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Chemical Bonding and Molecular Structure question

2019 · 8 Apr · Shift 2 · Q16
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Chemical Bonding and Molecular Structure question

2019 · 8 Apr · Shift 2 · Q16

JEE MainChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
The covalent alkaline earth metal halide (X = Cl, Br, I) is :
  1. A
    CaX2CaX_2CaX2​
  2. B
    SrX2SrX_2SrX2​
  3. C
    MgX2MgX_2MgX2​
  4. D
    BeX2BeX_2BeX2​
View written solutionFree

Correct answer: D

  1. Use Fajan's rule

    The covalent character in an ionic compound increases when:

    • the cation is small and highly polarizing,
    • the anion is large and highly polarizable.

    Here, the compounds are alkaline earth metal halides: MX2 ,X=Cl,Br,IMX_2 \, , \quad X = Cl, Br, IMX2​,X=Cl,Br,I

  2. Compare the alkaline earth metal cations

    The cations are: Ca2+, Sr2+, Mg2+, Be2+Ca^{2+},\ Sr^{2+},\ Mg^{2+},\ Be^{2+}Ca2+, Sr2+, Mg2+, Be2+

    Among these, the size order is approximately: Be2+<Mg2+<Ca2+<Sr2+Be^{2+} < Mg^{2+} < Ca^{2+} < Sr^{2+}Be2+<Mg2+<Ca2+<Sr2+

    Since all have charge +2+2+2, the smallest cation has the highest polarizing power.

    Therefore, Be2+Be^{2+}Be2+ has the maximum tendency to distort the electron cloud of halide ions and hence forms the most covalent halide.

  3. Check the options

    • A: CaX2CaX_2CaX2​ — less covalent than beryllium halides
    • B: SrX2SrX_2SrX2​ — even larger cation, hence more ionic
    • C: MgX2MgX_2MgX2​ — shows some covalent character, but less than beryllium halides
    • D: BeX2BeX_2BeX2​ — maximum covalent character among the given alkaline earth metal halides
  4. Conclusion

    The covalent alkaline earth metal halide is: BeX2\boxed{BeX_2}BeX2​​

  5. Comparison with stored answer

    Stored correct answer: D

    Our derived answer is also D, so they agree.

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