, all three possible structures may be drawn as follows.
Statement (II): Structure III is most stable, as the orbitals having the lone pairs are axial, where the lp – bp repulsion is minimum. In the light of the above statements, choose the most appropriate answer from the options given below:- ABoth Statement I and Statement II are correct
- BBoth Statement I and Statement II are incorrect
- CStatement I is correct but Statement II is incorrect
- DStatement I is incorrect but Statement II is correct
View written solutionFree
Correct answer: C
- Interpretation of the question
The species referred to is an AXE type species (such as -type electron arrangement), where the electron-pair geometry is trigonal bipyramidal.
In a trigonal bipyramidal arrangement:
- there are 2 axial positions,
- there are 3 equatorial positions.
The important repulsion order is: And among positions:
- an axial position has 3 equatorial neighbors at ,
- an equatorial position has only 2 axial neighbors at .
So lone pairs prefer equatorial positions because that minimizes repulsions.
- Check Statement I
Statement I says that all three possible structures may be drawn.
For a trigonal bipyramidal arrangement with two lone pairs, the three positional possibilities are:
- both lone pairs axial,
- one axial and one equatorial,
- both equatorial.
These are indeed the three possible ways of placing two lone pairs in a trigonal bipyramidal set of five positions.
So Statement I is correct.
- Check Statement II
Statement II says structure III is most stable because the orbitals having lone pairs are axial, where lp-bp repulsion is minimum.
This is incorrect.
Why?
In trigonal bipyramidal geometry:
- lone pairs are most stable at equatorial positions, not axial.
- equatorial positions experience fewer interactions.
Thus, the most stable structure is the one with lone pairs in equatorial positions.
Therefore, the reason given in Statement II is wrong.
So Statement II is incorrect.
- Conclusion
- Statement I: Correct
- Statement II: Incorrect
Hence, the correct option is:
- Comparison with stored answer
Stored correct answer: C
My derived answer: C
They match.
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