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Ionic Equilibrium question

2025 · 7 Apr · Shift 1 · Q1
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  5. /2025 · 7 Apr · Shift 1 · Q1

Ionic Equilibrium question

2025 · 7 Apr · Shift 1 · Q1

JEE MainChemistryIonic EquilibriumMCQ+4 / −1
An aqueous solution of HCl with pH 1.0 is diluted by adding equal volume of water (ignoring dissociation of water). The pH of HCl solution would ((( Given log⁡2=0.30)\log 2=0.30)log2=0.30)
  1. A
    increase to 1.3
  2. B
    reduce to 0.5
  3. C
    increase to 2
  4. D
    remain same
View written solutionFree

Correct answer: A

  1. Initial pH and hydrogen ion concentration

Given: pH=1.0\text{pH} = 1.0pH=1.0

Using pH=−log⁡[H+]\text{pH} = -\log[H^+]pH=−log[H+] we get [H+]=10−1=0.1 M[H^+] = 10^{-1} = 0.1\,\text{M}[H+]=10−1=0.1M

Since HCl is a strong acid, it dissociates completely, so this is the acid concentration as well.

  1. Effect of adding equal volume of water

If equal volume of water is added, the total volume becomes double.

Hence concentration becomes half: [H+]new=0.12=0.05 M[H^+]_{\text{new}} = \frac{0.1}{2} = 0.05\,\text{M}[H+]new​=20.1​=0.05M

  1. Calculate new pH

pHnew=−log⁡(0.05)\text{pH}_{\text{new}} = -\log(0.05)pHnew​=−log(0.05)

Now, 0.05=5×10−20.05 = 5 \times 10^{-2}0.05=5×10−2 so log⁡(0.05)=log⁡5+log⁡10−2\log(0.05) = \log 5 + \log 10^{-2}log(0.05)=log5+log10−2

Using log⁡5=log⁡(102)=1−log⁡2=1−0.30=0.70\log 5 = \log\left(\frac{10}{2}\right) = 1 - \log 2 = 1 - 0.30 = 0.70log5=log(210​)=1−log2=1−0.30=0.70

Therefore, log⁡(0.05)=0.70−2=−1.30\log(0.05) = 0.70 - 2 = -1.30log(0.05)=0.70−2=−1.30

Hence, pHnew=−(−1.30)=1.30\text{pH}_{\text{new}} = -(-1.30) = 1.30pHnew​=−(−1.30)=1.30

  1. Conclusion

The pH increases from 1.01.01.0 to 1.31.31.3.

So the correct option is: A: increase to 1.3\boxed{\text{A: increase to }1.3}A: increase to 1.3​

  1. Comparison with stored correct answer

Stored correct answer: A

This matches the derived answer.

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