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Chemical Bonding and Molecular Structure question

2025 · 22 Jan · Shift 1 · Q21
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Chemical Bonding and Molecular Structure question

2025 · 22 Jan · Shift 1 · Q21

JEE MainChemistryChemical Bonding and Molecular StructureNumerical+4 / −1
The number of molecules/ions that show linear geometry among the following is ‾\underline{\hspace{2cm}}​. SO2,BeCl2,CO2, N3−,NO2, F2O,XeF2,NO2+,I3−,O3\mathrm{SO}_2, \mathrm{BeCl}_2, \mathrm{CO}_2, \mathrm{~N}_3^{-}, \mathrm{NO}_2, \mathrm{~F}_2 \mathrm{O}, \mathrm{XeF}_2, \mathrm{NO}_2^{+}, \mathrm{I}_3^{-}, \mathrm{O}_3SO2​,BeCl2​,CO2​, N3−​,NO2​, F2​O,XeF2​,NO2+​,I3−​,O3​
Numerical answer
View written solutionFree

Correct answer: 6

  1. We need to count the species with linear geometry among:

SO2, BeCl2, CO2, N3−, NO2, F2O, XeF2, NO2+, I3−, O3\mathrm{SO_2,\ BeCl_2,\ CO_2,\ N_3^-,\ NO_2,\ F_2O,\ XeF_2,\ NO_2^+,\ I_3^-,\ O_3}SO2​, BeCl2​, CO2​, N3−​, NO2​, F2​O, XeF2​, NO2+​, I3−​, O3​

We evaluate each using VSEPR / known molecular geometry.


  1. Check each species:

(i) SO2\mathrm{SO_2}SO2​

  • Central atom: S
  • Electron geometry: trigonal planar (one lone pair on S)
  • Molecular shape: bent/angular
  • Not linear

(ii) BeCl2\mathrm{BeCl_2}BeCl2​

  • Central atom: Be
  • Two bond pairs, no lone pair on Be
  • Shape: linear
  • Linear

(iii) CO2\mathrm{CO_2}CO2​

  • Central atom: C
  • Two electron domains, no lone pair
  • Shape: linear
  • Linear

(iv) N3−\mathrm{N_3^-}N3−​

  • Azide ion
  • Resonance-stabilized and known to be linear
  • Linear

(v) NO2\mathrm{NO_2}NO2​

  • Neutral nitrogen dioxide has an odd electron
  • Shape is bent
  • Not linear

(vi) F2O\mathrm{F_2O}F2​O

  • Same as OF2\mathrm{OF_2}OF2​
  • Central atom O has two lone pairs
  • Shape: bent
  • Not linear

(vii) XeF2\mathrm{XeF_2}XeF2​

  • Central atom Xe
  • Five electron pairs around Xe: 222 bond pairs + 333 lone pairs
  • Trigonal bipyramidal electron arrangement; lone pairs occupy equatorial positions
  • Molecular shape: linear
  • Linear

(viii) NO2+\mathrm{NO_2^+}NO2+​

  • Nitronium ion
  • Central atom N with two bonding regions, no lone pair
  • Shape: linear
  • Linear

(ix) I3−\mathrm{I_3^-}I3−​

  • Central atom I
  • Five electron pairs: 222 bond pairs + 333 lone pairs
  • Shape: linear
  • Linear

(x) O3\mathrm{O_3}O3​

  • Ozone
  • Central atom O with one lone pair
  • Shape: bent
  • Not linear

  1. Linear species are:

BeCl2, CO2, N3−, XeF2, NO2+, I3−\mathrm{BeCl_2,\ CO_2,\ N_3^-,\ XeF_2,\ NO_2^+,\ I_3^-}BeCl2​, CO2​, N3−​, XeF2​, NO2+​, I3−​

Total number:

666


  1. Comparison with stored answer:
  • Derived answer = 666
  • Stored correct answer = 666

They match.

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