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Chemical Bonding and Molecular Structure question

2024 · 30 Jan · Shift 1 · Q19
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Chemical Bonding and Molecular Structure question

2024 · 30 Jan · Shift 1 · Q19

JEE MainChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A) : There is a considerable increase in covalent radius from N\mathrm{N}N to P\mathrm{P}P. However from As to Bi only a small increase in covalent radius is observed. Reason (R) : Covalent and ionic radii in a particular oxidation state increases down the group. In the light of the above statements, choose the most appropriate answer from the options given below:
  1. A
    (A) is false but (R) is true
  2. B
    Both (A) and (R) are true and (R) is the correct explanation of (A)
  3. C
    Both (A) and (R) are true but (R) is not the correct explanation of (A)
  4. D
    (A) is true but (R) is false
View written solutionFree

Correct answer: C

  1. Examine Assertion (A)

Assertion:

  • There is a considerable increase in covalent radius from N\mathrm{N}N to P\mathrm{P}P.
  • From As\mathrm{As}As to Bi\mathrm{Bi}Bi only a small increase in covalent radius is observed.

For group 15 elements, the covalent radius generally increases down the group, but not uniformly.

Approximate trend: N<P<As≈Sb≈Bi\mathrm{N} < \mathrm{P} < \mathrm{As} \approx \mathrm{Sb} \approx \mathrm{Bi}N<P<As≈Sb≈Bi

  • The increase from N\mathrm{N}N to P\mathrm{P}P is indeed large because we move from the 2nd period to the 3rd period.
  • From As\mathrm{As}As to Sb\mathrm{Sb}Sb to Bi\mathrm{Bi}Bi, the increase is relatively small due to poor shielding by intervening ddd and fff electrons, causing contraction effects.

So, Assertion (A) is true.


  1. Examine Reason (R)

Reason:

  • Covalent and ionic radii in a particular oxidation state increase down the group.

This is a generally correct periodic trend:

  • On moving down a group, additional shells are added.
  • Hence atomic size, covalent radius, and ionic radius generally increase.

So, Reason (R) is true.


  1. Check whether (R) correctly explains (A)

The reason only states the general trend that radii increase down the group.

But Assertion (A) is about a non-uniform increase:

  • large increase from N\mathrm{N}N to P\mathrm{P}P,
  • only small increase from As\mathrm{As}As to Bi\mathrm{Bi}Bi.

This non-uniformity is explained by poor shielding of ddd and fff electrons and resulting contraction effects, not merely by the general statement that radii increase down the group.

Therefore, (R) is not the correct explanation of (A).


  1. Evaluate options
  • A: (A) is false but (R) is true →\rightarrow→ False
  • B: Both (A) and (R) are true and (R) is the correct explanation of (A) →\rightarrow→ False
  • C: Both (A) and (R) are true but (R) is not the correct explanation of (A) →\rightarrow→ True
  • D: (A) is true but (R) is false →\rightarrow→ False

  1. Final Answer

The correct option is: C\boxed{\text{C}}C​


  1. Comparison with stored correct answer

Stored correct answer: C

My derived answer: C

So, they agree.

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