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Chemical Bonding and Molecular Structure question

2021 · 27 Jul · Shift 2 · Q17
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  5. /2021 · 27 Jul · Shift 2 · Q17

Chemical Bonding and Molecular Structure question

2021 · 27 Jul · Shift 2 · Q17

JEE MainChemistryChemical Bonding and Molecular StructureNumerical+4 / −1
The total number of electrons in all bonding molecular orbitals of O22−O_2^{2 - }O22−​ is ‾\underline{\hspace{2cm}}​. (Round off to the nearest integer)
Numerical answer
View written solutionFree

Correct answer: 10

  1. Find total number of electrons in O22−O_2^{2-}O22−​

Each oxygen atom has 888 electrons. So, neutral O2O_2O2​ has: 8+8=168+8=168+8=16 For O22−O_2^{2-}O22−​, add 222 more electrons: 16+2=1816+2=1816+2=18

So, O22−O_2^{2-}O22−​ has 18 electrons.

  1. Write the MO configuration for O22−O_2^{2-}O22−​

For oxygen and heavier diatomic molecules, the molecular orbital order is: σ1s, σ1s∗, σ2s, σ2s∗, σ2pz, π2px=π2py, π2px∗=π2py∗, σ2pz∗\sigma_{1s},\ \sigma_{1s}^*,\ \sigma_{2s},\ \sigma_{2s}^*,\ \sigma_{2p_z},\ \pi_{2p_x}=\pi_{2p_y},\ \pi_{2p_x}^*=\pi_{2p_y}^*,\ \sigma_{2p_z}^*σ1s​, σ1s∗​, σ2s​, σ2s∗​, σ2pz​​, π2px​​=π2py​​, π2px​∗​=π2py​∗​, σ2pz​∗​

Filling 181818 electrons: (σ1s)2(σ1s∗)2(σ2s)2(σ2s∗)2(σ2pz)2(π2px)2(π2py)2(π2px∗)2(π2py∗)2\left(\sigma_{1s}\right)^2\left(\sigma_{1s}^*\right)^2\left(\sigma_{2s}\right)^2\left(\sigma_{2s}^*\right)^2\left(\sigma_{2p_z}\right)^2\left(\pi_{2p_x}\right)^2\left(\pi_{2p_y}\right)^2\left(\pi_{2p_x}^*\right)^2\left(\pi_{2p_y}^*\right)^2(σ1s​)2(σ1s∗​)2(σ2s​)2(σ2s∗​)2(σ2pz​​)2(π2px​​)2(π2py​​)2(π2px​∗​)2(π2py​∗​)2

  1. Identify all bonding molecular orbitals

Bonding MOs occupied here are:

  • σ1s\sigma_{1s}σ1s​ : 222 electrons
  • σ2s\sigma_{2s}σ2s​ : 222 electrons
  • σ2pz\sigma_{2p_z}σ2pz​​ : 222 electrons
  • π2px\pi_{2p_x}π2px​​ : 222 electrons
  • π2py\pi_{2p_y}π2py​​ : 222 electrons

Total electrons in all bonding molecular orbitals: 2+2+2+2+2=102+2+2+2+2=102+2+2+2+2=10

  1. Final answer

The total number of electrons in all bonding molecular orbitals of O22−O_2^{2-}O22−​ is: 10\boxed{10}10​

  1. Comparison with stored answer

Stored correct answer = 101010

Our derived answer = 101010

So, the answer agrees with the stored correct answer.

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