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Chemical Bonding and Molecular Structure question

2021 · 24 Feb · Shift 2 · Q12
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Chemical Bonding and Molecular Structure question

2021 · 24 Feb · Shift 2 · Q12

JEE MainChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
The correct shape and I−I−II - I - II−I−I bond angles respectively in I3−I_3^ -I3−​ ion are :
  1. A
    Linear; 180 ∘^\circ∘
  2. B
    T-shaped; 180 ∘^\circ∘ and 90 ∘^\circ∘
  3. C
    Trigonal planar; 120 ∘^\circ∘
  4. D
    Distorted trigonal planar; 135 ∘^\circ∘ and 90 ∘^\circ∘
View written solutionFree

Correct answer: A

  1. Identify the central atom and count electron pairs

In I3−I_3^-I3−​, the central iodine is bonded to two terminal iodine atoms.

Total valence electrons: 3×7+1=223 \times 7 + 1 = 223×7+1=22

The central iodine forms two bond pairs with the two terminal iodines.

  1. Find lone pairs on the central atom

Using the Lewis structure, after completing octets of terminal iodines, the central iodine is left with 3 lone pairs.

So, around the central iodine, there are:

  • 222 bond pairs
  • 333 lone pairs

Thus, total electron pairs around the central atom =5= 5=5.

  1. Determine electron-pair geometry using VSEPR

For 555 electron pairs, the electron-pair geometry is trigonal bipyramidal.

In trigonal bipyramidal arrangement, lone pairs prefer equatorial positions because they experience less repulsion there.

So the 333 lone pairs occupy all three equatorial positions, leaving the two bonded iodine atoms in the two axial positions.

  1. Determine molecular shape

Since the two bonded atoms are opposite each other in axial positions, the molecular shape is: Linear\text{Linear}Linear

  1. Determine bond angle

The angle between the two axial bonds is: 180∘180^\circ180∘

Hence, the correct shape and bond angle in I3−I_3^-I3−​ are: Linear; 180∘\boxed{\text{Linear; }180^\circ}Linear; 180∘​

  1. Check options
  • A: Linear; 180∘180^\circ180∘ ✅
  • B: T-shaped; 180∘180^\circ180∘ and 90∘90^\circ90∘ ❌
  • C: Trigonal planar; 120∘120^\circ120∘ ❌
  • D: Distorted trigonal planar; 135∘135^\circ135∘ and 90∘90^\circ90∘ ❌

Therefore, the correct option is A.

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