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Chemical Bonding and Molecular Structure question

2025 · 4 Apr · Shift 2 · Q1
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Chemical Bonding and Molecular Structure question

2025 · 4 Apr · Shift 2 · Q1

JEE MainChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
Given below are two statements: Statement (I): For JEE Main 2025 (Online) 4th April Evening Shift Chemistry - Chemical Bonding & Molecular Structure Question 4 English 1, all three possible structures may be drawn as follows. JEE Main 2025 (Online) 4th April Evening Shift Chemistry - Chemical Bonding & Molecular Structure Question 4 English 2Statement (II): Structure III is most stable, as the orbitals having the lone pairs are axial, where the lp – bp repulsion is minimum. In the light of the above statements, choose the most appropriate answer from the options given below:
  1. A
    Both Statement I and Statement II are correct
  2. B
    Both Statement I and Statement II are incorrect
  3. C
    Statement I is correct but Statement II is incorrect
  4. D
    Statement I is incorrect but Statement II is correct
View written solutionFree

Correct answer: C

  1. Interpretation of the question

The species referred to is an AX3_33​E2_22​ type species (such as ClF3\mathrm{ClF_3}ClF3​-type electron arrangement), where the electron-pair geometry is trigonal bipyramidal.

In a trigonal bipyramidal arrangement:

  • there are 2 axial positions,
  • there are 3 equatorial positions.

The important repulsion order is: lp-lp>lp-bp>bp-bp\text{lp-lp} > \text{lp-bp} > \text{bp-bp}lp-lp>lp-bp>bp-bp And among positions:

  • an axial position has 3 equatorial neighbors at 90∘90^\circ90∘,
  • an equatorial position has only 2 axial neighbors at 90∘90^\circ90∘.

So lone pairs prefer equatorial positions because that minimizes 90∘90^\circ90∘ repulsions.


  1. Check Statement I

Statement I says that all three possible structures may be drawn.

For a trigonal bipyramidal arrangement with two lone pairs, the three positional possibilities are:

  1. both lone pairs axial,
  2. one axial and one equatorial,
  3. both equatorial.

These are indeed the three possible ways of placing two lone pairs in a trigonal bipyramidal set of five positions.

So Statement I is correct.


  1. Check Statement II

Statement II says structure III is most stable because the orbitals having lone pairs are axial, where lp-bp repulsion is minimum.

This is incorrect.

Why?

In trigonal bipyramidal geometry:

  • lone pairs are most stable at equatorial positions, not axial.
  • equatorial positions experience fewer 90∘90^\circ90∘ interactions.

Thus, the most stable structure is the one with lone pairs in equatorial positions.

Therefore, the reason given in Statement II is wrong.

So Statement II is incorrect.


  1. Conclusion
  • Statement I: Correct
  • Statement II: Incorrect

Hence, the correct option is: C\boxed{\text{C}}C​


  1. Comparison with stored answer

Stored correct answer: C

My derived answer: C

They match.

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