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Chemical Bonding and Molecular Structure question

2022 · 25 Jun · Shift 1 · Q1
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Chemical Bonding and Molecular Structure question

2022 · 25 Jun · Shift 1 · Q1

JEE MainChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
Bonding in which of the following diatomic molecule(s) become(s) stronger, on the basis of MO Theory, by removal of an electron? (A) NONONO (B) N2N_2N2​ (C) O2O_2O2​ (D) C2C_2C2​ (E) B2B_2B2​ Choose the most appropriate answer from the options given below :
  1. A
    (A), (B), (C) only
  2. B
    (B), (C), (E) only
  3. C
    (A), (C) only
  4. D
    (D) only
View written solutionFree

Correct answer: C

  1. Idea used

    On removing one electron, bonding becomes stronger if the electron removed is from an antibonding molecular orbital. Then bond order increases by 12\tfrac{1}{2}21​.

    Recall: Bond order=Nb−Na2\text{Bond order} = \frac{N_b - N_a}{2}Bond order=2Nb​−Na​​ where NbN_bNb​ = number of bonding electrons, NaN_aNa​ = number of antibonding electrons.

  2. Check each molecule


    (A) NONONO

    Total electrons =7+8=15= 7+8 = 15=7+8=15.

    In NONONO, the highest occupied MO contains one electron in a π∗\pi^*π∗ antibonding orbital.

    Bond order of NONONO is: B.O.=2.5\text{B.O.} = 2.5B.O.=2.5

    If one electron is removed, it is removed from the antibonding π∗\pi^*π∗ orbital: B.O. increases from 2.5→3\text{B.O. increases from } 2.5 \to 3B.O. increases from 2.5→3

    So bonding becomes stronger.

    ✅ (A) is correct.


    (B) N2N_2N2​

    Total electrons =14= 14=14.

    MO configuration up to valence shell: σ2s2 σ∗2s2 (π2px)2(π2py)2(σ2pz)2\sigma 2s^2\, \sigma^{*}2s^2\, (\pi 2p_x)^2(\pi 2p_y)^2(\sigma 2p_z)^2σ2s2σ∗2s2(π2px​)2(π2py​)2(σ2pz​)2

    Bond order: B.O.=3\text{B.O.} = 3B.O.=3

    The highest occupied MO is σ2pz\sigma 2p_zσ2pz​, which is bonding.

    Removing one electron decreases bond order: 3→2.53 \to 2.53→2.5

    So bonding becomes weaker.

    ❌ (B) is not correct.


    (C) O2O_2O2​

    Total electrons =16= 16=16.

    MO configuration: σ2s2 σ∗2s2 σ2pz2 (π2px)2(π2py)2 (π∗2px)1(π∗2py)1\sigma 2s^2\, \sigma^{*}2s^2\, \sigma 2p_z^2\, (\pi 2p_x)^2(\pi 2p_y)^2\, (\pi^{*}2p_x)^1(\pi^{*}2p_y)^1σ2s2σ∗2s2σ2pz2​(π2px​)2(π2py​)2(π∗2px​)1(π∗2py​)1

    Bond order: B.O.=2\text{B.O.} = 2B.O.=2

    The electron removed comes from π∗\pi^*π∗ antibonding orbital.

    So: 2→2.52 \to 2.52→2.5

    Bonding becomes stronger.

    ✅ (C) is correct.


    (D) C2C_2C2​

    Total electrons =12= 12=12.

    MO configuration: σ2s2 σ∗2s2 (π2px)2(π2py)2\sigma 2s^2\, \sigma^{*}2s^2\, (\pi 2p_x)^2(\pi 2p_y)^2σ2s2σ∗2s2(π2px​)2(π2py​)2

    Bond order: B.O.=2\text{B.O.} = 2B.O.=2

    HOMO is π2p\pi 2pπ2p, which is bonding.

    Removing one electron decreases bond order: 2→1.52 \to 1.52→1.5

    Bonding becomes weaker.

    ❌ (D) is not correct.


    (E) B2B_2B2​

    Total electrons =10= 10=10.

    MO configuration: σ2s2 σ∗2s2 (π2px)1(π2py)1\sigma 2s^2\, \sigma^{*}2s^2\, (\pi 2p_x)^1(\pi 2p_y)^1σ2s2σ∗2s2(π2px​)1(π2py​)1

    Bond order: B.O.=1\text{B.O.} = 1B.O.=1

    HOMO is π2p\pi 2pπ2p, which is bonding.

    Removing one electron decreases bond order: 1→0.51 \to 0.51→0.5

    Bonding becomes weaker.

    ❌ (E) is not correct.

  3. Final selection

    Molecules whose bonding becomes stronger on removal of an electron: NO and O2NO \text{ and } O_2NO and O2​

    Therefore, the correct option is: C: (A), (C) only\boxed{\text{C: (A), (C) only}}C: (A), (C) only​

  4. Comparison with stored answer

    Stored correct answer = C.

    My derived answer also = C, so they agree.

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