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Chemical Bonding and Molecular Structure question

2024 · 27 Jan · Shift 1 · Q29
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Chemical Bonding and Molecular Structure question

2024 · 27 Jan · Shift 1 · Q29

JEE MainChemistryChemical Bonding and Molecular StructureNumerical+4 / −1
Sum of bond order of CO and NO +^++ is ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 6

  1. Find total electrons in each species

    • For CO:

      • Carbon has 666 electrons
      • Oxygen has 888 electrons
      • Total =6+8=14= 6+8 = 14=6+8=14
    • For NO+NO^+NO+:

      • Nitrogen has 777 electrons
      • Oxygen has 888 electrons
      • Positive charge means one electron removed
      • Total =7+8−1=14= 7+8-1 = 14=7+8−1=14

    So, both CO and NO+NO^+NO+ are isoelectronic with 141414 electrons.

  2. Use molecular orbital idea for 14-electron diatomic species

    Species with 141414 total electrons like N2N_2N2​, CO, and NO+NO^+NO+ have the same valence MO filling pattern and hence the same bond order.

    For such species, Bond order=Nb−Na2\text{Bond order} = \frac{N_b - N_a}{2}Bond order=2Nb​−Na​​ where NbN_bNb​ = number of bonding electrons and NaN_aNa​ = number of antibonding electrons.

  3. Bond order of CO

    CO is isoelectronic with N2N_2N2​, so its bond order is 333

  4. Bond order of NO+NO^+NO+

    NO+NO^+NO+ is also isoelectronic with N2N_2N2​, so its bond order is 333

  5. Sum of bond orders

    3+3=63 + 3 = 63+3=6

Therefore, the required sum is 6\boxed{6}6​

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