Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Ionic Equilibrium question

2024 · 1 Feb · Shift 2 · Q2
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Ionic Equilibrium
  5. /2024 · 1 Feb · Shift 2 · Q2

Ionic Equilibrium question

2024 · 1 Feb · Shift 2 · Q2

JEE MainChemistryIonic EquilibriumMCQ+4 / −1
Solubility of calcium phosphate (molecular mass, M) in water is Wg\mathrm{W_{g}}Wg​ per 100 mL100 \mathrm{~mL}100 mL at 25∘C25^{\circ} \mathrm{C}25∘C. Its solubility product at 25∘C25^{\circ} \mathrm{C}25∘C will be approximately.
  1. A
    107(WM)310^7\left(\frac{W}{M}\right)^3107(MW​)3
  2. B
    103(WM)510^3\left(\frac{\mathrm{W}}{\mathrm{M}}\right)^5103(MW​)5
  3. C
    107(WM)510^7\left(\frac{W}{M}\right)^5107(MW​)5
  4. D
    105(WM)510^5\left(\frac{\mathrm{W}}{\mathrm{M}}\right)^5105(MW​)5
View written solutionFree

Correct answer: C

  1. Write the dissolution equilibrium

Calcium phosphate is: Ca3(PO4)2\mathrm{Ca_3(PO_4)_2}Ca3​(PO4​)2​

Its dissolution in water is: Ca3(PO4)2(s)⇌3Ca2++2PO43−\mathrm{Ca_3(PO_4)_2(s) \rightleftharpoons 3Ca^{2+} + 2PO_4^{3-}}Ca3​(PO4​)2​(s)⇌3Ca2++2PO43−​

So, if its molar solubility is sss mol L−1^{-1}−1, then: [Ca2+]=3s,[PO43−]=2s[\mathrm{Ca^{2+}}]=3s, \qquad [\mathrm{PO_4^{3-}}]=2s[Ca2+]=3s,[PO43−​]=2s

  1. Write the solubility product expression

Ksp=[Ca2+]3[PO43−]2K_{sp}=[\mathrm{Ca^{2+}}]^3[\mathrm{PO_4^{3-}}]^2Ksp​=[Ca2+]3[PO43−​]2

Substitute the ion concentrations: Ksp=(3s)3(2s)2=27s3⋅4s2=108s5K_{sp}=(3s)^3(2s)^2=27s^3 \cdot 4s^2=108s^5Ksp​=(3s)3(2s)2=27s3⋅4s2=108s5

Thus, Ksp=108s5K_{sp}=108s^5Ksp​=108s5

  1. Convert given solubility into molar solubility

Given solubility = WWW g per 100100100 mL.

Therefore, in 111 L (= 100010001000 mL), solubility is: 10W g L−110W \text{ g L}^{-1}10W g L−1

Hence molar solubility: s=10WMs=\frac{10W}{M}s=M10W​

  1. Substitute into KspK_{sp}Ksp​

Ksp=108(10WM)5K_{sp}=108\left(\frac{10W}{M}\right)^5Ksp​=108(M10W​)5

Now, 108×105(WM)5=1.08×107(WM)5108\times 10^5 \left(\frac{W}{M}\right)^5 = 1.08\times 10^7 \left(\frac{W}{M}\right)^5108×105(MW​)5=1.08×107(MW​)5

Approximately, Ksp≈107(WM)5K_{sp} \approx 10^7\left(\frac{W}{M}\right)^5Ksp​≈107(MW​)5

  1. Match with the options

This corresponds to:

Option C: 107(WM)510^7\left(\frac{W}{M}\right)^5107(MW​)5

PreviousNext

More from Ionic Equilibrium

  • Consider the dissociation of the weak acid HX as given below HX(aq)⇌H+(aq)+X−(aq),Ka=1.2×10−5[Ka​: dissociation…2024 · Numerical
  • The equilibrium Cr2​O72−​⇌2CrO42−​ is shifted to the right in :2024 · MCQ
  • Given below are two statements : Statement (I) : A Buffer solution is the mixture of a salt and an acid or a base mixed in any particular quantities Statement (II) : Blood is naturally occurring buffer solution whose pH is…2024 · MCQ
  • For a sparingly soluble salt AB2​, the equilibrium concentrations of A2+ ions and B− ions are 1.2×10−4M and 0.24×10−3M, respectively. The solubility product of AB2​…2024 · MCQ
  • Given below are two statements : Statement (I) : Aqueous solution of ammonium carbonate is basic. Statement (II) : Acidic/basic nature of salt solution of a salt of weak acid and weak base depends on Ka​ and Kb​ value of acid and the…2024 · MCQ
  • The pH at which Mg(OH)2​[ Ksp​=1×10−11] begins to precipitate from a solution containing 0.10 M Mg2+ ions is ​.2024 · Numerical
  • The pH of an aqueous solution containing 1M benzoic acid (pKa​=4.20) and 1M sodium benzoate is 4.5. The volume of benzoic acid solution in 300 mL of this…2024 · Numerical
  • The titration curve of weak acid vs. strong base with phenolphthalein as indictor) is shown below. The Kphenolphthalein ​=4×10−10. Given: log2=0.3 The number of following statement/s which is/are… Includes diagram2023 · Numerical