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Ionic Equilibrium question

2020 · 2 Sep · Shift 1 · Q10
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Ionic Equilibrium question

2020 · 2 Sep · Shift 1 · Q10

JEE MainChemistryIonic EquilibriumMCQ+4 / −1
For the following Assertion and Reason, the correct option is Assertion (A): When CuCuCu (II) and sulphide ions are mixed, they react together extremely quickly to give a solid. Reason (R): The equilibrium constant of Cu2+Cu^{2+}Cu2+(aq) + S2−S^{2-}S2−–(aq) ⇌ CuSCuSCuS(s) is high because the solubility product is low.
  1. A
    (A) is false and (R) is true.
  2. B
    Both (A) and (R) are true but (R) is not the explanation for (A).
  3. C
    Both (A) and (R) are true and (R) is the explanation for (A).
  4. D
    Both (A) and (R) are false.
View written solutionFree

Correct answer: C

  1. Identify the process

    The reaction is: Cu2+(aq)+S2−(aq)⇌CuS(s)Cu^{2+}(aq) + S^{2-}(aq) \rightleftharpoons CuS(s)Cu2+(aq)+S2−(aq)⇌CuS(s)

    This is a precipitation reaction.

  2. Analyze the Assertion (A)

    Assertion says that when Cu2+Cu^{2+}Cu2+ and S2−S^{2-}S2− ions are mixed, they react extremely quickly to give a solid.

    • Ionic precipitation reactions in aqueous solution are generally very fast.
    • CuSCuSCuS is a highly insoluble salt, so on mixing the ions, precipitate forms almost immediately.

    Therefore, Assertion (A) is true.

  3. Analyze the Reason (R)

    Reason says that the equilibrium constant of Cu2+(aq)+S2−(aq)⇌CuS(s)Cu^{2+}(aq) + S^{2-}(aq) \rightleftharpoons CuS(s)Cu2+(aq)+S2−(aq)⇌CuS(s) is high because the solubility product is low.

    For the dissolution equilibrium: CuS(s)⇌Cu2+(aq)+S2−(aq)CuS(s) \rightleftharpoons Cu^{2+}(aq) + S^{2-}(aq)CuS(s)⇌Cu2+(aq)+S2−(aq) the equilibrium constant is the solubility product: Ksp=[Cu2+][S2−]K_{sp} = [Cu^{2+}][S^{2-}]Ksp​=[Cu2+][S2−]

    For the precipitation reaction written in the question, Cu2+(aq)+S2−(aq)⇌CuS(s)Cu^{2+}(aq) + S^{2-}(aq) \rightleftharpoons CuS(s)Cu2+(aq)+S2−(aq)⇌CuS(s) the equilibrium constant is: K=1KspK = \frac{1}{K_{sp}}K=Ksp​1​

    Since CuSCuSCuS has a very low KspK_{sp}Ksp​, its precipitation equilibrium constant KKK is very high.

    Therefore, Reason (R) is true.

  4. Check whether R explains A

    • A very low KspK_{sp}Ksp​ means the product CuSCuSCuS is highly insoluble.
    • Hence, as soon as Cu2+Cu^{2+}Cu2+ and S2−S^{2-}S2− meet in solution, the equilibrium strongly favors formation of solid CuSCuSCuS.
    • This explains why solid forms essentially immediately on mixing.

    So, (R) is the correct explanation of (A).

  5. Evaluate options

    • A: (A) false, (R) true → incorrect
    • B: both true but (R) not explanation → incorrect
    • C: both true and (R) is explanation → correct
    • D: both false → incorrect

Final Answer

C\boxed{C}C​

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