Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Ionic Equilibrium question

2008 · Shift 0 · Q6
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Ionic Equilibrium
  5. /2008 · Shift 0 · Q6

Ionic Equilibrium question

2008 · Shift 0 · Q6

JEE MainChemistryIonic EquilibriumMCQ+4 / −1
The pKa of a weak acid, HA, is 4.80. The pKb of a weak base, BOH, is 4.78. The pH of an aqueous solution of the corresponding salt, BA, will be
  1. A
    9.58
  2. B
    4.79
  3. C
    7.01
  4. D
    9.22
View written solutionFree

Correct answer: C

  1. Identify the type of salt

The salt BABABA is formed from:

  • weak acid: HAHAHA
  • weak base: BOHBOHBOH

So, BABABA is a salt of a weak acid and weak base.

For such a salt, the pH is given by:

pH=7+12log⁡(KbKa)\mathrm{pH} = 7 + \frac{1}{2}\log\left(\frac{K_b}{K_a}\right)pH=7+21​log(Ka​Kb​​)

This can also be written as:

pH=7+12(pKa−pKb)\mathrm{pH} = 7 + \frac{1}{2}(\mathrm{p}K_a - \mathrm{p}K_b)pH=7+21​(pKa​−pKb​)

because

log⁡(KbKa)=log⁡Kb−log⁡Ka=−pKb+pKa\log\left(\frac{K_b}{K_a}\right)=\log K_b - \log K_a = -\mathrm{p}K_b + \mathrm{p}K_alog(Ka​Kb​​)=logKb​−logKa​=−pKb​+pKa​


  1. Substitute the given values

Given:

pKa=4.80,pKb=4.78\mathrm{p}K_a = 4.80, \qquad \mathrm{p}K_b = 4.78pKa​=4.80,pKb​=4.78

So,

pH=7+12(4.80−4.78)\mathrm{pH} = 7 + \frac{1}{2}(4.80 - 4.78)pH=7+21​(4.80−4.78)

pH=7+12(0.02)\mathrm{pH} = 7 + \frac{1}{2}(0.02)pH=7+21​(0.02)

pH=7+0.01=7.01\mathrm{pH} = 7 + 0.01 = 7.01pH=7+0.01=7.01


  1. Match with the options

The calculated pH is:

7.01\boxed{7.01}7.01​

So the correct option is:

C: 7.01


  1. Compare with stored correct answer

Stored correct answer: C

Our derived answer: C

They match.

PreviousNext

More from Ionic Equilibrium

  • Four species are listed below i. HCO3−​ ii. H3​O+ iii. HSO4−​ iv. HSO3​F Which one of the following is the correct sequence of their acid strength?2008 · MCQ
  • The pKa of a weak acid (HA) is 4.5. The pOH of an aqueous buffered solution of HA in which 50% of the acid is ionized is :2007 · MCQ
  • In a sautrated solution of the sparingly soluble strong electrolyte AgIO3​ (Molecular mass = 283) the equilibrium which sets in is AgIO3​(s) ⇋ Ag+(aq) +IO3−​ If the solubility product constant Ksp of AgIO3​…2007 · MCQ
  • The first and second dissociation constants of an acid H2​A are 1.0 × 10−5 and 5.0 × 10−10 respectively. The overall dissociation constant of the acid will be :2007 · MCQ
  • Hydrogen ion concentration in mol / L in a solution of pH = 5.4 will be :2005 · MCQ
  • The solubility product of a salt having general formula MX2​, in water is: 4 × 10-12 . The concentration of M2+ ions in the aqueous solution of the salt is :2005 · MCQ
  • What is the conjugate base of OH−?2005 · MCQ
  • The conjugate base of H2​PO4−​ is :2004 · MCQ