JEE MainChemistryChemical Bonding and Molecular StructureNumerical+4 / −1
Amongst the following, the number of oxide(s) which are paramagnetic in nature is
Numerical answer
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Correct answer: 4
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We need to count how many of the given oxides are paramagnetic.
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A species is paramagnetic if it has one or more unpaired electrons.
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Now check each oxide one by one:
(i)
- This is an ionic oxide: and .
- has completely filled orbitals.
- Hence, diamagnetic.
(ii)
- This is potassium superoxide: .
- The superoxide ion has one unpaired electron.
- Hence, paramagnetic.
(iii)
- Total valence electrons:
- Odd-electron molecule, so it has one unpaired electron.
- Hence, paramagnetic.
(iv)
- Total valence electrons:
- Even-electron molecule; usual Lewis structures show all electrons paired.
- Hence, diamagnetic.
(v)
- Total valence electrons:
- Odd-electron molecule, so it has one unpaired electron.
- Hence, paramagnetic.
(vi)
- Total valence electrons:
- Odd-electron molecule, so it has one unpaired electron.
- Hence, paramagnetic.
(vii)
- Total valence electrons:
- All electrons are paired in the ground state.
- Hence, diamagnetic.
(viii)
- Total valence electrons:
- All electrons are paired.
- Hence, diamagnetic.
- Therefore, the paramagnetic oxides are:
So, the total number of paramagnetic oxides is
- Comparison with stored answer:
- Stored correct answer =
- Derived answer =
- Hence, they agree.
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