Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Ionic Equilibrium question

2023 · 30 Jan · Shift 1 · Q16
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Ionic Equilibrium
  5. /2023 · 30 Jan · Shift 1 · Q16

Ionic Equilibrium question

2023 · 30 Jan · Shift 1 · Q16

JEE MainChemistryIonic EquilibriumNumerical+4 / −1
600 mL600 \mathrm{~mL}600 mL of 0.01 M HCl0.01~\mathrm{M} ~\mathrm{HCl}0.01 M HCl is mixed with 400 mL400 \mathrm{~mL}400 mL of 0.01 M H2SO40.01~\mathrm{M} ~\mathrm{H}_{2} \mathrm{SO}_{4}0.01 M H2​SO4​. The pH\mathrm{pH}pH of the mixture is ‾\underline{\hspace{2cm}}​×10−2\times 10^{-2}×10−2. (Nearest integer) [Given log⁡2=0.30log⁡3=0.48log⁡5=0.69log⁡7=0.84log⁡11=1.04]\log 2=0.30\log 3=0.48\log 5=0.69\log 7=0.84\log 11=1.04]log2=0.30log3=0.48log5=0.69log7=0.84log11=1.04]
Numerical answer
View written solutionFree

Correct answer: 186

  1. Calculate moles of acids mixed
  • From 600 mL600\text{ mL}600 mL of 0.01 M HCl0.01\,\text{M HCl}0.01M HCl: n(HCl)=0.600×0.01=0.006 moln(\mathrm{HCl})=0.600\times 0.01=0.006\text{ mol}n(HCl)=0.600×0.01=0.006 mol Since HCl is a strong monoprotic acid, it gives: 0.006 mol of H+0.006\text{ mol of }\mathrm{H}^+0.006 mol of H+

  • From 400 mL400\text{ mL}400 mL of 0.01 M H2SO40.01\,\text{M }\mathrm{H_2SO_4}0.01M H2​SO4​: n(H2SO4)=0.400×0.01=0.004 moln(\mathrm{H_2SO_4})=0.400\times 0.01=0.004\text{ mol}n(H2​SO4​)=0.400×0.01=0.004 mol For this level of JEE problem, H2SO4\mathrm{H_2SO_4}H2​SO4​ is treated as a strong dibasic acid, so it gives: H2SO4→2H++SO42−\mathrm{H_2SO_4}\rightarrow 2\mathrm{H}^+ + \mathrm{SO_4^{2-}}H2​SO4​→2H++SO42−​ Hence moles of H+\mathrm{H}^+H+ from sulfuric acid: 2×0.004=0.008 mol2\times 0.004=0.008\text{ mol}2×0.004=0.008 mol

  1. Total moles of H+\mathrm{H}^+H+

n(H+)=0.006+0.008=0.014 moln(\mathrm{H}^+)=0.006+0.008=0.014\text{ mol}n(H+)=0.006+0.008=0.014 mol

  1. Total volume after mixing

Vtotal=600 mL+400 mL=1000 mL=1.0 LV_{\text{total}}=600\text{ mL}+400\text{ mL}=1000\text{ mL}=1.0\text{ L}Vtotal​=600 mL+400 mL=1000 mL=1.0 L

  1. Concentration of H+\mathrm{H}^+H+ in mixture

[H+]=0.0141.0=0.014 M=1.4×10−2[\mathrm{H}^+]=\frac{0.014}{1.0}=0.014\,\text{M}=1.4\times 10^{-2}[H+]=1.00.014​=0.014M=1.4×10−2

  1. Find pH

pH=−log⁡(1.4×10−2)\mathrm{pH}=-\log(1.4\times 10^{-2})pH=−log(1.4×10−2) =2−log⁡(1.4)=2-\log(1.4)=2−log(1.4) Now, 1.4=14101.4=\frac{14}{10}1.4=1014​ so log⁡(1.4)=log⁡14−1=log⁡(2×7)−1\log(1.4)=\log 14-1=\log(2\times 7)-1log(1.4)=log14−1=log(2×7)−1 Using given values: log⁡2=0.30,log⁡7=0.84\log 2=0.30,\qquad \log 7=0.84log2=0.30,log7=0.84 log⁡14=0.30+0.84=1.14\log 14=0.30+0.84=1.14log14=0.30+0.84=1.14 Thus, log⁡(1.4)=1.14−1=0.14\log(1.4)=1.14-1=0.14log(1.4)=1.14−1=0.14 Therefore, pH=2−0.14=1.86\mathrm{pH}=2-0.14=1.86pH=2−0.14=1.86

  1. Match with required format

The question writes pH as: ‾×10−2\underline{\hspace{2cm}}\times 10^{-2}​×10−2 Now, 1.86=186×10−21.86=186\times 10^{-2}1.86=186×10−2 So the required nearest integer is: 186\boxed{186}186​

  1. Comparison with stored answer

Derived answer =186=186=186, which matches the stored correct answer.

PreviousNext

More from Ionic Equilibrium

  • The incorrect statement for the use of indicators in acid-base titration is :2023 · MCQ
  • At 298 K, the solubility of silver chloride in water is 1.434×10−3 g L−1. The value of −logKsp​ for silver chloride is ​. (Given mass of Ag…2023 · Numerical
  • 20 mL of 0.1MNH4​OH is mixed with 40 mL of 0.05MHCl. The pH of the mixture is nearest to : (Given : Kb​(NH4​OH)=1×10−5,log2=0.30,log3=0.48,log5=0.69,log7=0.84,log11=1.04)…2022 · MCQ
  • Ka1​​, Ka2​​ and Ka3​​ are the respective ionization constants for the following reactions (a), (b) and (c). (a) H2​C2​O4​⇌H++HC2​O4−​(b) HC2​O4−​⇌H++C2​O42−​…2022 · MCQ
  • The Ksp for bismuth sulphide (Bi2​S3​) is 1.08 × 10 − 73. The solubility of Bi2​S3​ in mol L − 1 at 298 K is :2022 · MCQ
  • Given below are two statements one is labelled as Assertion A and the other is labelled as Reason R : Assertion A : The amphoteric nature of water is explained by using Lewis acid/base concept. Reason R : Water acts as an acid with NH3​…2022 · MCQ
  • Class XII students were asked to prepare one litre of buffer solution of pH8.26 by their Chemistry teacher: The amount of ammonium chloride to be dissolved by the student in 0.2M ammonia solution to make one…2022 · MCQ
  • 50 mL of 0.1 M CH3​COOH is being titrated against 0.1 M NaOH. When 25 mL of NaOH has been added, the pH of the solution will be ​× 10 − 2. (Nearest integer) (Given : pKa (CH3​COOH) = 4.76) log 2 =…2022 · Numerical