- ABoth A and R are true, and R is the correct explanation of A
- BA is true but R is false
- CA is false but R is true
- DBoth A and R are true, but R is not the correct explanation of A
View written solutionFree
Correct answer: A
- Check Assertion A
Water has the molecular formula . Around oxygen, there are:
- bond pairs
- lone pairs
According to VSEPR theory, the electron pair geometry is tetrahedral, but because of the two lone pairs, the molecular shape is bent (angular).
For water, the observed bond angle is: So, Assertion A is true.
- Check Reason R
By VSEPR theory, electron pair repulsions follow the order: Thus, lone pair-lone pair repulsion is greater than bond pair-bond pair repulsion. So, Reason R is true.
- Does R correctly explain A?
In an ideal tetrahedral arrangement, the angle is: But in water, oxygen has two lone pairs. Since lone pairs repel more strongly than bond pairs, they compress the bond angle between the two bonds from to .
Hence, the reason correctly explains why water has a bond angle of .
- Conclusion
- Assertion A is true.
- Reason R is true.
- Reason R correctly explains Assertion A.
Therefore, the correct option is:
More from Chemical Bonding and Molecular Structure
- A central atom in a molecule has two lone pairs of electrons and forms three single bonds. The shape of this molecule is :2021 · MCQ
- Amongst the following, the linear species is :2021 · MCQ
- AX is a covalent diatomic molecule where A and X are second row elements of periodic table. Based on Molecular orbital theory, the bond order of AX is 2.5. The total number of electrons in AX is . (Round off to…2021 · Numerical
- The number of species below that have two lone pairs of electrons in their central atom is . (Round off to the Nearest Integer). , BF , , , , , , 2021 · Numerical
- The number of lone pairs of electrons on the central I atom in I is .2021 · Numerical
- The hybridisations of the atomic orbitals of nitrogen in NO , NO and NH respectively are.2021 · MCQ
- Match List-I with List-II : Choose the correct answer from the options given below : Includes table2021 · MCQ
- Which of the following are isostructural pairs ? A. and B. , and C. and D. and 2021 · MCQ