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Chemical Bonding and Molecular Structure question

2020 · 6 Sep · Shift 1 · Q1
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Chemical Bonding and Molecular Structure question

2020 · 6 Sep · Shift 1 · Q1

JEE MainChemistryChemical Bonding and Molecular StructureNumerical+4 / −1
The number of Cl = O bonds in perchloric acid is, "‾\underline{\hspace{2cm}}​".
Numerical answer
View written solutionFree

Correct answer: 3

  1. Write the formula of perchloric acid

    Perchloric acid is HClO4\mathrm{HClO_4}HClO4​.

  2. Draw its bonding pattern

    In oxyacids of chlorine, the hydrogen is attached to oxygen, so the structure is of the type:

    HO−ClO3\mathrm{HO{-}ClO_3}HO−ClO3​

    To minimize formal charges, chlorine forms:

    • one single bond with the −OH\mathrm{-OH}−OH oxygen,
    • and three double bonds with the other three oxygens.

    So the structure is:

    HO−Cl(=O)3\mathrm{HO{-}Cl(=O)_3}HO−Cl(=O)3​

  3. Count the number of Cl=O\mathrm{Cl=O}Cl=O bonds

    From the above structure, there are three Cl=O\mathrm{Cl=O}Cl=O double bonds.

  4. Final answer

    3\boxed{3}3​

  5. Comparison with stored correct answer

    Stored correct answer = 333

    Our derived answer = 333

    Hence, the answer agrees with the stored correct answer.

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