JEE MainChemistryChemical Bonding and Molecular StructureNumerical+4 / −1
The number of species from the following which have square pyramidal structure is
Numerical answer
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Correct answer: 3
- Use VSEPR to determine shape of each species
Square pyramidal geometry generally arises for steric number with arrangement : This gives an octahedral electron-pair geometry and a square pyramidal molecular shape.
We now check each species.
Central atom:
Valence electrons on
It forms bonds and has no lone pair.
So it is: Geometry = trigonal bipyramidal, not square pyramidal.
❌ Not counted.
Central atom:
Valence electrons on , plus extra for negative charge electrons.
It forms bonds, leaving lone pairs on Br.
So:
Electron pair geometry = octahedral
Molecular shape = square planar.
❌ Not counted.
Central atom:
Valence electrons on
Forms bonds, leaving lone pair. So: Electron pair geometry = octahedral
Molecular shape = square pyramidal.
✅ Counted.
Central atom:
Valence electrons on
Forms bonds, leaving lone pair. So: Molecular shape = square pyramidal.
✅ Counted.
Central atom:
Valence electrons on .
Around Xe: one double bond, four single bonds, and one lone pair.
In VSEPR, the double bond counts as one electron domain.
Thus total electron domains around Xe:
So:
Molecular shape = square pyramidal.
✅ Counted.
Central atom:
Valence electrons on , plus extra due to charge .
Forms bonds, leaving lone pairs. So: Molecular shape = square planar.
❌ Not counted.
- Total number of square pyramidal species
Square pyramidal species are:
Hence, total number is:
- Comparison with stored correct answer
Stored correct answer =
Derived answer =
So the answer agrees with the stored correct answer.
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