- Aonly
- Bonly
- Cand both
- Donly
View written solutionFree
Correct answer: C
- Write the reaction
Silver nitrate and potassium iodide react as:
Spectator ions are and .
- Calculate initial moles
For :
For :
Also,
- Find limiting reagent
Reaction is between and .
Since
is limiting, so all precipitates as .
Excess iodide left:
Total volume after mixing:
So bulk concentrations are approximately:
Clearly and are present in large amounts.
- Check ions present in very small quantity
Even though almost all precipitates, because solid is present, there will be a tiny amount of both and in solution governed by solubility equilibrium:
with
Since excess iodide is present, is finite and becomes extremely small. Also, compared with spectator ions, the dissolved iodide associated with the sparingly soluble salt is also the ion involved in the very low-solubility equilibrium. Thus the ions occurring in very small amount due to the precipitation equilibrium are and .
Hence, among the options, the intended answer is:
- Compare with stored correct answer
Stored correct answer: C
Derived answer: C
They match.
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