JEE MainChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
The compound that has the largest H–M–H bond angle (M = N, O, S, C) is :
- A
- B
- C
- D
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Correct answer: A
- We compare the bond angles in the given hydrides:
- :
- :
- :
- :
- Use VSEPR theory:
- More lone pairs on the central atom compress bond angle.
- Tetrahedral electron geometry gives ideal angle .
- Now evaluate each molecule:
(A)
- Central atom has 4 bond pairs and 0 lone pairs.
- Shape: tetrahedral.
- Bond angle:
(C)
- Central atom has 3 bond pairs and 1 lone pair.
- Shape: trigonal pyramidal.
- Lone pair-bond pair repulsion decreases bond angle.
- Bond angle:
(D)
- Central atom has 2 bond pairs and 2 lone pairs.
- Shape: bent.
- Two lone pairs compress the angle further.
- Bond angle:
(B)
- Central atom has 2 bond pairs and 2 lone pairs.
- Shape: bent.
- Because of larger size of sulfur and less effective hybridization, the angle is even smaller.
- Bond angle:
- Compare all values:
So the largest bond angle is in .
- Therefore, the correct option is:
- Comparison with stored correct answer:
- Stored correct answer:
- Derived answer:
They match.
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