are two statements: Statement I : Wet cotton clothes made of cellulose based carbohydrate takes comparatively longer time to get dried than wet nylon polymer based clothes. Statement II : Intermolecular hydrogen bonding with…2025 · 3 Apr · Shift 2 · Q1 · MCQ
  6. Given below are two statements. In the light of the above statements, choose the correct answer from the options given below: Includes diagram2025 · 4 Apr · Shift 1 · Q10 · MCQ
  7. Which of the following molecule(s) show/s paramagnetic behavior? A. O2​ B. N2​ C. F2​ D. S2​ E. Cl2​ Choose the correct answer from the options given below:2025 · 4 Apr · Shift 1 · Q17 · MCQ
  8. Given below are two statements: Statement (I): For , all three possible structures may be drawn as follows. Statement (II): Structure III is most stable, as the orbitals having the lone pairs are axial, where the lp – bp repulsion is… Includes diagram2025 · 4 Apr · Shift 2 · Q1 · MCQ
  9. Match the List I with List II. Choose the correct answer from the options given below: Includes table2025 · 7 Apr · Shift 1 · Q6 · MCQ
  10. In SO2​, NO2​ − and N3​ −, the hybridizations at the central atom are respectively :2025 · 7 Apr · Shift 2 · Q5 · MCQ
  11. Given below are two statements : Statement (I) : is more polar than Statement (II) : Boiling point of is lower than but it is more polar than . In the light of the above statements, choose the most appropriate answer from the options given… Includes diagram2025 · 7 Apr · Shift 2 · Q9 · MCQ
  12. The number of molecules/ions that show linear geometry among the following is ​. SO2​,BeCl2​,CO2​, N3−​,NO2​, F2​O,XeF2​,NO2+​,I3−​,O3​…2025 · 22 Jan · Shift 1 · Q21 · Numerical
  13. Arrange the following compounds in increasing order of their dipole moment : HBr,H2​ S,NF3​ and CHCl3​2025 · 22 Jan · Shift 2 · Q9 · MCQ
  14. Match the List - I with List - II Choose the correct answer from the options given below: Includes table2025 · 23 Jan · Shift 1 · Q2 · MCQ
  15. Which of the following linear combination of atomic orbitals will lead to formation of molecular orbitals in homonuclear diatomic molecules [internuclear axis in z-direction] ? A. 2pz​ and 2px​…2025 · 24 Jan · Shift 1 · Q10 · MCQ
  16. Which of the following statement is true with respect to H2​O,NH3​ and CH4​? A. The central atoms of all the molecules are sp3 hybridized. B. The H−O−H,H−N−H…2025 · 24 Jan · Shift 1 · Q13 · MCQ
  17. Given below are two statements : Statement (I) : Experimentally determined oxygen-oxygen bond lengths in the O3​ are found to be same and the bond length is greater than that of a O=O(double bond) but less…2025 · 24 Jan · Shift 2 · Q16 · MCQ
  18. Consider ' n ' is the number of lone pair of electrons present in the equatorial position of the most stable structure of ClF3​. The ions from the following with ' n ' number of unpaired electrons are A. V3+ B. Ti3+…2025 · 28 Jan · Shift 1 · Q14 · MCQ
  19. The molecules having square pyramidal geometry are2025 · 28 Jan · Shift 1 · Q19 · MCQ
  20. Total number of non-bonded electrons present in NO2​ − ion based on Lewis theory is ​.2025 · 29 Jan · Shift 2 · Q21 · Numerical
  21. Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A): PH3​ has lower boiling point than NH3​. Reason (R) : In liquid state NH3​ molecules…2024 · 1 Feb · Shift 1 · Q14 · MCQ
  22. Arrange the bonds in order of increasing ionic character in the molecules. LiF, K2​O,N2​,SO2​ and ClF3​ :2024 · 1 Feb · Shift 1 · Q20 · MCQ
  23. The number of molecules/ion/s having trigonal bipyramidal shape is ​. PF5​,BrF5​,PCl5​,[PtCl4​]2−,BF3​,Fe(CO)5​2024 · 1 Feb · Shift 1 · Q26 · Numerical
  24. The lowest oxidation number of an atom in a compound A2​B is -2 . The number of electrons in its valence shell is ​.2024 · 1 Feb · Shift 1 · Q27 · Numerical
  25. Given below are two statements : Statement (I) : A π bonding MO has lower electron density above and below the inter-nuclear axis. Statement (II) : The π∗ antibonding MO has a node between the nuclei. In the light of the above…2024 · 1 Feb · Shift 2 · Q17 · MCQ
  26. Select the compound from the following that will show intramolecular hydrogen bonding.2024 · 1 Feb · Shift 2 · Q20 · MCQ
  27. Number of molecules/ions from the following in which the central atom is involved in sp3 hybridization is ​. NO3−​,BCl3​,ClO2−​,ClO3−​2024 · 4 Apr · Shift 1 · Q11 · MCQ
  28. Which one of the following molecules has maximum dipole moment?2024 · 4 Apr · Shift 1 · Q18 · MCQ
  29. Number of molecules/species from the following having one unpaired electron is ​. O2​,O2−1​,NO,CN−1,O22−​2024 · 4 Apr · Shift 1 · Q29 · Numerical
  30. The correct statement/s about Hydrogen bonding is/are A. Hydrogen bonding exists when H is covalently bonded to the highly electro negative atom. B. Intermolecular H bonding is present in o-nitro phenol C. Intramolecular H…2024 · 4 Apr · Shift 2 · Q11 · MCQ
  31. The number of species from the following that have pyramidal geometry around the central atom is ​ S2​O32−​,SO42−​,SO32−​,S2​O72−​2024 · 4 Apr · Shift 2 · Q14 · MCQ
  32. Number of compounds / species from the following with non-zero dipole moment is ​. BeCl2​,BCl3​,NF3​,XeF4​,CCl4​,H2​O,H2​ S,HBr,CO2​,H2​,HCl…2024 · 4 Apr · Shift 2 · Q22 · Numerical
  33. In the lewis dot structure for NO2−​, total number of valence electrons around nitrogen is ​.2024 · 5 Apr · Shift 1 · Q26 · Numerical
  34. Number of σ and π bonds present in ethylene molecule is respectively :2024 · 5 Apr · Shift 1 · Q9 · MCQ
  35. Match List I with List II. Choose the correct answer from the options given below : Includes table2024 · 5 Apr · Shift 2 · Q2 · MCQ
  36. Number of compounds from the following with zero dipole moment is ​. HF,H2​,H2​ S,CO2​,NH3​,BF3​,CH4​,CHCl3​,SiF4​,H2​O,BeF2​…2024 · 5 Apr · Shift 2 · Q30 · Numerical
  37. Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A) : NH3​ and NF3​ molecule have pyramidal shape with a lone pair of electrons on nitrogen atom.…2024 · 5 Apr · Shift 2 · Q9 · MCQ
  38. Match List I with List II Choose the correct answer from the options given below: Includes table2024 · 6 Apr · Shift 1 · Q11 · MCQ
  39. Match List I with List II Choose the correct answer from the options given below: Includes table2024 · 6 Apr · Shift 1 · Q12 · MCQ
  40. Number of molecules from the following which can exhibit hydrogen bonding is ​. (nearest integer) Includes diagram2024 · 6 Apr · Shift 1 · Q28 · Numerical
  41. Consider the following reactions The number of protons that do not involve in hydrogen bonding in the product B is ​. Includes diagram2024 · 6 Apr · Shift 2 · Q20 · Numerical
  42. Total number of species from the following with central atom utilising sp2 hybrid orbitals for bonding is ​. NH3​,SO2​,SiO2​,BeCl2​,C2​H2​,C2​H4​,BCl3​,HCHO,C6​H6​,BF3​,C2​H4​Cl2​…2024 · 6 Apr · Shift 2 · Q29 · Numerical
  43. Number of molecules from the following which are exceptions to octet rule is ​. CO2​,NO2​,H2​SO4​,BF3​,CH4​,SiF4​,ClO2​,PCl5​,BeF2​,C2​H6​,CHCl3​,CBr4​…2024 · 8 Apr · Shift 1 · Q27 · Numerical
  44. Match List I with List II Choose the correct answer from the options given below: Includes table2024 · 8 Apr · Shift 1 · Q8 · MCQ
  45. Number of molecules having bond order 2 from the following molecules is ​. C2​,O2​,Be2​,Li2​,Ne2​, N2​,He2​2024 · 8 Apr · Shift 2 · Q30 · Numerical
  46. The shape of carbocation is :2024 · 8 Apr · Shift 2 · Q6 · MCQ
  47. When ψA​ and ψB​ are the wave functions of atomic orbitals, then σ∗ is represented by :2024 · 8 Apr · Shift 2 · Q7 · MCQ
  48. In which one of the following pairs the central atoms exhibit sp2 hybridization ?2024 · 9 Apr · Shift 1 · Q10 · MCQ
  49. The total number of species from the following in which one unpaired electron is present, is ​. N2​,O2​,C2−​,O2−​,O22−​,H2+​,CN−,He2+​…2024 · 9 Apr · Shift 1 · Q25 · Numerical
  50. The correct increasing order for bond angles among BF3​,PF3​ and ClF3​ is :2024 · 9 Apr · Shift 2 · Q13 · MCQ
  51. Total number of electrons present in (π∗) molecular orbitals of O2​,O2+​ and O2−​ is ​.2024 · 9 Apr · Shift 2 · Q24 · Numerical
  52. Sum of bond order of CO and NO + is ​.2024 · 27 Jan · Shift 1 · Q29 · Numerical
  53. Choose the polar molecule from the following:2024 · 27 Jan · Shift 1 · Q9 · MCQ
  54. The number of non-polar molecules from the following is ​. HF,H2​O,SO2​,H2​,CO2​,CH4​,NH3​,HCl,CHCl3​,BF3​…2024 · 27 Jan · Shift 2 · Q26 · Numerical
  55. The difference in energy between the actual structure and the lowest energy resonance structure for the given compound is2024 · 29 Jan · Shift 1 · Q11 · MCQ
  56. The number of species from the following which are paramagnetic and with bond order equal to one is ​. H2​,He2+​,O2+​,N22−​,O22−​,F2​,Ne2+​,B2​…2024 · 29 Jan · Shift 1 · Q25 · Numerical
  57. Number of compounds with one lone pair of electrons on central atom amongst following is ​. O3​,H2​O,SF4​,ClF3​,NH3​,BrF5​,XeF4​2024 · 29 Jan · Shift 1 · Q28 · Numerical
  58. The total number of molecules with zero dipole moment among CH4​,BF3​,H2​O,HF,NH3​,CO2​ and SO2​ is ​.2024 · 29 Jan · Shift 2 · Q21 · Numerical
  59. The total number of anti bonding molecular orbitals, formed from 2s and 2p atomic orbitals in a diatomic molecule is ​.2024 · 29 Jan · Shift 2 · Q26 · Numerical
  60. Aluminium chloride in acidified aqueous solution forms an ion having geometry2024 · 30 Jan · Shift 1 · Q1 · MCQ
  61. Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A) : There is a considerable increase in covalent radius from N to P. However from As to Bi only a…2024 · 30 Jan · Shift 1 · Q19 · MCQ
  62. The total number of molecular orbitals formed from 2s and 2p atomic orbitals of a diatomic molecule is ​.2024 · 30 Jan · Shift 1 · Q21 · Numerical
  63. Match List I with List II. Choose the correct answer from the options given below : Includes table2024 · 30 Jan · Shift 1 · Q9 · MCQ
  64. Given below are two statements: Statement - I: Since Fluorine is more electronegative than nitrogen, the net dipole moment of NF3​ is greater than NH3​. Statement - II: In NH3​, the orbital dipole due to…2024 · 30 Jan · Shift 2 · Q6 · MCQ
  65. The molecule / ion with square pyramidal shape is2024 · 30 Jan · Shift 2 · Q9 · MCQ
  66. The linear combination of atomic orbitals to form molecular orbitals takes place only when the combining atomic orbitals A. have the same energy B. have the minimum overlap C. have same symmetry about the molecular axis D. have different…2024 · 31 Jan · Shift 1 · Q13 · MCQ
  67. The number of species from the following in which the central atom uses sp3 hybrid orbitals in its bonding is ​. NH3​,SO2​,SiO2​,BeCl2​,CO2​,H2​O,CH4​,BF3​…2024 · 31 Jan · Shift 1 · Q30 · Numerical
  68. Which of the following is least ionic?2024 · 31 Jan · Shift 2 · Q12 · MCQ
  69. A diatomic molecule has a dipole moment of 1.2 D. If the bond distance is 1 A∘, then fractional charge on each atom is ​×10−1 esu. (Given 1 D=10−18 esucm)2024 · 31 Jan · Shift 2 · Q22 · Numerical
  70. O−O bond length in H2​O2​ is X​ than the O−O bond length in F2​O2​. The O−H bond length in H2​O2​…2023 · 1 Feb · Shift 2 · Q1 · MCQ
  71. The number of species from the following which have square pyramidal structure is ​ PF5​,BrF4−​,IF5​,BrF5​,XeOF4​,ICl4−​2023 · 6 Apr · Shift 1 · Q16 · Numerical
  72. Match List I with List II Choose the correct answer from the options given below: Includes table2023 · 6 Apr · Shift 1 · Q7 · MCQ
  73. The number of species having a square planar shape from the following is ​. XeF4​,SF4​,SiF4​,BF4−​,BrF4−​,[Cu(NH3​)4​]2+,[FeCl4​]2−,[PtCl4​]2−…2023 · 6 Apr · Shift 2 · Q16 · Numerical
  74. In an ice crystal, each water molecule is hydrogen bonded to ​ neighbouring molecules.2023 · 6 Apr · Shift 2 · Q21 · Numerical
  75. The number of following factors which affect the percent covalent character of the ionic bond is ​ (A) Polarising power of cation (B) Extent of distortion of anion (C) Polarisability of the anion (D) Polarising…2023 · 8 Apr · Shift 1 · Q16 · Numerical
  76. The number of species from the following carrying a single lone pair on central atom Xenon is ​. XeF5+​,XeO3​,XeO2​ F2​,XeF5−​,XeO3​ F2​,XeOF4​,XeF4​…2023 · 8 Apr · Shift 2 · Q14 · Numerical
  77. The compound which does not exist is2023 · 10 Apr · Shift 1 · Q1 · MCQ
  78. The number of bent-shaped molecule/s from the following is ​ N 3−​, NO 2−​, I 3−​, O 3​, SO 2​2023 · 10 Apr · Shift 1 · Q16 · Numerical
  79. The sum of lone pairs present on the central atom of the interhalogen IF 5​ and IF 7​ is ​2023 · 10 Apr · Shift 1 · Q18 · Numerical
  80. The number of molecules from the following which contain only two lone pair of electrons is ​ H2​O,N2​,CO,XeF4​,NH3​,NO,CO2​, F2​…2023 · 10 Apr · Shift 2 · Q13 · Numerical
  81. Match List - I with List - II: Choose the correct answer from the options given below: Includes table2023 · 11 Apr · Shift 1 · Q5 · MCQ
  82. The maximum number of lone pairs of electrons on the central atom from the following species is ​. ClO3​−,XeF4​,SF4​ and I3​−2023 · 11 Apr · Shift 2 · Q16 · Numerical
  83. The bond order and magnetic property of acetylide ion are same as that of2023 · 12 Apr · Shift 1 · Q4 · MCQ
  84. In which of the following processes, the bond order increases and paramagnetic character changes to diamagnetic one ?2023 · 13 Apr · Shift 1 · Q1 · MCQ
  85. ClF5​ at room temperature is a:2023 · 13 Apr · Shift 1 · Q6 · MCQ
  86. Given below are two statements : Statement I : SO2​ and H2​O both possess V-shaped structure. Statement II : The bond angle of SO2​ is less than that of H2​O. In the…2023 · 13 Apr · Shift 2 · Q8 · MCQ
  87. Consider the following statements: (A) NF3​ molecule has a trigonal planar structure. (B) Bond length of N2​ is shorter than O2​. (C) Isoelectronic molecules or ions have identical bond order. (D) Dipole moment…2023 · 15 Apr · Shift 1 · Q10 · MCQ
  88. The number of P−O−P bonds in H4​P2​O7​,(HPO3​)3​ and P4​O10​ are respectively :2023 · 15 Apr · Shift 1 · Q4 · MCQ
  89. Order of Covalent bond; A. KF>KI;LiF>KF B. KF<KI;LiF>KF C. SnCl4​>SnCl2​;CuCl>NaCl D. LiF>KF;CuCl<NaCl E. KF<KI;CuCl>NaCl Choose the…2023 · 24 Jan · Shift 1 · Q11 · MCQ
  90. Decreasing order of the hydrogen bonding in following forms of water is correctly represented by A. Liquid water B. Ice C. Impure water Choose the correct answer from the options given below :2023 · 24 Jan · Shift 1 · Q3 · MCQ
  91. What is the number of unpaired electron(s) in the highest occupied molecular orbital of the following species : N2​;N2+​;O2​;O2+​ ?2023 · 24 Jan · Shift 2 · Q3 · MCQ
  92. The total number of lone pairs of electrons on oxygen atoms of ozone is ​.2023 · 25 Jan · Shift 1 · Q23 · Numerical
  93. Statement I : Dipole moment is a vector quantity and by convention it is depicted by a small arrow with tail on the negative centre and head pointing towards the positive centre. Statement II : The crossed arrow of the dipole moment…2023 · 25 Jan · Shift 2 · Q9 · MCQ
  94. The number of molecules or ions from the following, which do not have odd number of electrons are ​. (A) NO 2​ (B) ICl 4−​ (C) BrF 3​ (D) ClO 2​ (E) NO 2+​ (F) NO2023 · 29 Jan · Shift 1 · Q15 · Numerical
  95. The magnetic behaviour of Li2​O,Na2​O2​ and KO2​, respectively, are :2023 · 29 Jan · Shift 1 · Q2 · MCQ
  96. The bond dissociation energy is highest for2023 · 29 Jan · Shift 1 · Q5 · MCQ
  97. According to MO theory the bond orders for O22−​, CO and NO+ respectively, are2023 · 29 Jan · Shift 2 · Q5 · MCQ
  98. Match List I with List II Choose the correct answer from the options given below : Includes table2023 · 30 Jan · Shift 1 · Q13 · MCQ
  99. For OF2​ molecule consider the following : A. Number of lone pairs on oxygen is 2 . B. FOF angle is less than 104.5∘. C. Oxidation state of O is −2. D. Molecule is bent 'V' shaped. E. Molecular…2023 · 30 Jan · Shift 1 · Q9 · MCQ
  100. Match List I with List II Choose the correct answer from the options given below : Includes table2023 · 31 Jan · Shift 1 · Q15 · MCQ
  101. Amongst the following, the number of species having the linear shape is ​. XeF2​,I3+​,C3​O2​,I3−​,CO2​,SO2​,BeCl2​…2023 · 31 Jan · Shift 2 · Q16 · Numerical
  102. The correct order of bond orders of C2​2−, N2​2− and O2​2− is, respectively2022 · 24 Jun · Shift 2 · Q3 · MCQ
  103. Among the following species N2​, N2+​,N2−​,N22−​,O2​,O2+​,O2−​,O22−​ the number of species showing diamagnesim is ​…2022 · 25 Jul · Shift 1 · Q12 · Numerical
  104. Match List I with List II: Choose the correct answer from the options given below: Includes table2022 · 25 Jul · Shift 2 · Q1 · MCQ
  105. The sum of number of lone pairs of electrons present on the central atoms of XeO3​, XeOF4​ and XeF6​, is ​2022 · 25 Jul · Shift 2 · Q18 · Numerical
  106. Bonding in which of the following diatomic molecule(s) become(s) stronger, on the basis of MO Theory, by removal of an electron? (A) NO (B) N2​ (C) O2​ (D) C2​ (E) B2​ Choose the most appropriate answer from the options given…2022 · 25 Jun · Shift 1 · Q1 · MCQ
  107. Number of electron deficient molecules among the following PH3​, B2​H6​, CCl4​, NH3​, LiH and BCl3​ is2022 · 25 Jun · Shift 1 · Q3 · MCQ
  108. Amongst BeF2​, BF3​, H2​O, NH3​, CCl4​ and HCl, the number of molecules with non-zero net dipole moment is ​.2022 · 25 Jun · Shift 2 · Q17 · Numerical
  109. Match List-I with List-II : Choose the correct answer from the options given below : Includes table2022 · 26 Jul · Shift 1 · Q1 · MCQ
  110. Arrange the following in increasing order of their covalent character. A. CaF2​ B. CaCl2​ C. CaBr2​ D. CaI2​ Choose the correct answer from the options given below.2022 · 26 Jul · Shift 2 · Q2 · MCQ
  111. Consider the ions/molecule O 2+​, O2​, O 2−​, O 22−​ For increasing bond order the correct option is :2022 · 26 Jun · Shift 1 · Q3 · MCQ
  112. Amongst SF4​, XeF4​, CF4​ and H2​O, the number of species with two lone pairs of electrons is ​.2022 · 26 Jun · Shift 2 · Q17 · Numerical
  113. Amongst the following, the number of oxide(s) which are paramagnetic in nature is Na2​O,KO2​,NO2​, N2​O,ClO2​,NO,SO2​,Cl2​O…2022 · 27 Jul · Shift 1 · Q16 · Numerical
  114. According to MO theory, number of species/ions from the following having identical bond order is ​. CN−,NO+,O2​,O2+​,O22+​2022 · 27 Jul · Shift 1 · Q18 · Numerical
  115. Given below are two statements. Statement I: O2​,Cu2+, and Fe3+ are weakly attracted by magnetic field and are magnetized in the same direction as magnetic field. Statement II: NaCl and H2​O…2022 · 27 Jul · Shift 1 · Q2 · MCQ
  116. The number of molecule(s) or ion(s) from the following having non-planar structure is ​. NO3−​,H2​O2​,BF3​,PCl3​,XeF4​,SF4​,XeO3​,PH4+​,SO3​,[Al(OH)4​]−…2022 · 27 Jul · Shift 2 · Q19 · Numerical
  117. Match List - I with List - II. Choose the correct answer from the options given below : Includes table2022 · 27 Jul · Shift 2 · Q2 · MCQ
  118. Based upon VSEPR theory, match the shape (geometry) of the molecules in List-I with the molecules in List-II and select the most appropriate option. Includes table2022 · 27 Jun · Shift 1 · Q2 · MCQ
  119. Identify the incorrect statement for PCl5​ from the following.2022 · 27 Jun · Shift 2 · Q1 · MCQ
  120. The correct order of increasing intermolecular hydrogen bond strength is :2022 · 27 Jun · Shift 2 · Q2 · MCQ
  121. The number of paramagnetic species among the following is ​. B2​,Li2​,C2​,C2−​,O22−​,O2+​ and He2+​2022 · 28 Jul · Shift 1 · Q15 · Numerical
  122. The number of interhalogens from the following having square pyramidal structure is : ClF3​,IF7​,BrF5​,BrF3​,I2​Cl6​,IF5​,ClF,ClF5​2022 · 28 Jul · Shift 1 · Q19 · Numerical
  123. The hybridization of P exhibited in PF5​ is spxdy. The value of y is ​.2022 · 28 Jun · Shift 1 · Q16 · Numerical
  124. In the structure of SF4​, the lone pair of electrons on S is in.2022 · 28 Jun · Shift 2 · Q3 · MCQ
  125. Which of the following pair of molecules contain odd electron molecule and an expanded octet molecule?2022 · 29 Jul · Shift 1 · Q1 · MCQ
  126. Number of lone pairs of electrons in the central atom of SCl2​,O3​,ClF3​ and SF6​, respectively, are :2022 · 29 Jul · Shift 1 · Q5 · MCQ
  127. Consider, PF5​,BrF5​,PCl3​,SF6​,[ICl4​]−,ClF3​ and IF5​. Amongst the above molecule(s)/ion(s), the number of molecule(s)/ion(s) having sp3 d2…2022 · 29 Jul · Shift 2 · Q16 · Numerical
  128. Consider the species CH4​, NH 4+​ and BH 4−​. Choose the correct option with respect to the these species.2022 · 29 Jun · Shift 2 · Q2 · MCQ
  129. Number of lone pair(s) of electrons on central atom and the shape BrF3​ molecule respectively, are2022 · 29 Jun · Shift 2 · Q6 · MCQ
  130. Amongst the following, the number of molecule/(s) having net resultant dipole moment is ​. NF3​, BF3​, BeF2​, CHCl3​, H2​S, SiF4​, CCl4​, PF5​2022 · 30 Jun · Shift 1 · Q16 · Numerical
  131. Number of paramagnetic oxides among the following given oxides is ​. Li2​O, CaO, Na2​O2​, KO2​, MgO and K2​O2021 · 1 Sep · Shift 2 · Q13 · MCQ
  132. The spin-only magnetic moment value of B2+​ species is ​× 10 − 2 BM. (Nearest integer) [Given : 3​ = 1.73]2021 · 1 Sep · Shift 2 · Q21 · Numerical
  133. Given below are two statements : one is labeled as Assertion A and the other is labelled as Reason R : Assertion A : The H − O − H bond angle in water molecule is 104.5 ∘. Reason R : The lone pair - lone pair repulsion of…2021 · 16 Mar · Shift 1 · Q2 · MCQ
  134. A central atom in a molecule has two lone pairs of electrons and forms three single bonds. The shape of this molecule is :2021 · 17 Mar · Shift 1 · Q11 · MCQ
  135. Amongst the following, the linear species is :2021 · 17 Mar · Shift 2 · Q4 · MCQ
  136. AX is a covalent diatomic molecule where A and X are second row elements of periodic table. Based on Molecular orbital theory, the bond order of AX is 2.5. The total number of electrons in AX is ​. (Round off to…2021 · 18 Mar · Shift 1 · Q15 · Numerical
  137. The number of species below that have two lone pairs of electrons in their central atom is ​. (Round off to the Nearest Integer). SF4​, BF 4−​, ClF3​, AsF3​, PCl5​, BrF5​, XeF4​, SF6​2021 · 18 Mar · Shift 2 · Q16 · Numerical
  138. The number of lone pairs of electrons on the central I atom in I 3−​ is ​.2021 · 20 Jul · Shift 1 · Q12 · Numerical
  139. The hybridisations of the atomic orbitals of nitrogen in NO 2−​, NO 2+​ and NH 4+​ respectively are.2021 · 20 Jul · Shift 2 · Q10 · MCQ
  140. Match List-I with List-II : Choose the correct answer from the options given below : Includes table2021 · 22 Jul · Shift 2 · Q7 · MCQ
  141. Which of the following are isostructural pairs ? A. SO42−​ and CrO42−​ B. SiCl4​, and TiCl4​ C. NH3​ and NO3−​ D. BCl3​ and BrCl3​2021 · 24 Feb · Shift 1 · Q3 · MCQ
  142. The correct shape and I−I−I bond angles respectively in I3−​ ion are :2021 · 24 Feb · Shift 2 · Q12 · MCQ
  143. The correct set from the following in which both pairs are in correct order of melting point is :2021 · 24 Feb · Shift 2 · Q6 · MCQ
  144. Among the following, the number of halide(s) which is/are inert to hydrolysis is ​. (A) BF3​ (B) SiCl4​ (C) PCl5​ (D) SF6​2021 · 25 Feb · Shift 1 · Q22 · Numerical
  145. According to molecular orbital theory, the species among the following that does not exist is :2021 · 25 Feb · Shift 1 · Q9 · MCQ
  146. Which among the following species has unequal bond lengths?2021 · 25 Feb · Shift 2 · Q4 · MCQ
  147. In the following the correct bond order sequence is :2021 · 25 Jul · Shift 2 · Q1 · MCQ
  148. Identify the species having one π-bond and maximum number of canonical forms from the following :2021 · 25 Jul · Shift 2 · Q9 · MCQ
  149. AB3​ is an interhalogen T-shaped molecule. The number of lone pairs of electrons on A is ​. (Integer answer)2021 · 26 Aug · Shift 1 · Q13 · Numerical
  150. The bond order and magnetic behaviour of O2−​ ion are respectively :2021 · 26 Aug · Shift 2 · Q2 · MCQ
  151. Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R. Assertion A : Dipole-dipole interactions are the only non-covalent interactions, resulting in hydrogen bond formation. Reason R :…2021 · 26 Feb · Shift 1 · Q6 · MCQ
  152. Match List - I with List - II. Choose the correct answer from the options given below : Includes table2021 · 26 Feb · Shift 2 · Q1 · MCQ
  153. Match List - I with List - II : Choose the most appropriate answer from the options given below : Includes diagram2021 · 27 Aug · Shift 1 · Q3 · MCQ
  154. Match items of List-I with those of List-II : Choose the most appropriate answer from the options given below : Includes table2021 · 27 Aug · Shift 1 · Q4 · MCQ
  155. The number of species having non-pyramidal shape among the following is ​. (A) SO3​ (B) NO 3−​ (C) PCl3​ (D) CO 32−​2021 · 27 Aug · Shift 2 · Q21 · Numerical
  156. The difference between bond orders of CO and NO ⊕ is 2x​ where x = ​. (Round off to the Nearest Integer)2021 · 27 Jul · Shift 1 · Q22 · Numerical
  157. The total number of electrons in all bonding molecular orbitals of O22−​ is ​. (Round off to the nearest integer)2021 · 27 Jul · Shift 2 · Q17 · Numerical
  158. The number of hydrogen bonded water molecule(s) associated with stoichiometry CuSO4​.5H2​O is ​.2021 · 31 Aug · Shift 1 · Q18 · Numerical
  159. According to molecular orbital theory, the number of unpaired electron(s) in O22−​ is :2021 · 31 Aug · Shift 2 · Q20 · Numerical
  160. If AB4​ molecule is a polar molecule, a possible geometry of AB4​ is2020 · 2 Sep · Shift 1 · Q17 · MCQ
  161. The molecular geometry of SF6​ is octahedral. What is the geometry of SF4​ (including lone pair(s) of electrons, if any)?2020 · 2 Sep · Shift 2 · Q10 · MCQ
  162. Match the type of interaction in column A with the distance dependence of their interaction energy in column B Includes table2020 · 2 Sep · Shift 2 · Q12 · MCQ
  163. The shape / structure of [XeF5​]– and XeO3​F2​, respectively, are2020 · 2 Sep · Shift 2 · Q8 · MCQ
  164. Of the species, NO, NO+, NO2+​ and NO− , the one with minimum bond strength is :2020 · 3 Sep · Shift 1 · Q17 · MCQ
  165. The intermolecular potential energy for the molecules A, B, C and D given below suggests that : Includes diagram2020 · 4 Sep · Shift 1 · Q12 · MCQ
  166. The reaction in which the hybridisation of the underlined atom is affected is :2020 · 4 Sep · Shift 2 · Q21 · MCQ
  167. The potential energy curve for the H2​ molecule as a function of internuclear distance is :2020 · 5 Sep · Shift 1 · Q18 · MCQ
  168. The structure of PCl5​ in the solid state is :2020 · 5 Sep · Shift 1 · Q5 · MCQ
  169. The compound that has the largest H–M–H bond angle (M = N, O, S, C) is :2020 · 5 Sep · Shift 2 · Q15 · MCQ
  170. The number of Cl = O bonds in perchloric acid is, "​".2020 · 6 Sep · Shift 1 · Q1 · Numerical
  171. Chlorine reacts with hot and concentrated NaOH and produces compounds (X) and (Y). Compound (X) gives white precipitate with silver nitrate solution. The average bond order between CI and O atoms in (Y) is.2020 · 7 Jan · Shift 1 · Q1 · Numerical
  172. The dipole of CCl4​, CHCl3​ and CH4​ are in the order :2020 · 7 Jan · Shift 1 · Q10 · MCQ
  173. The relative strength of interionic/intermolecular forces in decreasing order is :2020 · 7 Jan · Shift 1 · Q13 · MCQ
  174. The bond order and the magnetic characteristics of CN− are :2020 · 7 Jan · Shift 2 · Q12 · MCQ
  175. Arrange the following bonds according to their average bond energies in descending order : C–Cl, C–Br, C–F, C–I2020 · 8 Jan · Shift 2 · Q18 · MCQ
  176. If the magnetic moment of a dioxygen species is 1.73 B.M, it may be :2020 · 9 Jan · Shift 1 · Q3 · MCQ
  177. The number of sp2 hybrid orbitals in a molecule of benzene is :2020 · 9 Jan · Shift 2 · Q11 · MCQ
  178. Among the following molecules / ions, C22−​,N22−​,O22−​,O2​ which one is diamagnetic and has the shortest bond length?2019 · 8 Apr · Shift 2 · Q13 · MCQ
  179. The covalent alkaline earth metal halide (X = Cl, Br, I) is :2019 · 8 Apr · Shift 2 · Q16 · MCQ
  180. The ion that has sp3d2 hybridization for the central atom, is :2019 · 8 Apr · Shift 2 · Q21 · MCQ
  181. The correct statement about ICl5​ and ICl4−​ is2019 · 8 Apr · Shift 2 · Q6 · MCQ
  182. Among the following, the molecule expected to be stabilized by anion formation is : C2​, O2​, NO, F2​2019 · 9 Apr · Shift 1 · Q12 · MCQ
  183. Among the following species, the diamagnetic molecule is2019 · 9 Apr · Shift 2 · Q11 · MCQ
  184. HF has highest boiling point among hydrogen halides, because it has :2019 · 9 Apr · Shift 2 · Q18 · MCQ
  185. According to molecular orbital theory, which of the following is true with respect to Li2+​ and Li2​ − ?2019 · 9 Jan · Shift 1 · Q18 · MCQ
  186. In which of the following process, the bond order has increased and paramagnetic character has charged to diamagnetic ?2019 · 9 Jan · Shift 2 · Q17 · MCQ
  187. The oxoacid of sulphur that does not contain bond between sulphur atoms is2019 · 10 Apr · Shift 1 · Q1 · MCQ
  188. During the change of O2​ to O2−​ , the incoming electron goes to the orbital :2019 · 10 Apr · Shift 1 · Q5 · MCQ
  189. The type of hybridisation and number of lone pair (s) of electrons of Xe in XeOF4​, respectively, are:2019 · 10 Jan · Shift 1 · Q12 · MCQ
  190. Two pi and half sigma bonds are present in :2019 · 10 Jan · Shift 1 · Q18 · MCQ
  191. The pair that contains two P – H bonds in each of the oxoacids is2019 · 10 Jan · Shift 2 · Q10 · MCQ
  192. The correct statement among the following is :2019 · 12 Apr · Shift 1 · Q2 · MCQ
  193. The decreasing order of bond angles in BF3​, NH3​, PF3​ and I3−​ is :2018 · 15 Apr · Shift 1 · Q12 · MCQ
  194. Identify the pair in which the geometry of the species is T-shape and square - pyraidal, respectively :2018 · 15 Apr · Shift 1 · Q15 · MCQ
  195. In the molecular orbital diagram for the molecular ion, N2+​, the number of electrons in the σ 2pz molecular orbital is :2018 · 15 Apr · Shift 1 · Q19 · MCQ
  196. In hydrogen azide (above) the bond orders of bond (I) and (II) are : Includes diagram2018 · 15 Apr · Shift 1 · Q9 · MCQ
  197. Which of the following best describes the diagram below of a molecular orbital ? Includes diagram2018 · 15 Apr · Shift 2 · Q6 · MCQ
  198. The incorrect geometry is represented by :2018 · 16 Apr · Shift 1 · Q14 · MCQ
  199. Which of the following conversions involves change in both shape and hybridisation ?2018 · 16 Apr · Shift 1 · Q18 · MCQ
  200. Which of the following compounds contain(s) no covalent bond(s)? KCl, PH3​, O2​, B2​H6​, H2​SO4​2018 · Shift 0 · Q14 · MCQ