- A(a) and (b)
- B(a), (b) and (c)
- C(a), (b) and (d)
- D(b) and (c)
View written solutionFree
Correct answer: B
- Check statement (a)
We mix:
- of
- of
First calculate moles:
Since is dibasic, total acidic equivalents:
provides:
After neutralization, excess acid equivalents:
Total volume after mixing:
So,
Hence,
So (a) is correct.
- Check statement (b)
The ionic product of water is:
This is an equilibrium constant, and equilibrium constants depend on temperature.
Hence (b) is correct.
- Check statement (c)
Given a monobasic acid with
For a weak monobasic acid of concentration , if its pH is 5:
Degree of dissociation is
Also,
If pH , then . Let us test whether is possible.
Using
Since ,
Then
So pH indeed becomes 5 and degree of dissociation is 50%.
Hence (c) is correct.
- Check statement (d)
Common-ion effect is explained using suppression of ionization due to addition of a common ion, which is a direct application of Le Chatelier's principle.
Therefore the statement
Le Chatelier's principle is not applicable to common-ion effect
is false.
So (d) is incorrect.
- Correct option
Correct statements are:
So the correct option is:
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