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Chemical Bonding and Molecular Structure question

2022 · 26 Jun · Shift 2 · Q17
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Chemical Bonding and Molecular Structure question

2022 · 26 Jun · Shift 2 · Q17

JEE MainChemistryChemical Bonding and Molecular StructureNumerical+4 / −1
Amongst SF4SF_4SF4​, XeF4XeF_4XeF4​, CF4CF_4CF4​ and H2OH_2OH2​O, the number of species with two lone pairs of electrons is ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 2

  1. We need to count how many of the given species have exactly two lone pairs of electrons on the central atom.

The species are:

  • SF4SF_4SF4​
  • XeF4XeF_4XeF4​
  • CF4CF_4CF4​
  • H2OH_2OH2​O

  1. Analyze each species one by one.

(i) SF4SF_4SF4​

  • Central atom: SSS
  • Sulfur has 6 valence electrons.
  • It forms 4 bonds with 4 fluorine atoms.
  • So, after making 4 bond pairs, sulfur has 1 lone pair left.

Thus, SF4SF_4SF4​ has one lone pair, not two.


(ii) XeF4XeF_4XeF4​

  • Central atom: XeXeXe
  • Xenon has 8 valence electrons.
  • It forms 4 bonds with 4 fluorine atoms.
  • After forming 4 bond pairs, xenon has 2 lone pairs left.

Thus, XeF4XeF_4XeF4​ has two lone pairs.


(iii) CF4CF_4CF4​

  • Central atom: CCC
  • Carbon has 4 valence electrons.
  • It forms 4 bonds with 4 fluorine atoms.
  • No electrons remain as lone pairs on carbon.

Thus, CF4CF_4CF4​ has zero lone pairs.


(iv) H2OH_2OH2​O

  • Central atom: OOO
  • Oxygen has 6 valence electrons.
  • It forms 2 bonds with 2 hydrogen atoms.
  • So, oxygen has 2 lone pairs left.

Thus, H2OH_2OH2​O has two lone pairs.


  1. Species with exactly two lone pairs are:
  • XeF4XeF_4XeF4​
  • H2OH_2OH2​O

Hence, the number of such species is 222


  1. Comparison with stored answer:
  • Derived answer: 222
  • Stored correct answer: 111

These do not match. The stored answer appears to be incorrect, because both XeF4XeF_4XeF4​ and H2OH_2OH2​O have two lone pairs on the central atom.

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