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Chemical Bonding and Molecular Structure question

2019 · 9 Apr · Shift 1 · Q12
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Chemical Bonding and Molecular Structure question

2019 · 9 Apr · Shift 1 · Q12

JEE MainChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
Among the following, the molecule expected to be stabilized by anion formation is : C2C_2C2​, O2O_2O2​, NONONO, F2F_2F2​
  1. A
    C2C_2C2​
  2. B
    NO
  3. C
    O2O_2O2​
  4. D
    F2F_2F2​
View written solutionFree

Correct answer: A

  1. Idea used: Molecular Orbital (MO) theory
    A molecule will be stabilized by anion formation if adding one electron increases its bond order, i.e. the added electron goes into a bonding MO rather than an antibonding MO.

Bond order is

B.O.=Nb−Na2\text{B.O.} = \frac{N_b - N_a}{2}B.O.=2Nb​−Na​​

where NbN_bNb​ = number of electrons in bonding MOs and NaN_aNa​ = number of electrons in antibonding MOs.

We check each species.


  1. Option A: C2C_2C2​
    For C2C_2C2​ (12 total electrons; valence electrons = 8), for B–C–N type ordering:
σ(2s)2 σ∗(2s)2 π(2px)2=π(2py)2\sigma(2s)^2\,\sigma^*(2s)^2\,\pi(2p_x)^2=\pi(2p_y)^2σ(2s)2σ∗(2s)2π(2px​)2=π(2py​)2

The next MO is σ(2p)\sigma(2p)σ(2p), which is a bonding MO and is empty in C2C_2C2​.

Bond order of C2C_2C2​:

B.O.=2\text{B.O.} = 2B.O.=2

On forming C2−C_2^-C2−​, one electron enters the bonding σ(2p)\sigma(2p)σ(2p) MO, so bond order becomes

B.O.=2+12=2.5\text{B.O.} = 2 + \frac{1}{2} = 2.5B.O.=2+21​=2.5

So anion formation stabilizes C2C_2C2​.


  1. Option B: NONONO
    NONONO has 11 valence electrons. Its highest occupied MO contains one electron in a π∗\pi^*π∗ antibonding orbital.

Bond order of NONONO is:

B.O.=2.5\text{B.O.} = 2.5B.O.=2.5

On forming NO−NO^-NO−, the added electron goes into the same π∗\pi^*π∗ antibonding orbital, so bond order decreases:

B.O.=2\text{B.O.} = 2B.O.=2

Thus anion formation does not stabilize NONONO.


  1. Option C: O2O_2O2​
    For O2O_2O2​, the valence MO configuration ends as
π∗(2px)1 π∗(2py)1\pi^*(2p_x)^1\,\pi^*(2p_y)^1π∗(2px​)1π∗(2py​)1

Bond order of O2O_2O2​:

B.O.=2\text{B.O.} = 2B.O.=2

On forming O2−O_2^-O2−​, the extra electron goes into a π∗\pi^*π∗ antibonding MO, so

B.O.=1.5\text{B.O.} = 1.5B.O.=1.5

Hence anion formation reduces stability.


  1. Option D: F2F_2F2​
    For F2F_2F2​, bond order is
B.O.=1\text{B.O.} = 1B.O.=1

The added electron in F2−F_2^-F2−​ goes into the next available σ∗(2p)\sigma^*(2p)σ∗(2p) antibonding MO, so bond order becomes

B.O.=0.5\text{B.O.} = 0.5B.O.=0.5

Again, anion formation decreases stability.


  1. Conclusion
    Only in C2C_2C2​ does the added electron enter a bonding MO and increase bond order.

Therefore, the molecule expected to be stabilized by anion formation is:

C2\boxed{C_2}C2​​

So the correct option is A.

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