Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Chemical Bonding and Molecular Structure question

2023 · 11 Apr · Shift 2 · Q16
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Chemical Bonding and Molecular Structure
  5. /2023 · 11 Apr · Shift 2 · Q16

Chemical Bonding and Molecular Structure question

2023 · 11 Apr · Shift 2 · Q16

JEE MainChemistryChemical Bonding and Molecular StructureNumerical+4 / −1
The maximum number of lone pairs of electrons on the central atom from the following species is ‾\underline{\hspace{2cm}}​. ClO3−,XeF4,SF4\mathrm{ClO}_{3}{ }^{-}, \mathrm{XeF}_{4}, \mathrm{SF}_{4}ClO3​−,XeF4​,SF4​ and I3−\mathrm{I}_{3}{ }^{-}I3​−
Numerical answer
View written solutionFree

Correct answer: 3

  1. We need to find the number of lone pairs on the central atom in each species, then take the maximum.

The species are:

  • ClO3−\mathrm{ClO_3^-}ClO3−​
  • XeF4\mathrm{XeF_4}XeF4​
  • SF4\mathrm{SF_4}SF4​
  • I3−\mathrm{I_3^-}I3−​

  1. For ClO3−\mathrm{ClO_3^-}ClO3−​

Let chlorine be the central atom.

Total valence electrons: 7+3(6)+1=267 + 3(6) + 1 = 267+3(6)+1=26

In chlorate ion, chlorine forms three bonds with oxygen and has one lone pair in the usual Lewis structure.

Using VSEPR, steric number around Cl is 4:

  • 3 bond pairs
  • 1 lone pair

So, lone pairs on central atom in ClO3−\mathrm{ClO_3^-}ClO3−​: 111


  1. For XeF4\mathrm{XeF_4}XeF4​

Xenon is the central atom.

Total valence electrons: 8+4(7)=368 + 4(7) = 368+4(7)=36

Xe forms 4 bonds with F atoms. After completing octets, xenon has 2 lone pairs.

VSEPR: steric number =6= 6=6:

  • 4 bond pairs
  • 2 lone pairs

So, lone pairs on central atom in XeF4\mathrm{XeF_4}XeF4​: 222


  1. For SF4\mathrm{SF_4}SF4​

Sulfur is the central atom.

Total valence electrons: 6+4(7)=346 + 4(7) = 346+4(7)=34

Sulfur forms 4 bonds with F atoms and retains 1 lone pair.

VSEPR: steric number =5= 5=5:

  • 4 bond pairs
  • 1 lone pair

So, lone pairs on central atom in SF4\mathrm{SF_4}SF4​: 111


  1. For I3−\mathrm{I_3^-}I3−​

The central iodine is the middle atom.

Total valence electrons: 3(7)+1=223(7) + 1 = 223(7)+1=22

The central iodine forms 2 bonds with terminal iodine atoms.

After completing octets, the central iodine has 3 lone pairs.

VSEPR: steric number =5= 5=5:

  • 2 bond pairs
  • 3 lone pairs

So, lone pairs on central atom in I3−\mathrm{I_3^-}I3−​: 333


  1. Now compare all values:
  • ClO3−:1\mathrm{ClO_3^-} : 1ClO3−​:1
  • XeF4:2\mathrm{XeF_4} : 2XeF4​:2
  • SF4:1\mathrm{SF_4} : 1SF4​:1
  • I3−:3\mathrm{I_3^-} : 3I3−​:3

Therefore, the maximum number of lone pairs on the central atom is: 3\boxed{3}3​


  1. Comparison with stored answer

Stored correct answer = 333

Our derived answer = 333

So they agree.

PreviousNext

More from Chemical Bonding and Molecular Structure

  • The bond order and magnetic property of acetylide ion are same as that of2023 · MCQ
  • In which of the following processes, the bond order increases and paramagnetic character changes to diamagnetic one ?2023 · MCQ
  • ClF5​ at room temperature is a:2023 · MCQ
  • Given below are two statements : Statement I : SO2​ and H2​O both possess V-shaped structure. Statement II : The bond angle of SO2​ is less than that of H2​O. In the…2023 · MCQ
  • Consider the following statements: (A) NF3​ molecule has a trigonal planar structure. (B) Bond length of N2​ is shorter than O2​. (C) Isoelectronic molecules or ions have identical bond order. (D) Dipole moment…2023 · MCQ
  • The number of P−O−P bonds in H4​P2​O7​,(HPO3​)3​ and P4​O10​ are respectively :2023 · MCQ
  • Order of Covalent bond; A. KF>KI;LiF>KF B. KF<KI;LiF>KF C. SnCl4​>SnCl2​;CuCl>NaCl D. LiF>KF;CuCl<NaCl E. KF<KI;CuCl>NaCl Choose the…2023 · MCQ
  • Decreasing order of the hydrogen bonding in following forms of water is correctly represented by A. Liquid water B. Ice C. Impure water Choose the correct answer from the options given below :2023 · MCQ