JEE MainChemistryChemical Bonding and Molecular StructureNumerical+4 / −1
Total number of non-bonded electrons present in ion based on Lewis theory is .
Numerical answer
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Correct answer: 12
- Count total valence electrons
For :
- Nitrogen contributes valence electrons.
- Two oxygen atoms contribute valence electrons.
- The negative charge adds extra electron.
So total valence electrons are:
- Draw the Lewis structure
The nitrite ion, , has nitrogen as the central atom. A valid Lewis structure has:
- one double bond,
- one single bond,
- one lone pair on nitrogen.
There are two equivalent resonance structures, but the total number of non-bonded electrons remains the same in either one.
- Count bonding electrons
In one resonance structure:
- one double bond has bonding electrons,
- one single bond has bonding electrons.
Total bonding electrons:
- Find non-bonded electrons
Non-bonded electrons are:
- Check by direct lone-pair counting
- Double-bonded oxygen has lone pairs electrons
- Single-bonded oxygen has lone pairs electrons
- Nitrogen has lone pair electrons
Total non-bonded electrons:
Thus, the total number of non-bonded electrons in is:
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