JEE MainChemistryIonic EquilibriumMCQ+4 / −1
For the following Assertion and Reason, the correct option is Assertion (A): When (II) and sulphide ions are mixed, they react together extremely quickly to give a solid. Reason (R): The equilibrium constant of (aq) + –(aq) ⇌ (s) is high because the solubility product is low.
- A(A) is false and (R) is true.
- BBoth (A) and (R) are true but (R) is not the explanation for (A).
- CBoth (A) and (R) are true and (R) is the explanation for (A).
- DBoth (A) and (R) are false.
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Correct answer: C
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Identify the process
The reaction is:
This is a precipitation reaction.
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Analyze the Assertion (A)
Assertion says that when and ions are mixed, they react extremely quickly to give a solid.
- Ionic precipitation reactions in aqueous solution are generally very fast.
- is a highly insoluble salt, so on mixing the ions, precipitate forms almost immediately.
Therefore, Assertion (A) is true.
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Analyze the Reason (R)
Reason says that the equilibrium constant of is high because the solubility product is low.
For the dissolution equilibrium: the equilibrium constant is the solubility product:
For the precipitation reaction written in the question, the equilibrium constant is:
Since has a very low , its precipitation equilibrium constant is very high.
Therefore, Reason (R) is true.
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Check whether R explains A
- A very low means the product is highly insoluble.
- Hence, as soon as and meet in solution, the equilibrium strongly favors formation of solid .
- This explains why solid forms essentially immediately on mixing.
So, (R) is the correct explanation of (A).
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Evaluate options
- A: (A) false, (R) true → incorrect
- B: both true but (R) not explanation → incorrect
- C: both true and (R) is explanation → correct
- D: both false → incorrect
Final Answer
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