JEE MainChemistryChemical Bonding and Molecular StructureNumerical+4 / −1
Amongst the following, the number of species having the linear shape is . and
Numerical answer
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Correct answer: 5
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We check the shape of each species using VSEPR / known molecular geometry.
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Analyze one by one:
(i)
- Central atom: Xe
- Xe has 5 electron pairs around it: bond pairs + lone pairs
- Electron pair geometry: trigonal bipyramidal
- Lone pairs occupy equatorial positions, so the molecular shape is linear.
(ii)
- Total valence electrons
- Structure is analogous to a central I bonded to two I atoms with lone pairs on central atom
- Steric number on central I
- Electron pair geometry: tetrahedral
- Molecular shape: bent (V-shaped), not linear.
(iii)
- Carbon suboxide structure:
- Each central carbon is hybridized
- Entire molecule is linear.
(iv)
- Central I has bond pairs and lone pairs
- Trigonal bipyramidal electron arrangement
- Molecular shape: linear.
(v)
- Central C has two electron domains
- hybridized
- Shape: linear.
(vi)
- Central S has three electron domains ( bonds + lone pair)
- Trigonal planar electron arrangement
- Molecular shape: bent, not linear.
(vii)
- Central Be has two bond pairs and no lone pair
- hybridized
- Shape: linear.
(viii)
- Valence electrons:
- Central B has two bond pairs and one lone pair
- Steric number
- Electron pair geometry: trigonal planar
- Molecular shape: bent, not linear.
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Linear species are:
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Total number of linear species:
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