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Chemical Bonding and Molecular Structure question

2021 · 1 Sep · Shift 2 · Q21
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Chemical Bonding and Molecular Structure question

2021 · 1 Sep · Shift 2 · Q21

JEE MainChemistryChemical Bonding and Molecular StructureNumerical+4 / −1
The spin-only magnetic moment value of B2+B_2^ +B2+​ species is ‾\underline{\hspace{2cm}}​×\times× 10 −-− 2 BM. (Nearest integer) [Given : 3\sqrt 33​ = 1.73]
Numerical answer
View written solutionFree

Correct answer: 173

  1. Find total electrons in B2+B_2^+B2+​

    Boron has atomic number 555.

    So, neutral B2B_2B2​ has total electrons: 2×5=102 \times 5 = 102×5=10

    Therefore, B2+B_2^+B2+​ has: 10−1=9 electrons10 - 1 = 9 \text{ electrons}10−1=9 electrons

  2. Write molecular orbital filling for B2+B_2^+B2+​

    For light homonuclear diatomic molecules like B2B_2B2​, the MO order is: σ(1s)<σ∗(1s)<σ(2s)<σ∗(2s)<π(2px)=π(2py)<σ(2pz)\sigma(1s) < \sigma^*(1s) < \sigma(2s) < \sigma^*(2s) < \pi(2p_x)=\pi(2p_y) < \sigma(2p_z)σ(1s)<σ∗(1s)<σ(2s)<σ∗(2s)<π(2px​)=π(2py​)<σ(2pz​)

    Now fill 9 electrons: σ(1s)2 σ∗(1s)2 σ(2s)2 σ∗(2s)2 π(2p)1\sigma(1s)^2\, \sigma^*(1s)^2\, \sigma(2s)^2\, \sigma^*(2s)^2\, \pi(2p)^1σ(1s)2σ∗(1s)2σ(2s)2σ∗(2s)2π(2p)1

  3. Count unpaired electrons

    In π(2p)1\pi(2p)^1π(2p)1, there is 1 unpaired electron.

    So, n=1n = 1n=1

  4. Use spin-only magnetic moment formula

    μ=n(n+2) BM\mu = \sqrt{n(n+2)}\, \text{BM}μ=n(n+2)​BM

    Substituting n=1n=1n=1: μ=1(1+2)=3 BM\mu = \sqrt{1(1+2)} = \sqrt{3}\, \text{BM}μ=1(1+2)​=3​BM

    Given: 3=1.73\sqrt{3} = 1.733​=1.73

    Hence, μ=1.73 BM\mu = 1.73\, \text{BM}μ=1.73BM

  5. Match with required format

    The question asks for: ‾×10−2 BM\underline{\hspace{2cm}} \times 10^{-2} \text{ BM}​×10−2 BM

    Since 1.73 BM=173×10−2 BM1.73\, \text{BM} = 173 \times 10^{-2} \text{ BM}1.73BM=173×10−2 BM

    the required integer is: 173\boxed{173}173​

  6. Comparison with stored answer

    Derived answer = 173173173

    Stored correct answer = 173173173

    So they agree.

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