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Chemical Bonding and Molecular Structure question

2024 · 5 Apr · Shift 1 · Q26
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  5. /2024 · 5 Apr · Shift 1 · Q26

Chemical Bonding and Molecular Structure question

2024 · 5 Apr · Shift 1 · Q26

JEE MainChemistryChemical Bonding and Molecular StructureNumerical+4 / −1
In the lewis dot structure for NO2−\mathrm{NO}_2^{-}NO2−​, total number of valence electrons around nitrogen is ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 8

  1. Count total valence electrons in NO2−\mathrm{NO_2^-}NO2−​
  • Nitrogen has 555 valence electrons.
  • Each oxygen has 666 valence electrons, so two oxygens contribute 2×6=122 \times 6 = 122×6=12.
  • The negative charge adds 111 extra electron.

Thus, total valence electrons are 5+12+1=18.5 + 12 + 1 = 18.5+12+1=18.

  1. Draw the Lewis structure

The nitrite ion has nitrogen as the central atom: O−N−O\mathrm{O-N-O}O−N−O

To satisfy octets, one common Lewis structure is:

  • one N=O\mathrm{N=O}N=O double bond,
  • one N−O−\mathrm{N-O^-}N−O− single bond,
  • one lone pair on nitrogen.

There are resonance structures, but in each Lewis structure nitrogen has:

  • one double bond ⇒4\Rightarrow 4⇒4 electrons around N,
  • one single bond ⇒2\Rightarrow 2⇒2 electrons around N,
  • one lone pair ⇒2\Rightarrow 2⇒2 electrons around N.
  1. Count electrons around nitrogen

So total number of valence electrons around nitrogen is 4+2+2=8.4 + 2 + 2 = 8.4+2+2=8.

Hence, nitrogen satisfies the octet.

Final integer answer: 8\boxed{8}8​

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