Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Ionic Equilibrium question

2021 · 24 Feb · Shift 2 · Q16
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Ionic Equilibrium
  5. /2021 · 24 Feb · Shift 2 · Q16

Ionic Equilibrium question

2021 · 24 Feb · Shift 2 · Q16

JEE MainChemistryIonic EquilibriumNumerical+4 / −1
The solubility product of PbI2PbI_2PbI2​ is 8.0 ×\times× 10 −-− 9. The solubility of lead iodide in 0.1 molar solution of lead nitrate is x ×\times× 10 −-− 6. mol/L. The value of x is ‾\underline{\hspace{2cm}}​. (Rounded off to the nearest integer) [Given 2\sqrt 22​ = 1.41]
Numerical answer
View written solutionFree

Correct answer: 141

  1. Write the dissolution equilibrium

PbI2(s)⇌Pb2++2I−PbI_2(s) \rightleftharpoons Pb^{2+} + 2I^-PbI2​(s)⇌Pb2++2I−

So,

Ksp=[Pb2+][I−]2K_{sp} = [Pb^{2+}][I^-]^2Ksp​=[Pb2+][I−]2

Given:

Ksp=8.0×10−9K_{sp} = 8.0 \times 10^{-9}Ksp​=8.0×10−9

  1. Consider solubility in 0.10.10.1 M Pb(NO3)2Pb(NO_3)_2Pb(NO3​)2​

Let the solubility of PbI2PbI_2PbI2​ in this solution be sss mol/L.

Then at equilibrium:

  • [Pb2+]=0.1+s[Pb^{2+}] = 0.1 + s[Pb2+]=0.1+s
  • [I−]=2s[I^-] = 2s[I−]=2s

Since sss will be very small compared to 0.10.10.1,

[Pb2+]≈0.1[Pb^{2+}] \approx 0.1[Pb2+]≈0.1

Thus,

Ksp=(0.1)(2s)2K_{sp} = (0.1)(2s)^2Ksp​=(0.1)(2s)2

  1. Substitute the values

8.0×10−9=0.1⋅4s28.0 \times 10^{-9} = 0.1 \cdot 4s^28.0×10−9=0.1⋅4s2

8.0×10−9=0.4s28.0 \times 10^{-9} = 0.4s^28.0×10−9=0.4s2

s2=8.0×10−90.4=2.0×10−8s^2 = \frac{8.0 \times 10^{-9}}{0.4} = 2.0 \times 10^{-8}s2=0.48.0×10−9​=2.0×10−8

s=2.0×10−8=2×10−4s = \sqrt{2.0 \times 10^{-8}} = \sqrt{2} \times 10^{-4}s=2.0×10−8​=2​×10−4

Given 2=1.41\sqrt{2} = 1.412​=1.41,

s=1.41×10−4 mol/Ls = 1.41 \times 10^{-4}\,\text{mol/L}s=1.41×10−4mol/L

  1. Match with the required form

We need:

s=x×10−6 mol/Ls = x \times 10^{-6}\,\text{mol/L}s=x×10−6mol/L

Since,

1.41×10−4=141×10−61.41 \times 10^{-4} = 141 \times 10^{-6}1.41×10−4=141×10−6

So,

x=141x = 141x=141

  1. Check approximation

Since s=1.41×10−4≪0.1s = 1.41 \times 10^{-4} \ll 0.1s=1.41×10−4≪0.1, neglecting sss in 0.1+s0.1+s0.1+s is valid.

Therefore, the final answer is:

141\boxed{141}141​

PreviousNext

More from Ionic Equilibrium

  • The solubility of AgCN in a buffer solution of pH = 3 is x. The value of x is : [Assume : No cyano complex is formed; Ksp(AgCN) = 2.2 × 10 − 16 and Ka(HCN) = 6.2 × 10 − 10]2021 · MCQ
  • The solubility of Ca(OH)2​ in water is : [Given : The solubility product of Ca(OH)2​ in water = 5.5 × 10 − 6]2021 · MCQ
  • Given below are two statements. Statement I : In the titration between strong acid and weak base methyl orange is suitable as an indicator. Statement II : For titration of acetic acid with NaOH phenolphthalein is not a suitable indicator.…2021 · MCQ
  • The pH of ammonium phosphate solution, if pka of phosphoric acid and pkb of ammonium hydroxide are 5.23 and 4.75 respectively, is ​.2021 · Numerical
  • A3​B2​ is a sparingly soluble salt of molar mass M (g mol − 1) and solubility x g L − 1. The solubility product satisfies Ksp​=a(Mx​)5. The value of a is ​. (Integer answer)2021 · Numerical
  • The pH of a solution obtained by mixing 50 mL of 1 M HCl and 30 mL of 1 M NaOH is x × 10 − 4. The value of x is ​. (Nearest integer) [log 2.5 = 0.3979]2021 · Numerical
  • For the following Assertion and Reason, the correct option is Assertion (A): When Cu (II) and sulphide ions are mixed, they react together extremely quickly to give a solid. Reason (R): The equilibrium constant of Cu2+(aq) +…2020 · MCQ
  • An acidic buffer is obtained on mixing :2020 · MCQ