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Chemical Bonding and Molecular Structure question

2021 · 16 Mar · Shift 1 · Q2
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Chemical Bonding and Molecular Structure question

2021 · 16 Mar · Shift 1 · Q2

JEE MainChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
Given below are two statements : one is labeled as Assertion A and the other is labelled as Reason R : Assertion A : The H −-− O −-− H bond angle in water molecule is 104.5 ∘^\circ∘. Reason R : The lone pair - lone pair repulsion of electrons is higher than the bond pair - bond pair repulsion. In the light of the above statements, choose the correct answer from the options given below :
  1. A
    Both A and R are true, and R is the correct explanation of A
  2. B
    A is true but R is false
  3. C
    A is false but R is true
  4. D
    Both A and R are true, but R is not the correct explanation of A
View written solutionFree

Correct answer: A

  1. Check Assertion A

Water has the molecular formula H2O\mathrm{H_2O}H2​O. Around oxygen, there are:

  • 222 bond pairs
  • 222 lone pairs

According to VSEPR theory, the electron pair geometry is tetrahedral, but because of the two lone pairs, the molecular shape is bent (angular).

For water, the observed bond angle is: ∠H−O−H=104.5∘\angle \mathrm{H-O-H} = 104.5^\circ∠H−O−H=104.5∘ So, Assertion A is true.

  1. Check Reason R

By VSEPR theory, electron pair repulsions follow the order: lone pair-lone pair>lone pair-bond pair>bond pair-bond pair\text{lone pair-lone pair} > \text{lone pair-bond pair} > \text{bond pair-bond pair}lone pair-lone pair>lone pair-bond pair>bond pair-bond pair Thus, lone pair-lone pair repulsion is greater than bond pair-bond pair repulsion. So, Reason R is true.

  1. Does R correctly explain A?

In an ideal tetrahedral arrangement, the angle is: 109.5∘109.5^\circ109.5∘ But in water, oxygen has two lone pairs. Since lone pairs repel more strongly than bond pairs, they compress the bond angle between the two O−H\mathrm{O-H}O−H bonds from 109.5∘109.5^\circ109.5∘ to 104.5∘104.5^\circ104.5∘.

Hence, the reason correctly explains why water has a bond angle of 104.5∘104.5^\circ104.5∘.

  1. Conclusion
  • Assertion A is true.
  • Reason R is true.
  • Reason R correctly explains Assertion A.

Therefore, the correct option is: A\boxed{A}A​

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