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Chemical Bonding and Molecular Structure question

2022 · 27 Jul · Shift 1 · Q16
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Chemical Bonding and Molecular Structure question

2022 · 27 Jul · Shift 1 · Q16

JEE MainChemistryChemical Bonding and Molecular StructureNumerical+4 / −1
Amongst the following, the number of oxide(s) which are paramagnetic in nature is Na2O,KO2,NO2, N2O,ClO2,NO,SO2,Cl2O\mathrm{Na}_{2} \mathrm{O}, \mathrm{KO}_{2}, \mathrm{NO}_{2}, \mathrm{~N}_{2} \mathrm{O}, \mathrm{ClO}_{2}, \mathrm{NO}, \mathrm{SO}_{2}, \mathrm{Cl}_{2} \mathrm{O}Na2​O,KO2​,NO2​, N2​O,ClO2​,NO,SO2​,Cl2​O
Numerical answer
View written solutionFree

Correct answer: 4

  1. We need to count how many of the given oxides are paramagnetic.

  2. A species is paramagnetic if it has one or more unpaired electrons.

  3. Now check each oxide one by one:


(i) Na2O\mathrm{Na_2O}Na2​O

  • This is an ionic oxide: Na+\mathrm{Na^+}Na+ and O2−\mathrm{O^{2-}}O2−.
  • O2−\mathrm{O^{2-}}O2− has completely filled orbitals.
  • Hence, diamagnetic.

(ii) KO2\mathrm{KO_2}KO2​

  • This is potassium superoxide: K+O2−\mathrm{K^+O_2^-}K+O2−​.
  • The superoxide ion O2−\mathrm{O_2^-}O2−​ has one unpaired electron.
  • Hence, paramagnetic.

(iii) NO2\mathrm{NO_2}NO2​

  • Total valence electrons: 5+2×6=175 + 2\times 6 = 175+2×6=17
  • Odd-electron molecule, so it has one unpaired electron.
  • Hence, paramagnetic.

(iv) N2O\mathrm{N_2O}N2​O

  • Total valence electrons: 2×5+6=162\times 5 + 6 = 162×5+6=16
  • Even-electron molecule; usual Lewis structures show all electrons paired.
  • Hence, diamagnetic.

(v) ClO2\mathrm{ClO_2}ClO2​

  • Total valence electrons: 7+2×6=197 + 2\times 6 = 197+2×6=19
  • Odd-electron molecule, so it has one unpaired electron.
  • Hence, paramagnetic.

(vi) NO\mathrm{NO}NO

  • Total valence electrons: 5+6=115 + 6 = 115+6=11
  • Odd-electron molecule, so it has one unpaired electron.
  • Hence, paramagnetic.

(vii) SO2\mathrm{SO_2}SO2​

  • Total valence electrons: 6+2×6=186 + 2\times 6 = 186+2×6=18
  • All electrons are paired in the ground state.
  • Hence, diamagnetic.

(viii) Cl2O\mathrm{Cl_2O}Cl2​O

  • Total valence electrons: 2×7+6=202\times 7 + 6 = 202×7+6=20
  • All electrons are paired.
  • Hence, diamagnetic.

  1. Therefore, the paramagnetic oxides are:
  • KO2\mathrm{KO_2}KO2​
  • NO2\mathrm{NO_2}NO2​
  • ClO2\mathrm{ClO_2}ClO2​
  • NO\mathrm{NO}NO

So, the total number of paramagnetic oxides is 444

  1. Comparison with stored answer:
  • Stored correct answer = 444
  • Derived answer = 444
  • Hence, they agree.
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