JEE MainChemistryChemical Bonding and Molecular StructureNumerical+4 / −1
The number of species having non-pyramidal shape among the following is . (A) (B) NO (C) (D) CO
Numerical answer
View written solutionFree
Correct answer: 3
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We need to count the species that are non-pyramidal among:
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Recall:
- Pyramidal shape usually means trigonal pyramidal, which occurs when the central atom has bond pairs and lone pair.
- If a species is trigonal planar, it is non-pyramidal.
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Now analyze each species using VSEPR theory.
(A)
- Central atom:
- Around sulfur, there are three regions of electron density due to three bonds.
- No lone pair on sulfur in the usual VSEPR description.
- Shape = trigonal planar.
So, is non-pyramidal.
(B)
- Central atom:
- Three bonds around nitrogen.
- No lone pair on nitrogen.
- Shape = trigonal planar.
So, is non-pyramidal.
(C)
- Central atom:
- Phosphorus has valence electrons.
- It forms three bonds and retains one lone pair.
- Thus, there are electron pairs total: tetrahedral electron geometry.
- Molecular shape = trigonal pyramidal.
So, is pyramidal, hence not counted.
(D)
- Central atom:
- Three bonds around carbon.
- No lone pair on carbon.
- Shape = trigonal planar.
So, is non-pyramidal.
- Counting non-pyramidal species:
- : yes
- : yes
- : no
- : yes
Total number of non-pyramidal species .
- Comparison with stored correct answer:
- Stored correct answer =
- Derived answer =
- They match.
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