JEE MainChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
The correct statement about and is
- Ais square pyramidal and is square planar.
- Bis trigonal bipyramidal and is tetrahedral.
- Cis square pyramidal and is tetrahedral
- DBoth are isostructural.
View written solutionFree
Correct answer: A
- Find the central atom and count valence electrons
Both species have iodine as the central atom.
- Iodine has valence electrons.
- Each chlorine forms one single bond with iodine.
- Structure of
For :
- Central iodine forms bonds with chlorine atoms.
- So iodine uses electron pairs in bonding.
- Since iodine starts with valence electrons, after forming bonds, one lone pair remains on iodine.
Thus, around iodine there are:
According to VSEPR, electron pairs give an octahedral electron pair geometry. With one lone pair, the molecular shape becomes square pyramidal.
So,
- Structure of
For :
- Iodine has valence electrons.
- Negative charge adds more electron.
- Total on iodine side effectively becomes electrons.
- It forms bonds with chlorine atoms.
So around iodine:
- bond pairs
- Remaining electrons give lone pairs
Hence total electron pairs around iodine are:
Again, electron pair geometry is octahedral. With two lone pairs placed opposite each other, the molecular shape is square planar.
So,
- Check the options
- A: square pyramidal and square planar ✅
- B: trigonal bipyramidal and tetrahedral ❌
- C: square pyramidal and tetrahedral ❌
- D: Both are isostructural ❌
- Final answer
The correct option is:
- Comparison with stored correct answer
Stored correct answer:
My derived answer:
They match.
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