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Chemical Bonding and Molecular Structure question

2024 · 6 Apr · Shift 2 · Q29
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Chemical Bonding and Molecular Structure question

2024 · 6 Apr · Shift 2 · Q29

JEE MainChemistryChemical Bonding and Molecular StructureNumerical+4 / −1
Total number of species from the following with central atom utilising sp2\mathrm{sp}^2sp2 hybrid orbitals for bonding is ‾\underline{\hspace{2cm}}​. NH3,SO2,SiO2,BeCl2,C2H2,C2H4,BCl3,HCHO,C6H6,BF3,C2H4Cl2\mathrm{NH}_3, \mathrm{SO}_2, \mathrm{SiO}_2, \mathrm{BeCl}_2, \mathrm{C}_2 \mathrm{H}_2, \mathrm{C}_2 \mathrm{H}_4, \mathrm{BCl}_3, \mathrm{HCHO}, \mathrm{C}_6 \mathrm{H}_6, \mathrm{BF}_3, \mathrm{C}_2 \mathrm{H}_4 \mathrm{Cl}_2NH3​,SO2​,SiO2​,BeCl2​,C2​H2​,C2​H4​,BCl3​,HCHO,C6​H6​,BF3​,C2​H4​Cl2​
Numerical answer
View written solutionFree

Correct answer: 6

  1. We need species in which the central atom uses sp2sp^2sp2 hybrid orbitals for bonding.

    Recall:

    • sp2sp^2sp2 hybridisation ightarrow ightarrowightarrow steric number 333
    • Geometry around central atom is usually trigonal planar.
  2. Check each species one by one

    (i) NH3\mathrm{NH_3}NH3​

    • Central atom: N
    • Bonds = 3, lone pair = 1
    • Steric number =4=4=4
    • Hybridisation =sp3= sp^3=sp3
    • Not counted

    (ii) SO2\mathrm{SO_2}SO2​

    • Central atom: S
    • Around S: two σ\sigmaσ bonds + one lone pair
    • Steric number =3=3=3
    • Hybridisation =sp2= sp^2=sp2
    • Counted

    (iii) SiO2\mathrm{SiO_2}SiO2​

    • Molecular form is O=Si=O\mathrm{O=Si=O}O=Si=O
    • Central atom: Si
    • Two regions of electron density
    • Hybridisation =sp= sp=sp
    • Not counted

    (iv) BeCl2\mathrm{BeCl_2}BeCl2​

    • Central atom: Be
    • Two σ\sigmaσ bonds
    • Steric number =2=2=2
    • Hybridisation =sp= sp=sp
    • Not counted

    (v) C2H2\mathrm{C_2H_2}C2​H2​

    • Each C has two regions of electron density
    • Hybridisation of C =sp= sp=sp
    • Not counted

    (vi) C2H4\mathrm{C_2H_4}C2​H4​

    • Each C forms three σ\sigmaσ bonds
    • Hybridisation of each C =sp2= sp^2=sp2
    • Counted

    (vii) BCl3\mathrm{BCl_3}BCl3​

    • Central atom: B
    • Three σ\sigmaσ bonds, no lone pair
    • Steric number =3=3=3
    • Hybridisation =sp2= sp^2=sp2
    • Counted

    (viii) HCHO\mathrm{HCHO}HCHO (formaldehyde)

    • Central atom: C
    • Around C: two C-H σ\sigmaσ bonds + one C=O sigma bond
    • Steric number =3=3=3
    • Hybridisation =sp2= sp^2=sp2
    • Counted

    (ix) C6H6\mathrm{C_6H_6}C6​H6​

    • In benzene, each carbon is trigonal planar
    • Each C is sp2sp^2sp2 hybridised
    • Counted

    (x) BF3\mathrm{BF_3}BF3​

    • Central atom: B
    • Three σ\sigmaσ bonds
    • Hybridisation =sp2= sp^2=sp2
    • Counted

    (xi) C2H4Cl2\mathrm{C_2H_4Cl_2}C2​H4​Cl2​

    • This is saturated (e.g. ClCH2−CH2Cl\mathrm{ClCH_2-CH_2Cl}ClCH2​−CH2​Cl)
    • Each carbon forms four single bonds
    • Hybridisation of each C =sp3= sp^3=sp3
    • Not counted
  3. Total counted species

    Counted species are: SO2, C2H4, BCl3, HCHO, C6H6, BF3\mathrm{SO_2,\, C_2H_4,\, BCl_3,\, HCHO,\, C_6H_6,\, BF_3}SO2​,C2​H4​,BCl3​,HCHO,C6​H6​,BF3​

    Therefore, total number of species is 666

  4. Comparison with stored answer

    Stored correct answer = 666.

    Our derived answer also = 666.

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