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Chemical Bonding and Molecular Structure question

2019 · 8 Apr · Shift 2 · Q6
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Chemical Bonding and Molecular Structure question

2019 · 8 Apr · Shift 2 · Q6

JEE MainChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
The correct statement about ICl5ICl_5ICl5​ and ICl4−ICl_4^-ICl4−​ is
  1. A
    ICl5ICl_5ICl5​ is square pyramidal and ICl4−ICl_4^-ICl4−​ is square planar.
  2. B
    ICl5ICl_5ICl5​ is trigonal bipyramidal and is tetrahedral.
  3. C
    ICl5ICl_5ICl5​ is square pyramidal and ICl4−ICl_4^-ICl4−​ is tetrahedral
  4. D
    Both are isostructural.
View written solutionFree

Correct answer: A

  1. Find the central atom and count valence electrons

Both species have iodine as the central atom.

  • Iodine has 777 valence electrons.
  • Each chlorine forms one single bond with iodine.

  1. Structure of ICl5ICl_5ICl5​

For ICl5ICl_5ICl5​:

  • Central iodine forms 555 bonds with 555 chlorine atoms.
  • So iodine uses 555 electron pairs in bonding.
  • Since iodine starts with 777 valence electrons, after forming 555 bonds, one lone pair remains on iodine.

Thus, around iodine there are: 5 bond pairs+1 lone pair=6 electron pairs5\text{ bond pairs} + 1\text{ lone pair} = 6\text{ electron pairs}5 bond pairs+1 lone pair=6 electron pairs

According to VSEPR, 666 electron pairs give an octahedral electron pair geometry. With one lone pair, the molecular shape becomes square pyramidal.

So, ICl5 is square pyramidal.ICl_5 \text{ is square pyramidal.}ICl5​ is square pyramidal.


  1. Structure of ICl4−ICl_4^-ICl4−​

For ICl4−ICl_4^-ICl4−​:

  • Iodine has 777 valence electrons.
  • Negative charge adds 111 more electron.
  • Total on iodine side effectively becomes 888 electrons.
  • It forms 444 bonds with 444 chlorine atoms.

So around iodine:

  • 444 bond pairs
  • Remaining electrons give 222 lone pairs

Hence total electron pairs around iodine are: 4 bond pairs+2 lone pairs=6 electron pairs4\text{ bond pairs} + 2\text{ lone pairs} = 6\text{ electron pairs}4 bond pairs+2 lone pairs=6 electron pairs

Again, electron pair geometry is octahedral. With two lone pairs placed opposite each other, the molecular shape is square planar.

So, ICl4− is square planar.ICl_4^- \text{ is square planar.}ICl4−​ is square planar.


  1. Check the options
  • A: ICl5ICl_5ICl5​ square pyramidal and ICl4−ICl_4^-ICl4−​ square planar ✅
  • B: ICl5ICl_5ICl5​ trigonal bipyramidal and ICl4−ICl_4^-ICl4−​ tetrahedral ❌
  • C: ICl5ICl_5ICl5​ square pyramidal and ICl4−ICl_4^-ICl4−​ tetrahedral ❌
  • D: Both are isostructural ❌

  1. Final answer

The correct option is: A\boxed{A}A​


  1. Comparison with stored correct answer

Stored correct answer: AAA

My derived answer: AAA

They match.

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