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Chemical Bonding and Molecular Structure question

2024 · 29 Jan · Shift 2 · Q26
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  5. /2024 · 29 Jan · Shift 2 · Q26

Chemical Bonding and Molecular Structure question

2024 · 29 Jan · Shift 2 · Q26

JEE MainChemistryChemical Bonding and Molecular StructureNumerical+4 / −1
The total number of anti bonding molecular orbitals, formed from 2s2 s2s and 2p2 p2p atomic orbitals in a diatomic molecule is ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 4

  1. Atomic orbitals involved

    For each atom, the orbitals considered are:

    • one 2s2s2s orbital
    • three 2p2p2p orbitals: 2px,2py,2pz2p_x, 2p_y, 2p_z2px​,2py​,2pz​

    So, for a diatomic molecule, these atomic orbitals combine pairwise to form molecular orbitals.

  2. Formation from 2s2s2s orbitals

    Two 2s2s2s atomic orbitals combine to give:

    • one bonding MO: σ2s\sigma_{2s}σ2s​
    • one antibonding MO: σ2s∗\sigma^*_{2s}σ2s∗​

    Thus, antibonding orbitals from 2s2s2s = 111.

  3. Formation from 2p2p2p orbitals

    The three 2p2p2p orbitals from one atom combine with the three 2p2p2p orbitals from the other atom.

    • Along internuclear axis: one σ2p\sigma_{2p}σ2p​ and one σ2p∗\sigma^*_{2p}σ2p∗​
    • Perpendicular to internuclear axis: two π2p\pi_{2p}π2p​ and two π2p∗\pi^*_{2p}π2p∗​

    Thus, antibonding orbitals from 2p2p2p = 1 (σ∗)+2 (π∗)=31\,(\sigma^*) + 2\,(\pi^*) = 31(σ∗)+2(π∗)=3

  4. Total antibonding molecular orbitals

    Therefore, Total antibonding MOs=1+3=4\text{Total antibonding MOs} = 1 + 3 = 4Total antibonding MOs=1+3=4

  5. Final answer

    4\boxed{4}4​

  6. Comparison with stored answer

    Stored correct answer = 444

    This matches the derived answer.

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