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Chemical Bonding and Molecular Structure question

2024 · 5 Apr · Shift 2 · Q2
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  5. /2024 · 5 Apr · Shift 2 · Q2

Chemical Bonding and Molecular Structure question

2024 · 5 Apr · Shift 2 · Q2

JEE MainChemistryChemical Bonding and Molecular StructureMCQ+4 / −1

Match List I with List II.

LIST I
LIST II
A.
ICl\mathrm{ICl}ICl
I. T - shape
B.
ICl3\mathrm{ICl}_3ICl3​
II. Square pyramidal
C.
ClF5\mathrm{ClF}_5ClF5​
III. Pentagonal bipyramidal
D.
IF7\mathrm{IF}_7IF7​
IV. Linear

Choose the correct answer from the options given below :

  1. A
    (A)-(I), (B)-(IV), (C)-(III), (D)-(II)
  2. B
    (A)-(IV), (B)-(I), (C)-(II), (D)-(III)
  3. C
    (A)-(I), (B)-(III), (C)-(II), (D)-(IV)
  4. D
    (A)-(IV), (B)-(III), (C)-(II), (D)-(I)
View written solutionFree

Correct answer: B

  1. Determine the shapes one by one using VSEPR theory.

  1. For ICl\mathrm{ICl}ICl
  • It is a diatomic molecule.
  • Any diatomic molecule is linear.

So, ICl→Linear\mathrm{ICl} \rightarrow \text{Linear}ICl→Linear This matches IV.


  1. For ICl3\mathrm{ICl}_3ICl3​
  • Central atom: Iodine
  • Valence electrons on iodine = 7
  • It forms 3 bonds with 3 chlorine atoms, leaving 2 lone pairs.
  • Thus total electron pairs around iodine = 5

So the electron pair geometry is trigonal bipyramidal. With 2 lone pairs occupying equatorial positions, the molecular shape becomes: T-shape\text{T-shape}T-shape

Thus, ICl3→T-shape\mathrm{ICl}_3 \rightarrow \text{T-shape}ICl3​→T-shape This matches I.


  1. For ClF5\mathrm{ClF}_5ClF5​
  • Central atom: Chlorine
  • Valence electrons on chlorine = 7
  • It forms 5 bonds with fluorine atoms, leaving 1 lone pair.
  • Total electron pairs = 6

So the electron pair geometry is octahedral. With one lone pair, the molecular shape becomes: Square pyramidal\text{Square pyramidal}Square pyramidal

Thus, ClF5→Square pyramidal\mathrm{ClF}_5 \rightarrow \text{Square pyramidal}ClF5​→Square pyramidal This matches II.


  1. For IF7\mathrm{IF}_7IF7​
  • Central atom: Iodine
  • Valence electrons on iodine = 7
  • It forms 7 bonds with fluorine atoms and has no lone pair.
  • Total electron pairs = 7

Hence the geometry is: Pentagonal bipyramidal\text{Pentagonal bipyramidal}Pentagonal bipyramidal

Thus, IF7→Pentagonal bipyramidal\mathrm{IF}_7 \rightarrow \text{Pentagonal bipyramidal}IF7​→Pentagonal bipyramidal This matches III.


  1. Final matching

So we get:

  • A→IVA \rightarrow IVA→IV
  • B→IB \rightarrow IB→I
  • C→IIC \rightarrow IIC→II
  • D→IIID \rightarrow IIID→III

This corresponds to Option B.


  1. Comparison with stored answer

Stored correct answer = B

Our derived answer = B

So, the answer agrees with the stored answer.

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