JEE MainChemistryIonic EquilibriumMCQ+4 / −1
The equilibrium is shifted to the right in :
- Aa weakly acidic medium
- Ba basic medium
- Ca neutral medium
- Dan acidic medium
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Correct answer: B
- Consider the well-known chromate–dichromate equilibrium in water:
This is the more complete form of the given equilibrium.
- We are asked when the equilibrium
shifts to the right, i.e. when dichromate converts into chromate.
- From the equilibrium expression above:
- Increasing (acidic medium) shifts equilibrium to the left side of the given equation, favoring .
- Decreasing (basic medium) shifts equilibrium toward .
-
Therefore, in a basic medium, the equilibrium shifts to the right.
-
Check options:
- A: weakly acidic medium — not correct, acidity favors dichromate
- B: basic medium — correct
- C: neutral medium — not the best answer
- D: acidic medium — incorrect
Hence, the correct option is B.
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