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Chemical Bonding and Molecular Structure question

2021 · 17 Mar · Shift 2 · Q4
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Chemical Bonding and Molecular Structure question

2021 · 17 Mar · Shift 2 · Q4

JEE MainChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
Amongst the following, the linear species is :
  1. A
    O3O_3O3​
  2. B
    Cl2OCl_2OCl2​O
  3. C
    N 3−_3^ -3−​
  4. D
    NO2NO_2NO2​
View written solutionFree

Correct answer: C

  1. We need to identify which species has a linear geometry.

  2. Check each option using VSEPR / known molecular shape:

    A: O3O_3O3​ (ozone)

    • Central O atom has two bond pairs and one lone pair.
    • Electron pair geometry is trigonal planar, but molecular shape is bent.
    • So, O3O_3O3​ is not linear.

    B: Cl2OCl_2OCl2​O

    • Structure is Cl−O−ClCl-O-ClCl−O−Cl with oxygen as the central atom.
    • Oxygen has two bond pairs and two lone pairs.
    • Hence shape is bent, like H2OH_2OH2​O.
    • So, Cl2OCl_2OCl2​O is not linear.

    C: N3−N_3^-N3−​ (azide ion)

    • Total valence electrons: 3×5+1=163\times 5 + 1 = 163×5+1=16
    • The ion is represented by resonance structures such as: −N=N+=N−^-N=N^+=N^-−N=N+=N−
    • The central nitrogen has two regions of electron density and no lone pair causing bending.
    • Hence the geometry is linear with bond angle 180∘180^\circ180∘.
    • So, N3−N_3^-N3−​ is linear.

    D: NO2NO_2NO2​

    • Nitrogen dioxide has an odd number of electrons.
    • Around N, arrangement leads to a bent molecule.
    • So, NO2NO_2NO2​ is not linear.
  3. Therefore, the only linear species is: N3−\boxed{N_3^-}N3−​​

  4. Comparing with the stored correct answer: stored answer is C, which matches our result.

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