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Chemical Bonding and Molecular Structure question

2023 · 10 Apr · Shift 1 · Q18
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Chemical Bonding and Molecular Structure question

2023 · 10 Apr · Shift 1 · Q18

JEE MainChemistryChemical Bonding and Molecular StructureNumerical+4 / −1
The sum of lone pairs present on the central atom of the interhalogen IF 5_55​ and IF 7_77​ is ‾\underline{\hspace{2cm}}​
Numerical answer
View written solutionFree

Correct answer: 1

  1. Find the valence electrons on the central atom iodine

    Iodine belongs to group 17, so it has 777 valence electrons.

  2. Lone pairs in IF5\mathrm{IF_5}IF5​

    • Central atom: I\mathrm{I}I
    • It forms 555 sigma bonds with 555 fluorine atoms.
    • Out of iodine’s 777 valence electrons, 555 are used in bonding.
    • Remaining electrons on iodine: 7−5=2 electrons7 - 5 = 2 \text{ electrons}7−5=2 electrons
    • These 222 electrons form: 1 lone pair1 \text{ lone pair}1 lone pair
  3. Lone pairs in IF7\mathrm{IF_7}IF7​

    • Central atom: I\mathrm{I}I
    • It forms 777 sigma bonds with 777 fluorine atoms.
    • All 777 valence electrons are used in bonding.
    • Remaining electrons on iodine: 7−7=07 - 7 = 07−7=0
    • So lone pairs on iodine in IF7\mathrm{IF_7}IF7​ are: 000
  4. Total lone pairs on the central atom

    1+0=11 + 0 = 11+0=1

  5. Final Answer

    The required sum is: 1\boxed{1}1​

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