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Chemical Bonding and Molecular Structure question

2019 · 10 Jan · Shift 1 · Q12
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Chemical Bonding and Molecular Structure question

2019 · 10 Jan · Shift 1 · Q12

JEE MainChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
The type of hybridisation and number of lone pair (s) of electrons of Xe in XeOF4XeOF_4XeOF4​, respectively, are:
  1. A
    sp3d and 2
  2. B
    sp3d2 and 2
  3. C
    sp3d and 1
  4. D
    sp3d2 and 1
View written solutionFree

Correct answer: D

  1. Count the valence electrons around Xe

    Xenon has 8 valence electrons.

    In XeOF4XeOF_4XeOF4​, xenon is bonded to:

    • one oxygen atom
    • four fluorine atoms
  2. Count the number of sigma bonds around Xe

    Structure of XeOF4XeOF_4XeOF4​:

    • Xe=OXe=OXe=O contributes one sigma bond and one pi bond
    • four Xe−FXe-FXe−F bonds contribute four sigma bonds

    So, total number of sigma bonds around Xe is: 1+4=51 + 4 = 51+4=5

  3. Determine lone pairs on Xe

    Xenon starts with 8 valence electrons. After forming 5 sigma bonds, one lone pair remains on Xe.

    More formally, steric number is determined by: Steric number=sigma bonds+lone pairs\text{Steric number} = \text{sigma bonds} + \text{lone pairs}Steric number=sigma bonds+lone pairs

    For XeOF4XeOF_4XeOF4​, known arrangement is octahedral electron pair geometry with: 5 bond pairs+1 lone pair=65\ \text{bond pairs} + 1\ \text{lone pair} = 65 bond pairs+1 lone pair=6

    Hence Xe has 1 lone pair.

  4. Determine hybridisation

    Since steric number =6=6=6, the hybridisation is: sp3d2sp^3d^2sp3d2

  5. Match with options

    • A: sp3dsp^3dsp3d and 2 ❌
    • B: sp3d2sp^3d^2sp3d2 and 2 ❌
    • C: sp3dsp^3dsp3d and 1 ❌
    • D: sp3d2sp^3d^2sp3d2 and 1 ✅

Therefore, the correct answer is D.

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