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Ionic Equilibrium question

2023 · 24 Jan · Shift 2 · Q22
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  5. /2023 · 24 Jan · Shift 2 · Q22

Ionic Equilibrium question

2023 · 24 Jan · Shift 2 · Q22

JEE MainChemistryIonic EquilibriumNumerical+4 / −1
If the pKa of lactic acid is 5, then the pH of 0.005 M calcium lactate solution at 25 ∘^\circ∘ C is ‾×\underline{\hspace{2cm}}\times​× 10 −1^{-1}−1 (Nearest integer) JEE Main 2023 (Online) 24th January Evening Shift Chemistry - Ionic Equilibrium Question 34 English
Numerical answer
View written solutionFree

Correct answer: 85

  1. Identify the salt and its hydrolysis

Calcium lactate is a salt of:

  • strong base: Ca(OH)2\mathrm{Ca(OH)_2}Ca(OH)2​
  • weak acid: lactic acid

So its aqueous solution is basic due to hydrolysis of lactate ion.

Lactic acid is monoprotic, so calcium lactate is: Ca(lactate)2\mathrm{Ca(lactate)_2}Ca(lactate)2​

If its concentration is 0.005 M0.005\,\mathrm{M}0.005M, then lactate ion concentration is: [lactate−]=2×0.005=0.010 M[\mathrm{lactate^-}] = 2 \times 0.005 = 0.010\,\mathrm{M}[lactate−]=2×0.005=0.010M


  1. Find KaK_aKa​ and KbK_bKb​

Given: pKa=5\mathrm{p}K_a = 5pKa​=5 so Ka=10−5K_a = 10^{-5}Ka​=10−5

For the conjugate base lactate ion, Kb=KwKa=10−1410−5=10−9K_b = \frac{K_w}{K_a} = \frac{10^{-14}}{10^{-5}} = 10^{-9}Kb​=Ka​Kw​​=10−510−14​=10−9


  1. Use hydrolysis relation for weak base

For lactate ion hydrolysis: lactate−+H2O⇌HLac+OH−\mathrm{lactate^- + H_2O \rightleftharpoons HLac + OH^-}lactate−+H2​O⇌HLac+OH−

If initial concentration of lactate ion is C=0.010 MC = 0.010\,\mathrm{M}C=0.010M, then for a weak base, [OH−]≈KbC[\mathrm{OH^-}] \approx \sqrt{K_b C}[OH−]≈Kb​C​

So, [OH−]=10−9×10−2=10−11=10−5.5[\mathrm{OH^-}] = \sqrt{10^{-9} \times 10^{-2}} = \sqrt{10^{-11}} = 10^{-5.5}[OH−]=10−9×10−2​=10−11​=10−5.5

Thus, pOH=5.5\mathrm{pOH} = 5.5pOH=5.5

Hence, pH=14−5.5=8.5\mathrm{pH} = 14 - 5.5 = 8.5pH=14−5.5=8.5


  1. Match with asked format

The question writes pH as: ‾×10−1\underline{\hspace{2cm}} \times 10^{-1}​×10−1

Since 8.5=85×10−18.5 = 85 \times 10^{-1}8.5=85×10−1

the required nearest integer is: 85\boxed{85}85​


  1. Comparison with stored answer

Derived answer = 858585

Stored correct answer = 858585

So they agree.

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