JEE MainChemistryChemical Bonding and Molecular StructureNumerical+4 / −1
Chlorine reacts with hot and concentrated NaOH and produces compounds (X) and (Y). Compound (X) gives white precipitate with silver nitrate solution. The average bond order between CI and O atoms in (Y) is.
Numerical answer
View written solutionFree
Correct answer: 1.66TO1.67
- Reaction of chlorine with hot, concentrated NaOH
Chlorine reacts with hot and concentrated sodium hydroxide as:
So the products are:
- Identification of compound (X)
It is given that gives a white precipitate with silver nitrate solution.
Since:
and is a white precipitate, this confirms:
Hence,
- Structure of chlorate ion in
In sodium chlorate, the anion is .
We need the average bond order between and atoms in .
The chlorate ion has resonance structures. The major canonical forms contain:
- two double bonds
- one single bond
These single and double bonds are delocalized over the three oxygen atoms.
- Average bond order calculation
Total bond order over the three bonds:
Average bond order:
So,
For an integer-type/numerical format, the value is approximately:
- Comparison with stored correct answer
Stored correct answer: to
Our derived answer matches this range.
More from Chemical Bonding and Molecular Structure
- The dipole of , and are in the order :2020 · MCQ
- The relative strength of interionic/intermolecular forces in decreasing order is :2020 · MCQ
- The bond order and the magnetic characteristics of are :2020 · MCQ
- Arrange the following bonds according to their average bond energies in descending order : C–Cl, C–Br, C–F, C–I2020 · MCQ
- If the magnetic moment of a dioxygen species is 1.73 B.M, it may be :2020 · MCQ
- The number of sp2 hybrid orbitals in a molecule of benzene is :2020 · MCQ
- Among the following molecules / ions, which one is diamagnetic and has the shortest bond length?2019 · MCQ
- The covalent alkaline earth metal halide (X = Cl, Br, I) is :2019 · MCQ