JEE MainChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
The type of hybridisation and number of lone pair (s) of electrons of Xe in , respectively, are:
- Asp3d and 2
- Bsp3d2 and 2
- Csp3d and 1
- Dsp3d2 and 1
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Correct answer: D
-
Count the valence electrons around Xe
Xenon has 8 valence electrons.
In , xenon is bonded to:
- one oxygen atom
- four fluorine atoms
-
Count the number of sigma bonds around Xe
Structure of :
- contributes one sigma bond and one pi bond
- four bonds contribute four sigma bonds
So, total number of sigma bonds around Xe is:
-
Determine lone pairs on Xe
Xenon starts with 8 valence electrons. After forming 5 sigma bonds, one lone pair remains on Xe.
More formally, steric number is determined by:
For , known arrangement is octahedral electron pair geometry with:
Hence Xe has 1 lone pair.
-
Determine hybridisation
Since steric number , the hybridisation is:
-
Match with options
- A: and 2 ❌
- B: and 2 ❌
- C: and 1 ❌
- D: and 1 ✅
Therefore, the correct answer is D.
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