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Chemical Bonding and Molecular Structure question

2021 · 20 Jul · Shift 1 · Q12
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Chemical Bonding and Molecular Structure question

2021 · 20 Jul · Shift 1 · Q12

JEE MainChemistryChemical Bonding and Molecular StructureNumerical+4 / −1
The number of lone pairs of electrons on the central I atom in I 3−_3^ -3−​ is ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 3

  1. Count total valence electrons in I3−I_3^-I3−​:

    • Each iodine atom has 777 valence electrons.
    • For 333 iodine atoms: 3×7=213 \times 7 = 213×7=21
    • The negative charge adds 111 extra electron.

    Hence, total valence electrons: 21+1=2221 + 1 = 2221+1=22

  2. Choose the central atom:

    In I3−I_3^-I3−​, one iodine is the central atom and the other two are terminal atoms.

  3. Form two single bonds between central iodine and the two terminal iodines:

    • Two I−II-II−I bonds use 2×2=42 \times 2 = 42×2=4 electrons.

    Remaining electrons: 22−4=1822 - 4 = 1822−4=18

  4. Complete octets of terminal iodine atoms:

    • Each terminal iodine needs 666 more electrons as lone-pair electrons after forming one bond.
    • For two terminal iodines: 2×6=122 \times 6 = 122×6=12 electrons.

    Remaining electrons: 18−12=618 - 12 = 618−12=6

  5. Place remaining electrons on central iodine:

    • The remaining 666 electrons stay on the central iodine.
    • 666 electrons correspond to: 62=3 lone pairs\frac{6}{2} = 3 \text{ lone pairs}26​=3 lone pairs
  6. Answer:

    The number of lone pairs on the central iodine atom in I3−I_3^-I3−​ is: 3\boxed{3}3​

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