JEE MainChemistryChemical Bonding and Molecular StructureNumerical+4 / −1
Amongst , , and , the number of species with two lone pairs of electrons is .
Numerical answer
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Correct answer: 2
- We need to count how many of the given species have exactly two lone pairs of electrons on the central atom.
The species are:
- Analyze each species one by one.
(i)
- Central atom:
- Sulfur has 6 valence electrons.
- It forms 4 bonds with 4 fluorine atoms.
- So, after making 4 bond pairs, sulfur has 1 lone pair left.
Thus, has one lone pair, not two.
(ii)
- Central atom:
- Xenon has 8 valence electrons.
- It forms 4 bonds with 4 fluorine atoms.
- After forming 4 bond pairs, xenon has 2 lone pairs left.
Thus, has two lone pairs.
(iii)
- Central atom:
- Carbon has 4 valence electrons.
- It forms 4 bonds with 4 fluorine atoms.
- No electrons remain as lone pairs on carbon.
Thus, has zero lone pairs.
(iv)
- Central atom:
- Oxygen has 6 valence electrons.
- It forms 2 bonds with 2 hydrogen atoms.
- So, oxygen has 2 lone pairs left.
Thus, has two lone pairs.
- Species with exactly two lone pairs are:
Hence, the number of such species is
- Comparison with stored answer:
- Derived answer:
- Stored correct answer:
These do not match. The stored answer appears to be incorrect, because both and have two lone pairs on the central atom.
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