- AIn this molecule, orbitals of phosphorous are assumed to undergo sp3d hybridization.
- BThe geometry of is trigonal bipyramidal.
- Chas two axial bonds stronger than three equatorial bonds.
- DThe three equatorial bonds of lie in a plane.
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Correct answer: C
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Write the known structure of
In valence bond description, phosphorus in is commonly taken to form five hybrid orbitals: This gives a trigonal bipyramidal arrangement.
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Check option A
A: “In this molecule, orbitals of phosphorous are assumed to undergo hybridization.”
This is the standard textbook description for .
So, A is correct.
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Check option B
B: “The geometry of is trigonal bipyramidal.”
In , there are:
- 3 equatorial positions
- 2 axial positions
Hence the molecular geometry is indeed trigonal bipyramidal.
So, B is correct.
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Check option D
D: “The three equatorial bonds of lie in a plane.”
In trigonal bipyramidal geometry, the three equatorial bonds are arranged at in the same plane.
So, D is correct.
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Check option C
C: “ has two axial bonds stronger than three equatorial bonds.”
This is incorrect.
In :
- Axial bonds experience more repulsion because each axial bond pair is at to the three equatorial bond pairs.
- Equatorial bonds experience less repulsion comparatively.
Therefore:
- axial bonds are longer and weaker
- equatorial bonds are shorter and stronger
Hence the statement saying axial bonds are stronger is false.
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Conclusion
The incorrect statement is:
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