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Ionic Equilibrium

129 questions · Chemistry · JEE Main
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Ionic Equilibrium

129 questions · Chemistry · JEE Main

  1. If equal volumes of AB2​ and XY(both are salts) aqueous solutions are mixed, which of the following combination will give a precipitate of AY2​ at 300 K ? (Given Ksp​( at 300 K ) for AY2​=5.2×10−7…2025 · 2 Apr · Shift 1 · Q3 · MCQ
  2. 40 mL of a mixture of CH3​COOH and HCl (aqueous solution) is titrated against 0.1 M NaOH solution conductometrically. Which of the following statement is correct? Includes diagram2025 · 3 Apr · Shift 2 · Q19 · MCQ
  3. The pH of a 0.01 M weak acid HX(Ka​=4×10−10) is found to be 5 . Now the acid solution is diluted with excess of water so that the pH of the solution changes to 6 . The new concentration of the…2025 · 4 Apr · Shift 1 · Q21 · Numerical
  4. The molar conductance of an infinitely dilute solution of ammonium chloride was found to be 185 S cm2 mol−1 and the ionic conductance of hydroxyl and chloride ions are 170 and 70 S cm2 mol−1…2025 · 4 Apr · Shift 2 · Q24 · Numerical
  5. xmg of Mg(OH)2​( molar mass =58) is required to be dissolved in 1.0 L of water to produce a pH of 10.0 at 298 K . The value of x is ​ mg. (Nearest integer) (Given : Mg(OH)2​…2025 · 4 Apr · Shift 2 · Q25 · Numerical
  6. An aqueous solution of HCl with pH 1.0 is diluted by adding equal volume of water (ignoring dissociation of water). The pH of HCl solution would ( Given log2=0.30)2025 · 7 Apr · Shift 1 · Q1 · MCQ
  7. The percentage dissociation of a salt (MX3​) solution at given temperature (van't Hoff factor i=2 ) is ​ %(Nearest integer)2025 · 7 Apr · Shift 1 · Q24 · Numerical
  8. One litre buffer solution was prepared by adding 0.10 mol each of NH3​ and NH4​Cl in deionised water. The change in pH on addition of 0.05 mol of HCl to the above solution is ​×10−2…2025 · 7 Apr · Shift 2 · Q24 · Numerical
  9. The molar solubility(s) of zirconium phosphate with molecular formula (Zr4+)3​(PO43−​)4​ is given by relation :2025 · 22 Jan · Shift 2 · Q11 · MCQ
  10. Which of the following happens when NH4​OH is added gradually to the solution containing 1 M A2+ and 1MB3+ ions? Given : Ksp ​[A(OH)2​]=9×10−10…2025 · 23 Jan · Shift 1 · Q13 · MCQ
  11. If 1 mM solution of ethylamine produces pH=9, then the ionization constant (Kb​) of ethylamine is 10−x. The value of x is ​ (nearest integer). [The degree of…2025 · 23 Jan · Shift 1 · Q23 · Numerical
  12. pH of water is 7 at 25∘C. If water is heated to 80∘C., it's pH will :2025 · 23 Jan · Shift 2 · Q1 · MCQ
  13. Ksp​ for Cr(OH)3​ is 1.6×10−30. What is the molar solubility of this salt in water?2025 · 24 Jan · Shift 1 · Q9 · MCQ
  14. The observed and normal molar masses of compound MX2​ are 65.6 and 164 respectively. The percent degree of ionisation of MX2​ is ​%. (Nearest integer)2025 · 24 Jan · Shift 2 · Q24 · Numerical
  15. A weak acid HA has degree of dissociation x . Which option gives the correct expression of ( pH - pKa​)?2025 · 28 Jan · Shift 1 · Q4 · MCQ
  16. Arrange the following in increasing order of solubility product : Ca(OH)2​,AgBr,PbS,HgS2025 · 28 Jan · Shift 2 · Q5 · MCQ
  17. Ka​ for CH3​COOH is 1.8×10−5 and Kb​ for NH4​OH is 1.8×10−5. The pH of ammonium acetate solution will be ​…2024 · 1 Feb · Shift 1 · Q28 · Numerical
  18. Solubility of calcium phosphate (molecular mass, M) in water is Wg​ per 100 mL at 25∘C. Its solubility product at 25∘C will be approximately.2024 · 1 Feb · Shift 2 · Q2 · MCQ
  19. Consider the dissociation of the weak acid HX as given below HX(aq)⇌H+(aq)+X−(aq),Ka=1.2×10−5[Ka​: dissociation…2024 · 6 Apr · Shift 1 · Q23 · Numerical
  20. The equilibrium Cr2​O72−​⇌2CrO42−​ is shifted to the right in :2024 · 8 Apr · Shift 2 · Q12 · MCQ
  21. Given below are two statements : Statement (I) : A Buffer solution is the mixture of a salt and an acid or a base mixed in any particular quantities Statement (II) : Blood is naturally occurring buffer solution whose pH is…2024 · 8 Apr · Shift 2 · Q2 · MCQ
  22. For a sparingly soluble salt AB2​, the equilibrium concentrations of A2+ ions and B− ions are 1.2×10−4M and 0.24×10−3M, respectively. The solubility product of AB2​…2024 · 9 Apr · Shift 2 · Q14 · MCQ
  23. Given below are two statements : Statement (I) : Aqueous solution of ammonium carbonate is basic. Statement (II) : Acidic/basic nature of salt solution of a salt of weak acid and weak base depends on Ka​ and Kb​ value of acid and the…2024 · 27 Jan · Shift 1 · Q16 · MCQ
  24. The pH at which Mg(OH)2​[ Ksp​=1×10−11] begins to precipitate from a solution containing 0.10 M Mg2+ ions is ​.2024 · 30 Jan · Shift 1 · Q25 · Numerical
  25. The pH of an aqueous solution containing 1M benzoic acid (pKa​=4.20) and 1M sodium benzoate is 4.5. The volume of benzoic acid solution in 300 mL of this…2024 · 30 Jan · Shift 2 · Q26 · Numerical
  26. The titration curve of weak acid vs. strong base with phenolphthalein as indictor) is shown below. The Kphenolphthalein ​=4×10−10. Given: log2=0.3 The number of following statement/s which is/are… Includes diagram2023 · 8 Apr · Shift 1 · Q18 · Numerical
  27. The solubility product of BaSO4​ is 1×10−10 at 298 K. The solubility of BaSO4​ in 0.1 M K2​SO4​(aq) solution is ​×10−9 g L−1…2023 · 8 Apr · Shift 2 · Q16 · Numerical
  28. 25 mL of silver nitrate solution (1M) is added dropwise to 25 mL of potassium iodide (1.05M) solution. The ion(s) present in very small quantity in the solution is/are :2023 · 11 Apr · Shift 1 · Q7 · MCQ
  29. An analyst wants to convert 1 L HCl of pH=1 to a solution of HCl of pH 2. The volume of water needed to do this dilution is ​mL. (Nearest integer)2023 · 12 Apr · Shift 1 · Q21 · Numerical
  30. 25.0 mL of 0.050 M Ba(NO3​)2​ is mixed with 25.0 mL of 0.020 M NaF.KSp​ of BaF2​ is 0.5×10−6 at 298 K…2023 · 13 Apr · Shift 1 · Q22 · Numerical
  31. 20 mL of 0.1 M NaOH is added to 50 mL of 0.1 M acetic acid solution. The pH of the resulting solution is ​×10−2(Nearest integer) Given : pKa(CH3​COOH)=4.76…2023 · 13 Apr · Shift 2 · Q20 · Numerical
  32. Which of the following statement(s) is/are correct? (A) The pH of 1×10−8 M HCl solution is 8 . (B) The conjugate base of H2​PO4−​ is HPO42−​. (C) Kw​…2023 · 15 Apr · Shift 1 · Q9 · MCQ
  33. The dissociation constant of acetic acid is x×10−5. When 25 mL of 0.2 M CH3​COONa solution is mixed with 25 mL of 0.02 M CH3​COOH solution, the pH of the resultant solution is found to be equal to 5. The…2023 · 24 Jan · Shift 1 · Q20 · Numerical
  34. If the pKa of lactic acid is 5, then the pH of 0.005 M calcium lactate solution at 25 ∘ C is ​× 10 −1 (Nearest integer) Includes diagram2023 · 24 Jan · Shift 2 · Q22 · Numerical
  35. A litre of buffer solution contains 0.1 mole of each of NH 3​ and NH 4​ Cl. On the addition of 0.02 mole of HCl by dissolving gaseous HCl, the pH of the solution is found to be ​× 10 −3(Nearest…2023 · 25 Jan · Shift 1 · Q15 · Numerical
  36. When the hydrogen ion concentration [H +] changes by a factor of 1000, the value of pH of the solution ​2023 · 25 Jan · Shift 2 · Q2 · MCQ
  37. Millimoles of calcium hydroxide required to produce 100 mL of the aqueous solution of pH 12 is x×10−1. The value of x is ​ (Nearest integer). Assume complete dissociation.2023 · 29 Jan · Shift 1 · Q13 · Numerical
  38. 600 mL of 0.01 M HCl is mixed with 400 mL of 0.01 M H2​SO4​. The pH of the mixture is ​×10−2. (Nearest integer)…2023 · 30 Jan · Shift 1 · Q16 · Numerical
  39. The incorrect statement for the use of indicators in acid-base titration is :2023 · 31 Jan · Shift 2 · Q13 · MCQ
  40. At 298 K, the solubility of silver chloride in water is 1.434×10−3 g L−1. The value of −logKsp​ for silver chloride is ​. (Given mass of Ag…2023 · 31 Jan · Shift 2 · Q18 · Numerical
  41. 20 mL of 0.1MNH4​OH is mixed with 40 mL of 0.05MHCl. The pH of the mixture is nearest to : (Given : Kb​(NH4​OH)=1×10−5,log2=0.30,log3=0.48,log5=0.69,log7=0.84,log11=1.04)…2022 · 25 Jul · Shift 1 · Q4 · MCQ
  42. Ka1​​, Ka2​​ and Ka3​​ are the respective ionization constants for the following reactions (a), (b) and (c). (a) H2​C2​O4​⇌H++HC2​O4−​(b) HC2​O4−​⇌H++C2​O42−​…2022 · 25 Jul · Shift 2 · Q3 · MCQ
  43. The Ksp for bismuth sulphide (Bi2​S3​) is 1.08 × 10 − 73. The solubility of Bi2​S3​ in mol L − 1 at 298 K is :2022 · 25 Jun · Shift 2 · Q4 · MCQ
  44. Given below are two statements one is labelled as Assertion A and the other is labelled as Reason R : Assertion A : The amphoteric nature of water is explained by using Lewis acid/base concept. Reason R : Water acts as an acid with NH3​…2022 · 25 Jun · Shift 2 · Q6 · MCQ
  45. Class XII students were asked to prepare one litre of buffer solution of pH8.26 by their Chemistry teacher: The amount of ammonium chloride to be dissolved by the student in 0.2M ammonia solution to make one…2022 · 26 Jul · Shift 2 · Q3 · MCQ
  46. 50 mL of 0.1 M CH3​COOH is being titrated against 0.1 M NaOH. When 25 mL of NaOH has been added, the pH of the solution will be ​× 10 − 2. (Nearest integer) (Given : pKa (CH3​COOH) = 4.76) log 2 =…2022 · 26 Jun · Shift 1 · Q14 · Numerical
  47. At 310 K, the solubility of CaF2​ in water is 2.34×10−3 g/100 mL. The solubility product of CaF2​ is ​×10−8( mol/L)3…2022 · 27 Jul · Shift 1 · Q19 · Numerical
  48. In the titration of KMnO4​ and oxalic acid in acidic medium, the change in oxidation number of carbon at the end point is ​.2022 · 27 Jul · Shift 1 · Q21 · Numerical
  49. The plot of pH-metric titration of weak base NH4​OH vs strong acid HCl looks like :2022 · 27 Jul · Shift 2 · Q3 · MCQ
  50. pH value of 0.001 M NaOH solution is ​.2022 · 27 Jun · Shift 2 · Q19 · Numerical
  51. Ka​ for butyric acid (C3​H7​COOH) is 2×10−5. The pH of 0.2M solution of butyric acid is ​×10−1.…2022 · 28 Jul · Shift 1 · Q17 · Numerical
  52. Given below are two statements : One is labelled as Assertion A and the other is labelled as Reason R Assertion A : Permanganate titrations are not performed in presence of hydrochloric acid. Reason R : Chlorine is formed as a consequence…2022 · 28 Jul · Shift 2 · Q4 · MCQ
  53. The solubility product of a sparingly soluble salt A2​X3​ is 1.1 × 10 − 23. If specific conductance of the solution is 3 × 10 − 5 S m − 1, the limiting molar conductivity of the solution is x× 10 − 3 S m2…2022 · 28 Jun · Shift 1 · Q19 · Numerical
  54. A student needs to prepare a buffer solution of propanoic acid and its sodium salt with pH 4. The ratio of [CH3​CH2​COOH][CH3​CH2​COO−]​ required to make buffer is ​. Given : Ka​(CH3​CH2​COOH)=1.3×10−5…2022 · 28 Jun · Shift 2 · Q4 · MCQ
  55. If the solubility product of PbS is 8 × 10 − 28, then the solubility of PbS in pure water at 298 K is x × 10 − 16 mol L − 1. The value of x is ​. (Nearest Integer) [Given : 2​ = 1.41]2022 · 29 Jul · Shift 1 · Q20 · Numerical
  56. 200 mL of 0.01MHCl is mixed with 400 mL of 0.01MH2​SO4​. The pH of the mixture is ​. Given: log2=0.30,log3=0.48,log5=0.70,log7=0.84,log11=1.04…2022 · 29 Jul · Shift 2 · Q4 · MCQ
  57. The solubility of AgCl will be maximum in which of the following?2022 · 29 Jun · Shift 1 · Q3 · MCQ
  58. The molar solubility of Zn(OH)2​ in 0.1 M NaOH solution is x × 10 − 18 M. The value of x is ​ (Nearest integer) (Given : The solubility product of Zn(OH)2​ is 2 × 10 − 20)2021 · 1 Sep · Shift 2 · Q15 · Numerical
  59. Two salts A2​X and MX have the same value of solubility product of 4.0 × 10 − 12. The ratio of their molar solubilities i.e. S(MX)S(A2​X)​ = ​. (Round off to the Nearest Integer)2021 · 16 Mar · Shift 1 · Q15 · Numerical
  60. Sulphurous acid (H2​SO3​) has Ka1 = 1.7 × 10 − 2 and Ka2 = 6.4 × 10 − 8. The pH of 0.588 M H2​SO3​ is ​. (Round off to the Nearest Integer).2021 · 16 Mar · Shift 2 · Q22 · Numerical
  61. Which of the following compound CANNOT act as a Lewis base?2021 · 17 Mar · Shift 1 · Q7 · MCQ
  62. Given below are two statements : One is labelled as Assertion A and the other labelled as reason R Assertion A : During the boiling of water having temporary hardness, Mg(HCO3​)2​ is converted to MgCO3​. Reason R : The solubility…2021 · 18 Mar · Shift 1 · Q14 · MCQ
  63. In order to prepare a buffer solution of pH 5.74, sodium acetate is added to acetic acid. If the concentration of acetic acid in the buffer is 1.0 M, the concentration of sodium acetate in the buffer is ​ M. (Round…2021 · 18 Mar · Shift 1 · Q16 · Numerical
  64. The solubility of CdSO4​ in water is 8.0 × 10 − 4 mol L − 1. Its solubility in 0.01 M H2​SO4​ solution is ​× 10 − 6 mol L − 1. (Round off to the Nearest Integer). (Assume that solubility is…2021 · 18 Mar · Shift 2 · Q21 · Numerical
  65. A solution is 0.1 M in Cl − and 0.001 M in CrO 42−​. Solid AgNO3​ is gradually added to it. Assuming that the addition does not change in volume and Ksp(AgCl) = 1.7 × 10 − 10 M2 and Ksp(Ag2​CrO4​) = 1.9 × 10 −…2021 · 20 Jul · Shift 2 · Q4 · MCQ
  66. The solubility product of PbI2​ is 8.0 × 10 − 9. The solubility of lead iodide in 0.1 molar solution of lead nitrate is x × 10 − 6. mol/L. The value of x is ​. (Rounded off to the nearest…2021 · 24 Feb · Shift 2 · Q16 · Numerical
  67. The solubility of AgCN in a buffer solution of pH = 3 is x. The value of x is : [Assume : No cyano complex is formed; Ksp(AgCN) = 2.2 × 10 − 16 and Ka(HCN) = 6.2 × 10 − 10]2021 · 25 Feb · Shift 1 · Q1 · MCQ
  68. The solubility of Ca(OH)2​ in water is : [Given : The solubility product of Ca(OH)2​ in water = 5.5 × 10 − 6]2021 · 25 Feb · Shift 2 · Q3 · MCQ
  69. Given below are two statements. Statement I : In the titration between strong acid and weak base methyl orange is suitable as an indicator. Statement II : For titration of acetic acid with NaOH phenolphthalein is not a suitable indicator.…2021 · 26 Aug · Shift 1 · Q8 · MCQ
  70. The pH of ammonium phosphate solution, if pka of phosphoric acid and pkb of ammonium hydroxide are 5.23 and 4.75 respectively, is ​.2021 · 26 Feb · Shift 2 · Q22 · Numerical
  71. A3​B2​ is a sparingly soluble salt of molar mass M (g mol − 1) and solubility x g L − 1. The solubility product satisfies Ksp​=a(Mx​)5. The value of a is ​. (Integer answer)2021 · 31 Aug · Shift 1 · Q21 · Numerical
  72. The pH of a solution obtained by mixing 50 mL of 1 M HCl and 30 mL of 1 M NaOH is x × 10 − 4. The value of x is ​. (Nearest integer) [log 2.5 = 0.3979]2021 · 31 Aug · Shift 2 · Q17 · Numerical
  73. For the following Assertion and Reason, the correct option is Assertion (A): When Cu (II) and sulphide ions are mixed, they react together extremely quickly to give a solid. Reason (R): The equilibrium constant of Cu2+(aq) +…2020 · 2 Sep · Shift 1 · Q10 · MCQ
  74. An acidic buffer is obtained on mixing :2020 · 3 Sep · Shift 1 · Q1 · MCQ
  75. 100 mL of 0.1 M HCl is taken in a beaker and to it 100 mL of 0.1 M NaOH is added in steps of 2 mL and the pH is continuously measured. Which of the following graphs correctly depicts the change in pH?2020 · 3 Sep · Shift 2 · Q11 · MCQ
  76. A soft drink was bottled with a partial pressure of CO2​ of 3 bar over the liquid at room temperature. The partial pressure of CO2​ over the solution approaches a value of 30 bar when 44 g of CO2​ is dissolved in 1 kg of water at…2020 · 5 Sep · Shift 1 · Q14 · Numerical
  77. Arrange the following solutions in the decreasing order of pOH : (A) 0.01 M HCl (B) 0.01 M NaOH (C) 0.01 M CH3​COONa (D) 0.01 M NaCl2020 · 6 Sep · Shift 1 · Q16 · MCQ
  78. If the solubility product of AB2​ is 3.20 × 10–11 M3, then the solubility of AB2​ in pure water is ​× 10–4 mol L–1. [Assuming that neither kind of ion reacts with water]2020 · 6 Sep · Shift 2 · Q9 · Numerical
  79. Two solutions, A and B, each of 100L was made by dissolving 4g of NaOH and 9.8 g of H2​SO4​ in water, respectively. The pH of the resultant solution obtained from mixing 40L of solution A and 10L of solution B is :2020 · 7 Jan · Shift 1 · Q4 · Numerical
  80. 3 g of acetic acid is added to 250 mL of 0.1 M HCL and the solution made up to 500 mL. To 20 mL of this solutions 21​ mL of 5 M NaOH is added. The pH of the solution is ​. [Given : pKa of acetic acid =…2020 · 7 Jan · Shift 2 · Q18 · Numerical
  81. The strength of an aqueous NaOH solution is most accurately determined by titrating : (Note : consider that an appropriate indicator is used)2020 · 8 Jan · Shift 1 · Q15 · MCQ
  82. The stoichiometry and solubility product of a salt with the solubility curve given below is, respectively : Includes diagram2020 · 8 Jan · Shift 1 · Q17 · MCQ
  83. For the following Assertion and Reason, the correct option is : Assertion : The pH of water increases with increase in temperature. Reason : The dissociation of water into H+ and OH– is an exothermic reaction.2020 · 8 Jan · Shift 2 · Q17 · MCQ
  84. The Ksp for the following dissociation is 1.6 × 10–5 PbCl2(s)​⇋Pb(aq)2+​+2Cl(aq)−​ Which of the following choices is correct for a mixture of 300 mL 0.134 M Pb(NO3​)2​ and 100 mL 0.4 M NaCl ?2020 · 9 Jan · Shift 1 · Q5 · MCQ
  85. The solubility product of Cr(OH)3​ at 298 K is 6.0 × 10–31. The concentration of hydroxide ions in a saturated solution of Cr(OH)3​ will be :2020 · 9 Jan · Shift 2 · Q16 · MCQ
  86. If solublity product of Zr3​(PO4​)4​ is denoted by Ksp and its molar solubility is denoted by S, then which of the following relation between S and Ksp is correct ?2019 · 8 Apr · Shift 1 · Q19 · MCQ
  87. In an acid-base titration, 0.1 M HCl solution was added to the NaOH solution of unknown strength. Which of the following correctly shows the change of pH of the titraction mixture in this experiment? Includes diagram2019 · 9 Apr · Shift 2 · Q21 · MCQ
  88. 20 mL of 0.1 M H2​SO4​ solution is added to 30 mL of of 0.2 M NH4​OH solution. The pH of the resultant mixture is : [pkb of NH4​OH = 4.7].2019 · 9 Jan · Shift 1 · Q17 · MCQ
  89. The pH of rain water, is approximately :2019 · 9 Jan · Shift 2 · Q19 · MCQ
  90. Consider the following statements (a) The pH of a mixture containing 400 mL of 0.1 M H2​SO4​ and 400 mL of 0.1 M NaOH will be approximately 1.3 (b) Ionic product of water is temperature dependent. (c) A monobasic acid with Ka = 10–5…2019 · 10 Apr · Shift 1 · Q13 · MCQ
  91. The pH of a 0.02 M NH4​Cl solution will be : [given Kb (NH4​OH) = 10–5 and log 2 = 0.301]2019 · 10 Apr · Shift 2 · Q6 · MCQ
  92. A mixture of 100 m mol of Ca(OH)2​ and 2 g of sodium sulphate was dissolved in water and the volume was made up to 100 mL. The mass of calcium sulphate formed and the concentration of OH– in resulting solution, respectively, are : (Molar…2019 · 10 Jan · Shift 1 · Q22 · MCQ
  93. What is the molar solubility of Al(OH)3​ in 0.2 M NaOH solution ? Given that, solubility product of Al(OH)3​ = 2.4 × 10–24 :2019 · 12 Apr · Shift 1 · Q20 · MCQ
  94. The decreasing order of electrical conductivity of the following aqueous solutions is : 0.1 M Formic acid (A), 0.1 M Acetic acid (B), 0.1 M Benzoic acid (C)2019 · 12 Apr · Shift 2 · Q18 · MCQ
  95. The molar solubility of Cd(OH)2​ is 1.84 × 10–5 M in water. The expected solubility of Cd(OH)2​ in a buffer solution of pH = 12 is :2019 · 12 Apr · Shift 2 · Q4 · MCQ
  96. If Ksp of Ag2​CO3​ is 8 × 10–12, the molar solubility of Ag2​CO3​ in 0.1 M AgNO3​ is -2019 · 12 Jan · Shift 2 · Q9 · MCQ
  97. Which of the following is a Lewis acid?2018 · 15 Apr · Shift 1 · Q18 · MCQ
  98. The minimum volume of water required to dissolve 0.1 g lead (II) chloride to get a saturated solution (Ksp of PbCl2​ = 3.2 × 10-8 atomic mass of Pb = 207 u ) is :2018 · 15 Apr · Shift 1 · Q25 · MCQ
  99. Following four solutions are prepared by mixing different volumes of NaOH and HCl of different concentrations, pH of which one of them will be equal to 1 ?2018 · 15 Apr · Shift 2 · Q19 · MCQ
  100. Which of the following salts is the most basic in aqueous solution?2018 · Shift 0 · Q17 · MCQ
  101. Which of the following are Lewis acids?2018 · Shift 0 · Q18 · MCQ
  102. An aqueous solution contains 0.10 M H2​S and 0.20 M HCl. If the equilibrium constants for the formation of HS− from H2​S is 1.0 × 10–7 and that of S2− from HS− ions is 1.2 × 10–13 then the concentration of S2−…2018 · Shift 0 · Q19 · MCQ
  103. An alkali is titrated against an acid with methyl orange as indicator, which of the following is a correct combination?2018 · Shift 0 · Q2 · MCQ
  104. An aqueous solution contains an unknown concentration of Ba2+. When 50 mL of a 1 M solution of Na2​SO4​ is added, BaSO4​ just begins to precipitate. The final volume is 500 mL. The solubility product of BaSO4​ is 1 ×…2018 · Shift 0 · Q20 · MCQ
  105. Additin of sodium hydroxide solution to a weak acid (HA)results in a buffer of pH 6. If ionition constant of HA is 10 − 5, the ratio of salt to acid concentration in the buffer solution will be :2017 · 8 Apr · Shift 1 · Q20 · MCQ
  106. 50 mL of 0.2 M ammonia solution is treated with 25 mL of 0.2 M HCl. If pKb of ammonia solution is 4.75, the pH of the mixture will be :2017 · 9 Apr · Shift 1 · Q22 · MCQ
  107. pKa of a weak acid (HA) and pKb of a weak base (BOH) are 3.2 and 3.4, respectively. The pH of their salt (AB) solution is :2017 · Shift 0 · Q16 · MCQ
  108. How many litres of water must be added to 1 litre of an aqueous solution of HCl with a pH of 1 to create an aqueous solution with pH of 2?2013 · Shift 0 · Q2 · MCQ
  109. The pH of a 0.1 molar solution of the acid HQ is 3. The value of the ionization constant, Ka of this acid is :2012 · Shift 0 · Q6 · MCQ
  110. Solubility product of silver bromide is 5.0 × 10–13. The quantity of potassium bromide (molar mass taken as 120g of mol–1) to be added to 1 litre of 0.05 M solution of silver nitrate to start the precipitation of AgBr is :2010 · Shift 0 · Q4 · MCQ
  111. At 25°C, the solubility product of Mg(OH)2​ is 1.0 × 10–11. At which pH, will Mg2+ ions start precipitating in the form of Mg(OH)2​ from a solution of 0.001 M Mg2+ ions?2010 · Shift 0 · Q6 · MCQ
  112. Three reactions involving H2​PO4−​ are given below : (i) H3​PO4​ + H2​O → H3​O+ +H2​PO4−​(ii) H2​PO4−​+ H2​O →HPO42−​+ H3​O+ (iii) H2​PO4−​+ OH− → H3​PO4​ + O2− In which of the above does H2​PO4−​…2010 · Shift 0 · Q7 · MCQ
  113. Solid Ba(NO3​)2​ is gradually dissolved in a 1.0 × 10-4 M Na2​CO3​ solution. At what concentration of Ba2+ will a precipitate begin to form ? (Ksp for BaCO3​ = 5.1 × 10−9 )2009 · Shift 0 · Q6 · MCQ
  114. The pKa of a weak acid, HA, is 4.80. The pKb of a weak base, BOH, is 4.78. The pH of an aqueous solution of the corresponding salt, BA, will be2008 · Shift 0 · Q6 · MCQ
  115. Four species are listed below i. HCO3−​ ii. H3​O+ iii. HSO4−​ iv. HSO3​F Which one of the following is the correct sequence of their acid strength?2008 · Shift 0 · Q7 · MCQ
  116. The pKa of a weak acid (HA) is 4.5. The pOH of an aqueous buffered solution of HA in which 50% of the acid is ionized is :2007 · Shift 0 · Q4 · MCQ
  117. In a sautrated solution of the sparingly soluble strong electrolyte AgIO3​ (Molecular mass = 283) the equilibrium which sets in is AgIO3​(s) ⇋ Ag+(aq) +IO3−​ If the solubility product constant Ksp of AgIO3​…2007 · Shift 0 · Q5 · MCQ
  118. The first and second dissociation constants of an acid H2​A are 1.0 × 10−5 and 5.0 × 10−10 respectively. The overall dissociation constant of the acid will be :2007 · Shift 0 · Q6 · MCQ
  119. Hydrogen ion concentration in mol / L in a solution of pH = 5.4 will be :2005 · Shift 0 · Q10 · MCQ
  120. The solubility product of a salt having general formula MX2​, in water is: 4 × 10-12 . The concentration of M2+ ions in the aqueous solution of the salt is :2005 · Shift 0 · Q6 · MCQ
  121. What is the conjugate base of OH−?2005 · Shift 0 · Q9 · MCQ
  122. The conjugate base of H2​PO4−​ is :2004 · Shift 0 · Q3 · MCQ
  123. The molar solubility (in ol L-1) of a sparingly soluble salt MX4​ is "s". The corresponding solubility product is Ksp. 's' is given in term of Ksp by the relation :2004 · Shift 0 · Q7 · MCQ
  124. Which one of the following statements is not true?2003 · Shift 0 · Q1 · MCQ
  125. When rain is accompanied by a thunderstorm, the collected rain water will have a pH value :2003 · Shift 0 · Q10 · MCQ
  126. The solubility in water of a sparingly soluble salt AB2​ is 1.0 × 10-5 mol L-1. Its solubility product number will be :2003 · Shift 0 · Q7 · MCQ
  127. 1 M NaCL and 1 M HCL are present in an aqueous solution. The solution is2002 · Shift 0 · Q5 · MCQ
  128. Let the solubility of an aqueous solution of Mg(OH)2​ be x then its Ksp is :2002 · Shift 0 · Q6 · MCQ
  129. Species acting as both Bronsted acid and base is :2002 · Shift 0 · Q7 · MCQ