JEE MainChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
Match List I with List II.
| LIST I | LIST II | ||
|---|---|---|---|
| A. | I. | T - shape | |
| B. | II. | Square pyramidal | |
| C. | III. | Pentagonal bipyramidal | |
| D. | IV. | Linear |
Choose the correct answer from the options given below :
- A(A)-(I), (B)-(IV), (C)-(III), (D)-(II)
- B(A)-(IV), (B)-(I), (C)-(II), (D)-(III)
- C(A)-(I), (B)-(III), (C)-(II), (D)-(IV)
- D(A)-(IV), (B)-(III), (C)-(II), (D)-(I)
View written solutionFree
Correct answer: B
- Determine the shapes one by one using VSEPR theory.
- For
- It is a diatomic molecule.
- Any diatomic molecule is linear.
So, This matches IV.
- For
- Central atom: Iodine
- Valence electrons on iodine = 7
- It forms 3 bonds with 3 chlorine atoms, leaving 2 lone pairs.
- Thus total electron pairs around iodine = 5
So the electron pair geometry is trigonal bipyramidal. With 2 lone pairs occupying equatorial positions, the molecular shape becomes:
Thus, This matches I.
- For
- Central atom: Chlorine
- Valence electrons on chlorine = 7
- It forms 5 bonds with fluorine atoms, leaving 1 lone pair.
- Total electron pairs = 6
So the electron pair geometry is octahedral. With one lone pair, the molecular shape becomes:
Thus, This matches II.
- For
- Central atom: Iodine
- Valence electrons on iodine = 7
- It forms 7 bonds with fluorine atoms and has no lone pair.
- Total electron pairs = 7
Hence the geometry is:
Thus, This matches III.
- Final matching
So we get:
This corresponds to Option B.
- Comparison with stored answer
Stored correct answer = B
Our derived answer = B
So, the answer agrees with the stored answer.
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