- A(A), (B), (C) only
- B(B), (C), (E) only
- C(A), (C) only
- D(D) only
View written solutionFree
Correct answer: C
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Idea used
On removing one electron, bonding becomes stronger if the electron removed is from an antibonding molecular orbital. Then bond order increases by .
Recall: where = number of bonding electrons, = number of antibonding electrons.
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Check each molecule
(A)
Total electrons .
In , the highest occupied MO contains one electron in a antibonding orbital.
Bond order of is:
If one electron is removed, it is removed from the antibonding orbital:
So bonding becomes stronger.
✅ (A) is correct.
(B)
Total electrons .
MO configuration up to valence shell:
Bond order:
The highest occupied MO is , which is bonding.
Removing one electron decreases bond order:
So bonding becomes weaker.
❌ (B) is not correct.
(C)
Total electrons .
MO configuration:
Bond order:
The electron removed comes from antibonding orbital.
So:
Bonding becomes stronger.
✅ (C) is correct.
(D)
Total electrons .
MO configuration:
Bond order:
HOMO is , which is bonding.
Removing one electron decreases bond order:
Bonding becomes weaker.
❌ (D) is not correct.
(E)
Total electrons .
MO configuration:
Bond order:
HOMO is , which is bonding.
Removing one electron decreases bond order:
Bonding becomes weaker.
❌ (E) is not correct.
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Final selection
Molecules whose bonding becomes stronger on removal of an electron:
Therefore, the correct option is:
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Comparison with stored answer
Stored correct answer = C.
My derived answer also = C, so they agree.
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