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Chemical Bonding and Molecular Structure question

2020 · 2 Sep · Shift 2 · Q10
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Chemical Bonding and Molecular Structure question

2020 · 2 Sep · Shift 2 · Q10

JEE MainChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
The molecular geometry of SF6SF_6SF6​ is octahedral. What is the geometry of SF4SF_4SF4​ (including lone pair(s) of electrons, if any)?
  1. A
    Tetrahedral
  2. B
    Trigonal bipyramidal
  3. C
    Square planar
  4. D
    Pyramidal
View written solutionFree

Correct answer: B

  1. Count the valence electrons around sulfur in SF4SF_4SF4​

    • Sulfur has 666 valence electrons.
    • In SF4SF_4SF4​, sulfur forms 444 S−FS-FS−F bonds.

    So, around the central sulfur atom there are:

    • 444 bonding pairs
    • remaining 111 lone pair

    Thus, the total number of electron pairs around sulfur is: 4+1=54 + 1 = 54+1=5

  2. Determine the electron-pair geometry using VSEPR theory

    A central atom with 555 electron pairs has trigonal bipyramidal electron geometry.

    Since the question says including lone pair(s) of electrons, if any), we must give the geometry including the lone pair.

    Therefore, the geometry of SF4SF_4SF4​ including the lone pair is: Trigonal bipyramidal\boxed{\text{Trigonal bipyramidal}}Trigonal bipyramidal​

  3. Note on actual molecular shape

    If the question had asked for the shape of only the atoms (excluding the lone pair), SF4SF_4SF4​ would be see-saw. But that option is not given, and the question explicitly says to include lone pair(s).

  4. Check the options

    • A: Tetrahedral →\to→ incorrect
    • B: Trigonal bipyramidal →\to→ correct
    • C: Square planar →\to→ incorrect
    • D: Pyramidal →\to→ incorrect
  5. Final answer

    B: Trigonal bipyramidal\boxed{\text{B: Trigonal bipyramidal}}B: Trigonal bipyramidal​

  6. Comparison with stored correct answer

    Stored correct answer: B

    My derived answer: B

    They match.

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