JEE MainChemistryChemical Bonding and Molecular StructureNumerical+4 / −1
Total number of species from the following with central atom utilising hybrid orbitals for bonding is .
Numerical answer
View written solutionFree
Correct answer: 6
-
We need species in which the central atom uses hybrid orbitals for bonding.
Recall:
- hybridisation steric number
- Geometry around central atom is usually trigonal planar.
-
Check each species one by one
(i)
- Central atom: N
- Bonds = 3, lone pair = 1
- Steric number
- Hybridisation
- Not counted
(ii)
- Central atom: S
- Around S: two bonds + one lone pair
- Steric number
- Hybridisation
- Counted
(iii)
- Molecular form is
- Central atom: Si
- Two regions of electron density
- Hybridisation
- Not counted
(iv)
- Central atom: Be
- Two bonds
- Steric number
- Hybridisation
- Not counted
(v)
- Each C has two regions of electron density
- Hybridisation of C
- Not counted
(vi)
- Each C forms three bonds
- Hybridisation of each C
- Counted
(vii)
- Central atom: B
- Three bonds, no lone pair
- Steric number
- Hybridisation
- Counted
(viii) (formaldehyde)
- Central atom: C
- Around C: two C-H bonds + one C=O sigma bond
- Steric number
- Hybridisation
- Counted
(ix)
- In benzene, each carbon is trigonal planar
- Each C is hybridised
- Counted
(x)
- Central atom: B
- Three bonds
- Hybridisation
- Counted
(xi)
- This is saturated (e.g. )
- Each carbon forms four single bonds
- Hybridisation of each C
- Not counted
-
Total counted species
Counted species are:
Therefore, total number of species is
-
Comparison with stored answer
Stored correct answer = .
Our derived answer also = .
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