JEE MainChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
The covalent alkaline earth metal halide (X = Cl, Br, I) is :
- A
- B
- C
- D
View written solutionFree
Correct answer: D
-
Use Fajan's rule
The covalent character in an ionic compound increases when:
- the cation is small and highly polarizing,
- the anion is large and highly polarizable.
Here, the compounds are alkaline earth metal halides:
-
Compare the alkaline earth metal cations
The cations are:
Among these, the size order is approximately:
Since all have charge , the smallest cation has the highest polarizing power.
Therefore, has the maximum tendency to distort the electron cloud of halide ions and hence forms the most covalent halide.
-
Check the options
- A: — less covalent than beryllium halides
- B: — even larger cation, hence more ionic
- C: — shows some covalent character, but less than beryllium halides
- D: — maximum covalent character among the given alkaline earth metal halides
-
Conclusion
The covalent alkaline earth metal halide is:
-
Comparison with stored answer
Stored correct answer: D
Our derived answer is also D, so they agree.
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