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Ionic Equilibrium question

2024 · 8 Apr · Shift 2 · Q12
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  5. /2024 · 8 Apr · Shift 2 · Q12

Ionic Equilibrium question

2024 · 8 Apr · Shift 2 · Q12

JEE MainChemistryIonic EquilibriumMCQ+4 / −1
The equilibrium Cr2O72−⇌2CrO42−\mathrm{Cr}_2 \mathrm{O}_7^{2-} \rightleftharpoons 2 \mathrm{CrO}_4^{2-}Cr2​O72−​⇌2CrO42−​ is shifted to the right in :
  1. A
    a weakly acidic medium
  2. B
    a basic medium
  3. C
    a neutral medium
  4. D
    an acidic medium
View written solutionFree

Correct answer: B

  1. Consider the well-known chromate–dichromate equilibrium in water:

2CrO42−+2H+⇌Cr2O72−+H2O2\mathrm{CrO}_4^{2-} + 2\mathrm{H}^+ \rightleftharpoons \mathrm{Cr}_2\mathrm{O}_7^{2-} + \mathrm{H}_2\mathrm{O}2CrO42−​+2H+⇌Cr2​O72−​+H2​O

This is the more complete form of the given equilibrium.

  1. We are asked when the equilibrium

Cr2O72−⇌2CrO42−\mathrm{Cr}_2\mathrm{O}_7^{2-} \rightleftharpoons 2\mathrm{CrO}_4^{2-}Cr2​O72−​⇌2CrO42−​

shifts to the right, i.e. when dichromate converts into chromate.

  1. From the equilibrium expression above:
  • Increasing [H+][\mathrm{H}^+][H+] (acidic medium) shifts equilibrium to the left side of the given equation, favoring Cr2O72−\mathrm{Cr}_2\mathrm{O}_7^{2-}Cr2​O72−​.
  • Decreasing [H+][\mathrm{H}^+][H+] (basic medium) shifts equilibrium toward CrO42−\mathrm{CrO}_4^{2-}CrO42−​.
  1. Therefore, in a basic medium, the equilibrium shifts to the right.

  2. Check options:

  • A: weakly acidic medium — not correct, acidity favors dichromate
  • B: basic medium — correct
  • C: neutral medium — not the best answer
  • D: acidic medium — incorrect

Hence, the correct option is B.

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