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Chemical Bonding and Molecular Structure question

2022 · 29 Jun · Shift 2 · Q6
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Chemical Bonding and Molecular Structure question

2022 · 29 Jun · Shift 2 · Q6

JEE MainChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
Number of lone pair(s) of electrons on central atom and the shape BrF3BrF_3BrF3​ molecule respectively, are
  1. A
    0, triangular planar.
  2. B
    1, pyramidal.
  3. C
    2, bent T-shape.
  4. D
    1, bent T-shape.
View written solutionFree

Correct answer: C

  1. Find the total valence electrons around the central atom

    In BrF3BrF_3BrF3​, the central atom is bromine (BrBrBr).

    • Bromine belongs to group 17, so it has 777 valence electrons.
    • Each fluorine also has 777 valence electrons, but for shape determination we focus on electron pairs around the central atom.
  2. Determine how many bond pairs and lone pairs are on bromine

    Bromine forms 333 single bonds with 333 fluorine atoms.

    So, out of bromine’s 777 valence electrons:

    • 333 electrons are used in forming 333 bond pairs
    • Remaining electrons on bromine =7−3=4= 7 - 3 = 4=7−3=4 electrons

    These 444 electrons form: 42=2\frac{4}{2} = 224​=2 lone pairs.

    Hence, the central atom has 2 lone pairs.

  3. Use VSEPR theory to determine the shape

    Total electron pairs around bromine:

    • Bond pairs =3= 3=3
    • Lone pairs =2= 2=2

    Thus, steric number =5= 5=5.

    For steric number 555, the electron pair geometry is trigonal bipyramidal.

    In trigonal bipyramidal arrangement, lone pairs prefer equatorial positions to minimize repulsion.

    So with 222 lone pairs in equatorial positions, the molecular shape formed by the three bonded fluorine atoms becomes T-shaped.

  4. Match with the given options

    • A: 000, triangular planar  →\,\rightarrow→ incorrect
    • B: 111, pyramidal  →\,\rightarrow→ incorrect
    • C: 222, bent T-shape  →\,\rightarrow→ correct in intent for lone pairs =2=2=2 and shape =T=T=T-shape
    • D: 111, bent T-shape  →\,\rightarrow→ incorrect

    The standard description is 2 lone pairs, T-shaped.

  5. Final answer

    C\boxed{\text{C}}C​

    because BrF3BrF_3BrF3​ has 2 lone pairs on the central atom and a T-shaped molecular geometry.

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