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Ionic Equilibrium question

2002 · Shift 0 · Q7
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  5. /2002 · Shift 0 · Q7

Ionic Equilibrium question

2002 · Shift 0 · Q7

JEE MainChemistryIonic EquilibriumMCQ+4 / −1
Species acting as both Bronsted acid and base is :
  1. A
    (HSO4)−(HSO_4)^-(HSO4​)−1
  2. B
    Na2CO3Na_2CO_3Na2​CO3​
  3. C
    NH3NH_3NH3​
  4. D
    OH−OH^-OH−1
View written solutionFree

Correct answer: A

  1. Bronsted acid-base concept

A Bronsted acid is a proton donor, and a Bronsted base is a proton acceptor.

A species that can act as both acid and base is called amphiprotic.


  1. Check each option

Option A: HSO4−HSO_4^-HSO4−​

It can donate a proton: HSO4−→SO42−+H+HSO_4^- \rightarrow SO_4^{2-} + H^+HSO4−​→SO42−​+H+ So it acts as a Bronsted acid.

It can also accept a proton: HSO4−+H+→H2SO4HSO_4^- + H^+ \rightarrow H_2SO_4HSO4−​+H+→H2​SO4​ So it acts as a Bronsted base.

Hence, HSO4−HSO_4^-HSO4−​ is both acid and base.


Option B: Na2CO3Na_2CO_3Na2​CO3​

This is a salt. The basic species present is CO32−CO_3^{2-}CO32−​.

CO32−CO_3^{2-}CO32−​ can accept a proton: CO32−+H+→HCO3−CO_3^{2-} + H^+ \rightarrow HCO_3^-CO32−​+H+→HCO3−​ So it acts as a base.

But it has no proton to donate, so it does not act as a Bronsted acid.

Hence, Na2CO3Na_2CO_3Na2​CO3​ is not both.


Option C: NH3NH_3NH3​

It can accept a proton: NH3+H+→NH4+NH_3 + H^+ \rightarrow NH_4^+NH3​+H+→NH4+​ So it is a Bronsted base.

Under normal Bronsted consideration, it is not taken as a proton donor here.

Hence, NH3NH_3NH3​ is not acting as both acid and base in this context.


Option D: OH−OH^-OH−

It can accept a proton: OH−+H+→H2OOH^- + H^+ \rightarrow H_2OOH−+H+→H2​O So it acts as a base.

It can also donate a proton: OH−→O2−+H+OH^- \rightarrow O^{2-} + H^+OH−→O2−+H+ But in aqueous acid-base chemistry, OH−OH^-OH− is generally treated as a Bronsted base, and formation of O2−O^{2-}O2− is not feasible in water. Hence it is not usually considered amphiprotic in this level/context.

So this is not the intended correct answer.


  1. Conclusion

The species clearly acting as both Bronsted acid and Bronsted base is: HSO4−\boxed{HSO_4^-}HSO4−​​

So the correct option is A.

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