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Chemical Bonding and Molecular Structure question

2022 · 27 Jun · Shift 2 · Q1
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Chemical Bonding and Molecular Structure question

2022 · 27 Jun · Shift 2 · Q1

JEE MainChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
Identify the incorrect statement for PCl5PCl_5PCl5​ from the following.
  1. A
    In this molecule, orbitals of phosphorous are assumed to undergo sp3d hybridization.
  2. B
    The geometry of PCl5PCl_5PCl5​ is trigonal bipyramidal.
  3. C
    PCl5PCl_5PCl5​ has two axial bonds stronger than three equatorial bonds.
  4. D
    The three equatorial bonds of PCl5PCl_5PCl5​ lie in a plane.
View written solutionFree

Correct answer: C

  1. Write the known structure of PCl5PCl_5PCl5​

    In valence bond description, phosphorus in PCl5PCl_5PCl5​ is commonly taken to form five hybrid orbitals: sp3dsp^3dsp3d This gives a trigonal bipyramidal arrangement.

  2. Check option A

    A: “In this molecule, orbitals of phosphorous are assumed to undergo sp3dsp^3dsp3d hybridization.”

    This is the standard textbook description for PCl5PCl_5PCl5​.

    So, A is correct.

  3. Check option B

    B: “The geometry of PCl5PCl_5PCl5​ is trigonal bipyramidal.”

    In PCl5PCl_5PCl5​, there are:

    • 3 equatorial positions
    • 2 axial positions

    Hence the molecular geometry is indeed trigonal bipyramidal.

    So, B is correct.

  4. Check option D

    D: “The three equatorial bonds of PCl5PCl_5PCl5​ lie in a plane.”

    In trigonal bipyramidal geometry, the three equatorial bonds are arranged at 120∘120^\circ120∘ in the same plane.

    So, D is correct.

  5. Check option C

    C: “PCl5PCl_5PCl5​ has two axial bonds stronger than three equatorial bonds.”

    This is incorrect.

    In PCl5PCl_5PCl5​:

    • Axial bonds experience more repulsion because each axial bond pair is at 90∘90^\circ90∘ to the three equatorial bond pairs.
    • Equatorial bonds experience less repulsion comparatively.

    Therefore:

    • axial P−ClP-ClP−Cl bonds are longer and weaker
    • equatorial P−ClP-ClP−Cl bonds are shorter and stronger

    Hence the statement saying axial bonds are stronger is false.

  6. Conclusion

    The incorrect statement is: C\boxed{\text{C}}C​

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