- A
- BNO
- C
- D
View written solutionFree
Correct answer: A
- Idea used: Molecular Orbital (MO) theory
A molecule will be stabilized by anion formation if adding one electron increases its bond order, i.e. the added electron goes into a bonding MO rather than an antibonding MO.
Bond order is
where = number of electrons in bonding MOs and = number of electrons in antibonding MOs.
We check each species.
- Option A:
For (12 total electrons; valence electrons = 8), for B–C–N type ordering:
The next MO is , which is a bonding MO and is empty in .
Bond order of :
On forming , one electron enters the bonding MO, so bond order becomes
So anion formation stabilizes .
- Option B:
has 11 valence electrons. Its highest occupied MO contains one electron in a antibonding orbital.
Bond order of is:
On forming , the added electron goes into the same antibonding orbital, so bond order decreases:
Thus anion formation does not stabilize .
- Option C:
For , the valence MO configuration ends as
Bond order of :
On forming , the extra electron goes into a antibonding MO, so
Hence anion formation reduces stability.
- Option D:
For , bond order is
The added electron in goes into the next available antibonding MO, so bond order becomes
Again, anion formation decreases stability.
- Conclusion
Only in does the added electron enter a bonding MO and increase bond order.
Therefore, the molecule expected to be stabilized by anion formation is:
So the correct option is A.
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