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Correct answer: 1
- Interpret the question
We need to count how many of the given halides are inert to hydrolysis (i.e. they do not undergo hydrolysis with water).
The compounds are:
- (A)
- (B)
- (C)
- (D)
- Check each compound one by one
(A)
Although boron is electron deficient, is resistant/inert to hydrolysis compared to other boron halides because of strong - back bonding between and . This gives the bond partial double bond character and makes it difficult for water to hydrolyse it.
So, is taken as inert to hydrolysis.
(B)
is readily hydrolysed by water:
So, is not inert to hydrolysis.
(C)
also undergoes hydrolysis:
First step:
Further hydrolysis:
Overall, it is clearly not inert to hydrolysis.
(D)
is extremely stable and inert to hydrolysis because sulfur is sterically shielded by six fluorine atoms and the bonds are very strong.
So, is inert to hydrolysis.
- Count the inert halides
Inert to hydrolysis:
Therefore, the number of halides inert to hydrolysis is
- Compare with stored correct answer
Stored correct answer =
Our derived answer =
These do not match.
The likely reason is that some sources emphasize that can hydrolyse under suitable conditions, but in standard JEE-level inorganic chemistry, is commonly treated as inert/resistant to hydrolysis due to strong back bonding, just like other fluorides that resist hydrolysis compared with chlorides. Hence should be counted here along with .
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