JEE MainChemistryIonic EquilibriumNumerical+4 / −1
If the pKa of lactic acid is 5, then the pH of 0.005 M calcium lactate solution at 25 C is 10 (Nearest integer) 

Numerical answer
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Correct answer: 85
- Identify the salt and its hydrolysis
Calcium lactate is a salt of:
- strong base:
- weak acid: lactic acid
So its aqueous solution is basic due to hydrolysis of lactate ion.
Lactic acid is monoprotic, so calcium lactate is:
If its concentration is , then lactate ion concentration is:
- Find and
Given: so
For the conjugate base lactate ion,
- Use hydrolysis relation for weak base
For lactate ion hydrolysis:
If initial concentration of lactate ion is , then for a weak base,
So,
Thus,
Hence,
- Match with asked format
The question writes pH as:
Since
the required nearest integer is:
- Comparison with stored answer
Derived answer =
Stored correct answer =
So they agree.
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