Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Chemical Bonding and Molecular Structure question

2022 · 28 Jul · Shift 1 · Q19
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Chemical Bonding and Molecular Structure
  5. /2022 · 28 Jul · Shift 1 · Q19

Chemical Bonding and Molecular Structure question

2022 · 28 Jul · Shift 1 · Q19

JEE MainChemistryChemical Bonding and Molecular StructureNumerical+4 / −1
The number of interhalogens from the following having square pyramidal structure is : ClF3,IF7,BrF5,BrF3,I2Cl6,IF5,ClF,ClF5\mathrm{ClF}_{3}, \mathrm{IF}_{7}, \mathrm{BrF}_{5}, \mathrm{BrF}_{3}, \mathrm{I}_{2} \mathrm{Cl}_{6}, \mathrm{IF}_{5}, \mathrm{ClF}, \mathrm{ClF}_{5}ClF3​,IF7​,BrF5​,BrF3​,I2​Cl6​,IF5​,ClF,ClF5​
Numerical answer
View written solutionFree

Correct answer: 3

  1. Identify the geometry corresponding to square pyramidal

A square pyramidal molecular shape arises when the central atom has:

  • 666 electron pairs around it,
  • with arrangement AX5EAX_5EAX5​E.

So total electron-pair geometry is octahedral, and one lone pair gives square pyramidal shape.


  1. Check each given species

We examine the interhalogens one by one.

(i) ClF3\mathrm{ClF_3}ClF3​

Central atom =Cl= \mathrm{Cl}=Cl

  • Valence electrons on Cl =7= 7=7
  • Forms 333 bonds with F
  • Lone pairs on Cl =2= 2=2

Thus it is AX3E2AX_3E_2AX3​E2​. Molecular shape: T-shaped, not square pyramidal.


(ii) IF7\mathrm{IF_7}IF7​

Central atom =I= \mathrm{I}=I

  • 777 bonds, 000 lone pairs
  • Type AX7AX_7AX7​

Molecular shape: pentagonal bipyramidal, not square pyramidal.


(iii) BrF5\mathrm{BrF_5}BrF5​

Central atom =Br= \mathrm{Br}=Br

  • 555 bonds, 111 lone pair
  • Type AX5EAX_5EAX5​E

Molecular shape: square pyramidal.


(iv) BrF3\mathrm{BrF_3}BrF3​

Central atom =Br= \mathrm{Br}=Br

  • 333 bonds, 222 lone pairs
  • Type AX3E2AX_3E_2AX3​E2​

Molecular shape: T-shaped, not square pyramidal.


(v) I2Cl6\mathrm{I_2Cl_6}I2​Cl6​

This is dimeric, analogous to Al2Cl6\mathrm{Al_2Cl_6}Al2​Cl6​-type bridged structure, and is not a simple interhalogen with one central atom showing AX5EAX_5EAX5​E. It does not have square pyramidal molecular geometry.


(vi) IF5\mathrm{IF_5}IF5​

Central atom =I= \mathrm{I}=I

  • 555 bonds, 111 lone pair
  • Type AX5EAX_5EAX5​E

Molecular shape: square pyramidal.


(vii) ClF\mathrm{ClF}ClF

Diatomic molecule.

Shape is simply linear, not square pyramidal.


(viii) ClF5\mathrm{ClF_5}ClF5​

Central atom =Cl= \mathrm{Cl}=Cl

  • 555 bonds, 111 lone pair
  • Type AX5EAX_5EAX5​E

Molecular shape: square pyramidal.


  1. Count square pyramidal species

The species having square pyramidal structure are:

  • BrF5\mathrm{BrF_5}BrF5​
  • IF5\mathrm{IF_5}IF5​
  • ClF5\mathrm{ClF_5}ClF5​

So, total number is 333


  1. Comparison with stored answer

Stored correct answer =3= 3=3. Our derived answer =3= 3=3. They match.

PreviousNext

More from Chemical Bonding and Molecular Structure

  • The hybridization of P exhibited in PF5​ is spxdy. The value of y is ​.2022 · Numerical
  • In the structure of SF4​, the lone pair of electrons on S is in.2022 · MCQ
  • Which of the following pair of molecules contain odd electron molecule and an expanded octet molecule?2022 · MCQ
  • Number of lone pairs of electrons in the central atom of SCl2​,O3​,ClF3​ and SF6​, respectively, are :2022 · MCQ
  • Consider, PF5​,BrF5​,PCl3​,SF6​,[ICl4​]−,ClF3​ and IF5​. Amongst the above molecule(s)/ion(s), the number of molecule(s)/ion(s) having sp3 d2…2022 · Numerical
  • Consider the species CH4​, NH 4+​ and BH 4−​. Choose the correct option with respect to the these species.2022 · MCQ
  • Number of lone pair(s) of electrons on central atom and the shape BrF3​ molecule respectively, are2022 · MCQ
  • Amongst the following, the number of molecule/(s) having net resultant dipole moment is ​. NF3​, BF3​, BeF2​, CHCl3​, H2​S, SiF4​, CCl4​, PF5​2022 · Numerical