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Chemical Bonding and Molecular Structure question

2020 · 7 Jan · Shift 1 · Q1
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Chemical Bonding and Molecular Structure question

2020 · 7 Jan · Shift 1 · Q1

JEE MainChemistryChemical Bonding and Molecular StructureNumerical+4 / −1
Chlorine reacts with hot and concentrated NaOH and produces compounds (X) and (Y). Compound (X) gives white precipitate with silver nitrate solution. The average bond order between CI and O atoms in (Y) is.
Numerical answer
View written solutionFree

Correct answer: 1.66TO1.67

  1. Reaction of chlorine with hot, concentrated NaOH

Chlorine reacts with hot and concentrated sodium hydroxide as:

3Cl2+6NaOH→5NaCl+NaClO3+3H2O3Cl_2 + 6NaOH \rightarrow 5NaCl + NaClO_3 + 3H_2O3Cl2​+6NaOH→5NaCl+NaClO3​+3H2​O

So the products are:

  • (X)=NaCl(X) = NaCl(X)=NaCl
  • (Y)=NaClO3(Y) = NaClO_3(Y)=NaClO3​
  1. Identification of compound (X)

It is given that (X)(X)(X) gives a white precipitate with silver nitrate solution.

Since:

NaCl+AgNO3→AgCl↓+NaNO3NaCl + AgNO_3 \rightarrow AgCl\downarrow + NaNO_3NaCl+AgNO3​→AgCl↓+NaNO3​

and AgClAgClAgCl is a white precipitate, this confirms:

X=NaClX = NaClX=NaCl

Hence,

Y=NaClO3Y = NaClO_3Y=NaClO3​

  1. Structure of chlorate ion in (Y)(Y)(Y)

In sodium chlorate, the anion is ClO3−ClO_3^-ClO3−​.

We need the average bond order between ClClCl and OOO atoms in ClO3−ClO_3^-ClO3−​.

The chlorate ion has resonance structures. The major canonical forms contain:

  • two Cl=OCl=OCl=O double bonds
  • one Cl−O−Cl-O^-Cl−O− single bond

These single and double bonds are delocalized over the three oxygen atoms.

  1. Average bond order calculation

Total bond order over the three Cl−OCl-OCl−O bonds:

2+2+1=52 + 2 + 1 = 52+2+1=5

Average bond order:

Average bond order=53=1.666…\text{Average bond order} = \frac{5}{3} = 1.666\ldotsAverage bond order=35​=1.666…

So,

1.67\boxed{1.67}1.67​

For an integer-type/numerical format, the value is approximately:

1.66 to 1.67\boxed{1.66 \text{ to } 1.67}1.66 to 1.67​

  1. Comparison with stored correct answer

Stored correct answer: 1.661.661.66 to 1.671.671.67

Our derived answer matches this range.

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