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Chemical Bonding and Molecular Structure question

2021 · 27 Aug · Shift 2 · Q21
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Chemical Bonding and Molecular Structure question

2021 · 27 Aug · Shift 2 · Q21

JEE MainChemistryChemical Bonding and Molecular StructureNumerical+4 / −1
The number of species having non-pyramidal shape among the following is ‾\underline{\hspace{2cm}}​. (A) SO3SO_3SO3​ (B) NO 3−_3^ -3−​ (C) PCl3PCl_3PCl3​ (D) CO 32−_3^{2 - }32−​
Numerical answer
View written solutionFree

Correct answer: 3

  1. We need to count the species that are non-pyramidal among:

    • SO3SO_3SO3​
    • NO3−NO_3^-NO3−​
    • PCl3PCl_3PCl3​
    • CO32−CO_3^{2-}CO32−​
  2. Recall:

    • Pyramidal shape usually means trigonal pyramidal, which occurs when the central atom has 333 bond pairs and 111 lone pair.
    • If a species is trigonal planar, it is non-pyramidal.
  3. Now analyze each species using VSEPR theory.


(A) SO3SO_3SO3​

  • Central atom: SSS
  • Around sulfur, there are three regions of electron density due to three S−OS-OS−O bonds.
  • No lone pair on sulfur in the usual VSEPR description.
  • Shape = trigonal planar.

So, SO3SO_3SO3​ is non-pyramidal.


(B) NO3−NO_3^-NO3−​

  • Central atom: NNN
  • Three N−ON-ON−O bonds around nitrogen.
  • No lone pair on nitrogen.
  • Shape = trigonal planar.

So, NO3−NO_3^-NO3−​ is non-pyramidal.


(C) PCl3PCl_3PCl3​

  • Central atom: PPP
  • Phosphorus has 555 valence electrons.
  • It forms three P−ClP-ClP−Cl bonds and retains one lone pair.
  • Thus, there are 444 electron pairs total: tetrahedral electron geometry.
  • Molecular shape = trigonal pyramidal.

So, PCl3PCl_3PCl3​ is pyramidal, hence not counted.


(D) CO32−CO_3^{2-}CO32−​

  • Central atom: CCC
  • Three C−OC-OC−O bonds around carbon.
  • No lone pair on carbon.
  • Shape = trigonal planar.

So, CO32−CO_3^{2-}CO32−​ is non-pyramidal.


  1. Counting non-pyramidal species:
  • SO3SO_3SO3​ : yes
  • NO3−NO_3^-NO3−​ : yes
  • PCl3PCl_3PCl3​ : no
  • CO32−CO_3^{2-}CO32−​ : yes

Total number of non-pyramidal species =3= 3=3.

3\boxed{3}3​

  1. Comparison with stored correct answer:
  • Stored correct answer = 333
  • Derived answer = 333
  • They match.
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