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Chemical Bonding and Molecular Structure question

2024 · 4 Apr · Shift 1 · Q11
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Chemical Bonding and Molecular Structure question

2024 · 4 Apr · Shift 1 · Q11

JEE MainChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
Number of molecules/ions from the following in which the central atom is involved in sp3\mathrm{sp}^3sp3 hybridization is ‾\underline{\hspace{2cm}}​. NO3−,BCl3,ClO2−,ClO3−\mathrm{NO}_3^{-}, \mathrm{BCl}_3, \mathrm{ClO}_2^{-}, \mathrm{ClO}_3^{-}NO3−​,BCl3​,ClO2−​,ClO3−​
  1. A
    2
  2. B
    4
  3. C
    1
  4. D
    3
View written solutionFree

Correct answer: A

  1. We check the hybridization of the central atom in each species using steric number:

Steric number=number of σ-bonds+number of lone pairs on central atom\text{Steric number} = \text{number of }\sigma\text{-bonds} + \text{number of lone pairs on central atom}Steric number=number of σ-bonds+number of lone pairs on central atom

If steric number =4=4=4, then hybridization is sp3\mathrm{sp}^3sp3.


  1. Analyze each species:

(i) NO3−\mathrm{NO_3^-}NO3−​

Central atom: N\mathrm{N}N

  • Nitrogen is bonded to 3 oxygens.
  • It has 3 σ\sigmaσ-bonds and 0 lone pairs.

So, steric number:

3+0=33 + 0 = 33+0=3

Hence hybridization is:

sp2\mathrm{sp}^2sp2

So, not sp3\mathrm{sp}^3sp3.


(ii) BCl3\mathrm{BCl_3}BCl3​

Central atom: B\mathrm{B}B

  • Boron forms 3 σ\sigmaσ-bonds with 3 chlorine atoms.
  • It has 0 lone pairs.

Steric number:

3+0=33 + 0 = 33+0=3

Hence hybridization is:

sp2\mathrm{sp}^2sp2

So, not sp3\mathrm{sp}^3sp3.


(iii) ClO2−\mathrm{ClO_2^-}ClO2−​

Central atom: Cl\mathrm{Cl}Cl

Total valence electrons:

7+2(6)+1=207 + 2(6) + 1 = 207+2(6)+1=20

Structure has 2 Cl–O bonds and after completing octets, chlorine has 2 lone pairs. Thus around chlorine:

  • 2 σ\sigmaσ-bonds
  • 2 lone pairs

Steric number:

2+2=42 + 2 = 42+2=4

Hence hybridization is:

sp3\mathrm{sp}^3sp3

So, this is sp3\mathrm{sp}^3sp3.


(iv) ClO3−\mathrm{ClO_3^-}ClO3−​

Central atom: Cl\mathrm{Cl}Cl

Total valence electrons:

7+3(6)+1=267 + 3(6) + 1 = 267+3(6)+1=26

Chlorine is bonded to 3 oxygens and has 1 lone pair on the central atom. Thus around chlorine:

  • 3 σ\sigmaσ-bonds
  • 1 lone pair

Steric number:

3+1=43 + 1 = 43+1=4

Hence hybridization is:

sp3\mathrm{sp}^3sp3

So, this is sp3\mathrm{sp}^3sp3.


  1. Count species with central atom in sp3\mathrm{sp}^3sp3 hybridization:
  • NO3−\mathrm{NO_3^-}NO3−​ : No
  • BCl3\mathrm{BCl_3}BCl3​ : No
  • ClO2−\mathrm{ClO_2^-}ClO2−​ : Yes
  • ClO3−\mathrm{ClO_3^-}ClO3−​ : Yes

Therefore, number of such species is:

222

So the correct option is A.

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