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Correct answer: 3
- Identify the geometry corresponding to square pyramidal
A square pyramidal molecular shape arises when the central atom has:
- electron pairs around it,
- with arrangement .
So total electron-pair geometry is octahedral, and one lone pair gives square pyramidal shape.
- Check each given species
We examine the interhalogens one by one.
(i)
Central atom
- Valence electrons on Cl
- Forms bonds with F
- Lone pairs on Cl
Thus it is . Molecular shape: T-shaped, not square pyramidal.
(ii)
Central atom
- bonds, lone pairs
- Type
Molecular shape: pentagonal bipyramidal, not square pyramidal.
(iii)
Central atom
- bonds, lone pair
- Type
Molecular shape: square pyramidal.
(iv)
Central atom
- bonds, lone pairs
- Type
Molecular shape: T-shaped, not square pyramidal.
(v)
This is dimeric, analogous to -type bridged structure, and is not a simple interhalogen with one central atom showing . It does not have square pyramidal molecular geometry.
(vi)
Central atom
- bonds, lone pair
- Type
Molecular shape: square pyramidal.
(vii)
Diatomic molecule.
Shape is simply linear, not square pyramidal.
(viii)
Central atom
- bonds, lone pair
- Type
Molecular shape: square pyramidal.
- Count square pyramidal species
The species having square pyramidal structure are:
So, total number is
- Comparison with stored answer
Stored correct answer . Our derived answer . They match.
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