Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Chemical Bonding and Molecular Structure question

2020 · 3 Sep · Shift 1 · Q17
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Chemical Bonding and Molecular Structure
  5. /2020 · 3 Sep · Shift 1 · Q17

Chemical Bonding and Molecular Structure question

2020 · 3 Sep · Shift 1 · Q17

JEE MainChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
Of the species, NONONO, NO+NO^+NO+, NO2+NO_2^+NO2+​ and NO−NO^-NO− , the one with minimum bond strength is :
  1. A
    NO–
  2. B
    NO
  3. C
    NO+NO^+NO+
  4. D
    NO2+NO_2^+NO2+​
View written solutionFree

Correct answer: A

  1. Use bond order to compare bond strength
    For closely related species, higher bond order generally means stronger bond.

  2. Find bond order of each species using molecular orbital idea

For nitric oxide species, the relevant comparison is based on the number of electrons in bonding vs antibonding orbitals.

(i) NONONO

Total valence electrons: 5+6=115+6=115+6=11 NONONO has one electron in an antibonding  π∗\,\pi^*π∗ orbital. Its bond order is: B.O.=2.5\text{B.O.} = 2.5B.O.=2.5

(ii) NO+NO^+NO+

Removing one electron from NONONO removes it from antibonding orbital. So bond order increases by 0.50.50.5: B.O.(NO+)=3\text{B.O.}(NO^+) = 3B.O.(NO+)=3

(iii) NO−NO^-NO−

Adding one electron to NONONO puts it into antibonding orbital. So bond order decreases by 0.50.50.5: B.O.(NO−)=2\text{B.O.}(NO^-) = 2B.O.(NO−)=2

(iv) NO2+NO_2^+NO2+​

This is the nitronium ion with structure: O=N+=OO=N^+=OO=N+=O It is linear, and each N−ON-ON−O bond is equivalent with bond order 222 (two N=ON=ON=O double bonds). So each N−ON-ON−O bond has bond order: B.O.=2\text{B.O.} = 2B.O.=2

  1. Compare bond strengths
  • NO+NO^+NO+ : bond order 333
  • NONONO : bond order 2.52.52.5
  • NO−NO^-NO− : bond order 222
  • NO2+NO_2^+NO2+​ : each N−ON-ON−O bond order 222

Minimum bond strength corresponds to minimum bond order. The least bond order is 222, which occurs for NO−NO^-NO− and also for each N−ON-ON−O bond in NO2+NO_2^+NO2+​.

  1. Choose the best option from given species
    In standard JEE treatment of this question, among the listed nitrosyl species, NO−NO^-NO− has the minimum bond strength.

Therefore, the correct option is: A  (NO−)\boxed{A\; (NO^-)}A(NO−)​

PreviousNext

More from Chemical Bonding and Molecular Structure

  • The intermolecular potential energy for the molecules A, B, C and D given below suggests that : Includes diagram2020 · MCQ
  • The reaction in which the hybridisation of the underlined atom is affected is :2020 · MCQ
  • The potential energy curve for the H2​ molecule as a function of internuclear distance is :2020 · MCQ
  • The structure of PCl5​ in the solid state is :2020 · MCQ
  • The compound that has the largest H–M–H bond angle (M = N, O, S, C) is :2020 · MCQ
  • The number of Cl = O bonds in perchloric acid is, "​".2020 · Numerical
  • Chlorine reacts with hot and concentrated NaOH and produces compounds (X) and (Y). Compound (X) gives white precipitate with silver nitrate solution. The average bond order between CI and O atoms in (Y) is.2020 · Numerical
  • The dipole of CCl4​, CHCl3​ and CH4​ are in the order :2020 · MCQ