JEE MainChemistryChemical Bonding and Molecular StructureNumerical+4 / −1
The total number of anti bonding molecular orbitals, formed from and atomic orbitals in a diatomic molecule is .
Numerical answer
View written solutionFree
Correct answer: 4
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Atomic orbitals involved
For each atom, the orbitals considered are:
- one orbital
- three orbitals:
So, for a diatomic molecule, these atomic orbitals combine pairwise to form molecular orbitals.
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Formation from orbitals
Two atomic orbitals combine to give:
- one bonding MO:
- one antibonding MO:
Thus, antibonding orbitals from = .
-
Formation from orbitals
The three orbitals from one atom combine with the three orbitals from the other atom.
- Along internuclear axis: one and one
- Perpendicular to internuclear axis: two and two
Thus, antibonding orbitals from =
-
Total antibonding molecular orbitals
Therefore,
-
Final answer
-
Comparison with stored answer
Stored correct answer =
This matches the derived answer.
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